Fabricating High-Conduction and High-Transparency Tungsten-Doped Zinc Oxide Films by Pulse Laser Deposition Technique

Utilising a pulse laser deposition technique, 1.0 wt.% tungsten-doped zinc oxide (WZO) films were fabricated under different growth temperatures (200–400 °C), and their structural, optical, morphological, and electrical properties were discussed. The crystalline structures of the WZO target and film...

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Main Authors: Po-Chuan Pan, Horng-Show Koo, De-Xuan Chen, Chien-Ming Chen
Format: Article
Language:English
Published: MDPI AG 2022-07-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/12/8/1032
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author Po-Chuan Pan
Horng-Show Koo
De-Xuan Chen
Chien-Ming Chen
author_facet Po-Chuan Pan
Horng-Show Koo
De-Xuan Chen
Chien-Ming Chen
author_sort Po-Chuan Pan
collection DOAJ
description Utilising a pulse laser deposition technique, 1.0 wt.% tungsten-doped zinc oxide (WZO) films were fabricated under different growth temperatures (200–400 °C), and their structural, optical, morphological, and electrical properties were discussed. The crystalline structures of the WZO target and films were examined by X-ray diffraction (XRD) analysis, and preferred orientations along the strong c-axis (002) were strongly observed for all growth temperatures. All WZO films demonstrated transparencies above 75%, along with a wide spectral range (400–700 nm). Their bandgap values ranged between 3.21 and 3.35 eV and their optimised resistivity, which was significantly influenced by the growth temperature, was measured as 1.97 × 10<sup>−3</sup> Ω cm. Further, the electrical characteristics of the WZO films were investigated under different W-doping amounts (1.0–9.0 wt.%) and a constant growth temperature (300 °C), and the results indicated that the carrier mobility showed an opposite tendency to the W-doping percentage. In addition, the elemental compositions of the WZO films and pristine ZnO films were comparatively studied in terms of Zn, O, and W contents, via X-ray photoelectron spectroscopy (XPS) analysis.
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spelling doaj.art-d8914d658e4a4daca2ee3608bf0bf8f42023-11-30T21:10:09ZengMDPI AGCrystals2073-43522022-07-01128103210.3390/cryst12081032Fabricating High-Conduction and High-Transparency Tungsten-Doped Zinc Oxide Films by Pulse Laser Deposition TechniquePo-Chuan Pan0Horng-Show Koo1De-Xuan Chen2Chien-Ming Chen3College of Mechanical & Electrical Engineering, National Taipei University of Technology, Taipei 10608, TaiwanDepartment of Visual Communication Design, Innovative Design Colleague, Taipei University of Marine Technology, New Taipei 25172, TaiwanDepartment of Electro-Optical Engineering, Minghsin University Science and Technology, Xinfeng, Hsinchu 30401, TaiwanDepartment of Electro-Optical engineering, National Taipei University of Technology, Taipei 10608, TaiwanUtilising a pulse laser deposition technique, 1.0 wt.% tungsten-doped zinc oxide (WZO) films were fabricated under different growth temperatures (200–400 °C), and their structural, optical, morphological, and electrical properties were discussed. The crystalline structures of the WZO target and films were examined by X-ray diffraction (XRD) analysis, and preferred orientations along the strong c-axis (002) were strongly observed for all growth temperatures. All WZO films demonstrated transparencies above 75%, along with a wide spectral range (400–700 nm). Their bandgap values ranged between 3.21 and 3.35 eV and their optimised resistivity, which was significantly influenced by the growth temperature, was measured as 1.97 × 10<sup>−3</sup> Ω cm. Further, the electrical characteristics of the WZO films were investigated under different W-doping amounts (1.0–9.0 wt.%) and a constant growth temperature (300 °C), and the results indicated that the carrier mobility showed an opposite tendency to the W-doping percentage. In addition, the elemental compositions of the WZO films and pristine ZnO films were comparatively studied in terms of Zn, O, and W contents, via X-ray photoelectron spectroscopy (XPS) analysis.https://www.mdpi.com/2073-4352/12/8/1032tungsten-doped zinc oxide (WZO)pulse laser depositionbandgapphotoluminescence (PL)X-ray photoelectron spectroscopy (XPS)
spellingShingle Po-Chuan Pan
Horng-Show Koo
De-Xuan Chen
Chien-Ming Chen
Fabricating High-Conduction and High-Transparency Tungsten-Doped Zinc Oxide Films by Pulse Laser Deposition Technique
Crystals
tungsten-doped zinc oxide (WZO)
pulse laser deposition
bandgap
photoluminescence (PL)
X-ray photoelectron spectroscopy (XPS)
title Fabricating High-Conduction and High-Transparency Tungsten-Doped Zinc Oxide Films by Pulse Laser Deposition Technique
title_full Fabricating High-Conduction and High-Transparency Tungsten-Doped Zinc Oxide Films by Pulse Laser Deposition Technique
title_fullStr Fabricating High-Conduction and High-Transparency Tungsten-Doped Zinc Oxide Films by Pulse Laser Deposition Technique
title_full_unstemmed Fabricating High-Conduction and High-Transparency Tungsten-Doped Zinc Oxide Films by Pulse Laser Deposition Technique
title_short Fabricating High-Conduction and High-Transparency Tungsten-Doped Zinc Oxide Films by Pulse Laser Deposition Technique
title_sort fabricating high conduction and high transparency tungsten doped zinc oxide films by pulse laser deposition technique
topic tungsten-doped zinc oxide (WZO)
pulse laser deposition
bandgap
photoluminescence (PL)
X-ray photoelectron spectroscopy (XPS)
url https://www.mdpi.com/2073-4352/12/8/1032
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