Tunable Microwave Filters Using HfO<sub>2</sub>-Based Ferroelectrics

In this paper, we present microwave filters that are based on 6-nm-thick ferroelectric thin films of hafnium oxide doped with zirconium (HfZrO), which are tunable continuously in targeted bands of interest within the frequency range 0.1–16 GHz, when the applied direct current (DC) voltage is swept b...

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Main Authors: Martino Aldrigo, Mircea Dragoman, Sergiu Iordanescu, Florin Nastase, Silviu Vulpe
Format: Article
Language:English
Published: MDPI AG 2020-10-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/10/10/2057
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author Martino Aldrigo
Mircea Dragoman
Sergiu Iordanescu
Florin Nastase
Silviu Vulpe
author_facet Martino Aldrigo
Mircea Dragoman
Sergiu Iordanescu
Florin Nastase
Silviu Vulpe
author_sort Martino Aldrigo
collection DOAJ
description In this paper, we present microwave filters that are based on 6-nm-thick ferroelectric thin films of hafnium oxide doped with zirconium (HfZrO), which are tunable continuously in targeted bands of interest within the frequency range 0.1–16 GHz, when the applied direct current (DC) voltage is swept between 0 V and 4 V. Here, we exploit the orthorhombic polar phase in HfO<sub>2</sub> through a careful doping using zirconium in an Atomic Layer Deposition (ALD) process, in order to guarantee phase stabilization at room temperature. Polarization versus voltage characterization has been carried out, showing a remanent polarization (<i>P<sub>r</sub></i>) of ~0.8 μC/cm<sup>2</sup> and the coercive voltage at ~2.6 V. The average roughness has been found to be 0.2 nm for HfZrO films with a thickness of 6 nm. The uniform topography, without holes, and the low surface roughness demonstrate that the composition and the structure of the film are relatively constant in volume. Three filter configurations (low-pass, high-pass, and band-pass) have been designed, modelled, fabricated, and fully characterized in microwaves, showing a frequency shift of the minimum of the reflection coefficient between 90 MHz and 4.4 GHz, with a minimum insertion loss of approximately 6.9 dB in high-pass configuration.
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spelling doaj.art-d89c2778e3f54e7d84bd8d6a373839c62023-11-20T17:34:20ZengMDPI AGNanomaterials2079-49912020-10-011010205710.3390/nano10102057Tunable Microwave Filters Using HfO<sub>2</sub>-Based FerroelectricsMartino Aldrigo0Mircea Dragoman1Sergiu Iordanescu2Florin Nastase3Silviu Vulpe4National Institute for Research and Development in Microtechnologies (IMT Bucharest), Erou Iancu Nicolae Street 126A, 077190 Voluntari, Ilfov, RomaniaNational Institute for Research and Development in Microtechnologies (IMT Bucharest), Erou Iancu Nicolae Street 126A, 077190 Voluntari, Ilfov, RomaniaNational Institute for Research and Development in Microtechnologies (IMT Bucharest), Erou Iancu Nicolae Street 126A, 077190 Voluntari, Ilfov, RomaniaNational Institute for Research and Development in Microtechnologies (IMT Bucharest), Erou Iancu Nicolae Street 126A, 077190 Voluntari, Ilfov, RomaniaNational Institute for Research and Development in Microtechnologies (IMT Bucharest), Erou Iancu Nicolae Street 126A, 077190 Voluntari, Ilfov, RomaniaIn this paper, we present microwave filters that are based on 6-nm-thick ferroelectric thin films of hafnium oxide doped with zirconium (HfZrO), which are tunable continuously in targeted bands of interest within the frequency range 0.1–16 GHz, when the applied direct current (DC) voltage is swept between 0 V and 4 V. Here, we exploit the orthorhombic polar phase in HfO<sub>2</sub> through a careful doping using zirconium in an Atomic Layer Deposition (ALD) process, in order to guarantee phase stabilization at room temperature. Polarization versus voltage characterization has been carried out, showing a remanent polarization (<i>P<sub>r</sub></i>) of ~0.8 μC/cm<sup>2</sup> and the coercive voltage at ~2.6 V. The average roughness has been found to be 0.2 nm for HfZrO films with a thickness of 6 nm. The uniform topography, without holes, and the low surface roughness demonstrate that the composition and the structure of the film are relatively constant in volume. Three filter configurations (low-pass, high-pass, and band-pass) have been designed, modelled, fabricated, and fully characterized in microwaves, showing a frequency shift of the minimum of the reflection coefficient between 90 MHz and 4.4 GHz, with a minimum insertion loss of approximately 6.9 dB in high-pass configuration.https://www.mdpi.com/2079-4991/10/10/2057microwavestunable filterhafnium oxideferroelectric material
spellingShingle Martino Aldrigo
Mircea Dragoman
Sergiu Iordanescu
Florin Nastase
Silviu Vulpe
Tunable Microwave Filters Using HfO<sub>2</sub>-Based Ferroelectrics
Nanomaterials
microwaves
tunable filter
hafnium oxide
ferroelectric material
title Tunable Microwave Filters Using HfO<sub>2</sub>-Based Ferroelectrics
title_full Tunable Microwave Filters Using HfO<sub>2</sub>-Based Ferroelectrics
title_fullStr Tunable Microwave Filters Using HfO<sub>2</sub>-Based Ferroelectrics
title_full_unstemmed Tunable Microwave Filters Using HfO<sub>2</sub>-Based Ferroelectrics
title_short Tunable Microwave Filters Using HfO<sub>2</sub>-Based Ferroelectrics
title_sort tunable microwave filters using hfo sub 2 sub based ferroelectrics
topic microwaves
tunable filter
hafnium oxide
ferroelectric material
url https://www.mdpi.com/2079-4991/10/10/2057
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AT mirceadragoman tunablemicrowavefiltersusinghfosub2subbasedferroelectrics
AT sergiuiordanescu tunablemicrowavefiltersusinghfosub2subbasedferroelectrics
AT florinnastase tunablemicrowavefiltersusinghfosub2subbasedferroelectrics
AT silviuvulpe tunablemicrowavefiltersusinghfosub2subbasedferroelectrics