Modification, Characterization, and Catalytic Application of Mesolite for One Pot Synthesis of 3-Methyl-4-arylmethylene-isoxazol-5(4H)-ones
Natural mesolite type zeolite was collected, modified by sulphuric acid treatment and characterized by using Powder-X ray diffraction, Scanning electron microscopy and Energy dispersive spectroscopy, Fourier transform infrared spectroscopy. Temperature programmed ammonia desorption, Brunauer-Emmer-T...
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| Format: | Article |
| Language: | English |
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Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
2017-04-01
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| Series: | Bulletin of Chemical Reaction Engineering & Catalysis |
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| Online Access: | https://journal.bcrec.id/index.php/bcrec/article/view/655 |
| _version_ | 1797677852712239104 |
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| author | Ganesh Trambakrao Pawar Sachin Pandit Gadekar Balasaheb R. Arbad Machhindra Karbhari Lande |
| author_facet | Ganesh Trambakrao Pawar Sachin Pandit Gadekar Balasaheb R. Arbad Machhindra Karbhari Lande |
| author_sort | Ganesh Trambakrao Pawar |
| collection | DOAJ |
| description | Natural mesolite type zeolite was collected, modified by sulphuric acid treatment and characterized by using Powder-X ray diffraction, Scanning electron microscopy and Energy dispersive spectroscopy, Fourier transform infrared spectroscopy. Temperature programmed ammonia desorption, Brunauer-Emmer-Teller surface area analysis. Modified dealuminated mesolite shows an efficient catalytic activity for one pot synthesis of 3-methyl-4-arylmethylene-isoxazol-5(4H)-ones derivatives, via one pot three component condensation of benzaldehyde, ethylacetoacetate and hydroxylamine hydrochloride. Present method offers several advantages over the reported methods like a simple and inexpensive modification of catalyst, mild reaction condition, easy separation of catalyst, simple work-up procedure, nonchromatographic isolation and purification desired product and excellent yield. Furthermore, catalyst could be reused without significant loose in activity. |
| first_indexed | 2024-03-11T22:50:10Z |
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| id | doaj.art-d8abf1a771ab4ccfbdaaafab8b6927f6 |
| institution | Directory Open Access Journal |
| issn | 1978-2993 |
| language | English |
| last_indexed | 2024-03-11T22:50:10Z |
| publishDate | 2017-04-01 |
| publisher | Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) |
| record_format | Article |
| series | Bulletin of Chemical Reaction Engineering & Catalysis |
| spelling | doaj.art-d8abf1a771ab4ccfbdaaafab8b6927f62023-09-22T03:47:56ZengMasyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)Bulletin of Chemical Reaction Engineering & Catalysis1978-29932017-04-01121324010.9767/bcrec.12.1.655.32-40557Modification, Characterization, and Catalytic Application of Mesolite for One Pot Synthesis of 3-Methyl-4-arylmethylene-isoxazol-5(4H)-onesGanesh Trambakrao Pawar0Sachin Pandit Gadekar1Balasaheb R. Arbad2Machhindra Karbhari Lande3Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad (M.S.), 431004, IndiaDepartment of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad (M.S.), 431004, IndiaDepartment of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad (M.S.), 431004, IndiaDepartment of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad (M.S.), 431004, IndiaNatural mesolite type zeolite was collected, modified by sulphuric acid treatment and characterized by using Powder-X ray diffraction, Scanning electron microscopy and Energy dispersive spectroscopy, Fourier transform infrared spectroscopy. Temperature programmed ammonia desorption, Brunauer-Emmer-Teller surface area analysis. Modified dealuminated mesolite shows an efficient catalytic activity for one pot synthesis of 3-methyl-4-arylmethylene-isoxazol-5(4H)-ones derivatives, via one pot three component condensation of benzaldehyde, ethylacetoacetate and hydroxylamine hydrochloride. Present method offers several advantages over the reported methods like a simple and inexpensive modification of catalyst, mild reaction condition, easy separation of catalyst, simple work-up procedure, nonchromatographic isolation and purification desired product and excellent yield. Furthermore, catalyst could be reused without significant loose in activity.https://journal.bcrec.id/index.php/bcrec/article/view/6553-methyl-4-arylmethylene-isoxazol-5(4h)-onesbenzaldehydeethylacetoacetatehyroxylaminehydrochloridemodification of mesolitenatural zeolite |
| spellingShingle | Ganesh Trambakrao Pawar Sachin Pandit Gadekar Balasaheb R. Arbad Machhindra Karbhari Lande Modification, Characterization, and Catalytic Application of Mesolite for One Pot Synthesis of 3-Methyl-4-arylmethylene-isoxazol-5(4H)-ones Bulletin of Chemical Reaction Engineering & Catalysis 3-methyl-4-arylmethylene-isoxazol-5(4h)-ones benzaldehyde ethylacetoacetate hyroxylaminehydrochloride modification of mesolite natural zeolite |
| title | Modification, Characterization, and Catalytic Application of Mesolite for One Pot Synthesis of 3-Methyl-4-arylmethylene-isoxazol-5(4H)-ones |
| title_full | Modification, Characterization, and Catalytic Application of Mesolite for One Pot Synthesis of 3-Methyl-4-arylmethylene-isoxazol-5(4H)-ones |
| title_fullStr | Modification, Characterization, and Catalytic Application of Mesolite for One Pot Synthesis of 3-Methyl-4-arylmethylene-isoxazol-5(4H)-ones |
| title_full_unstemmed | Modification, Characterization, and Catalytic Application of Mesolite for One Pot Synthesis of 3-Methyl-4-arylmethylene-isoxazol-5(4H)-ones |
| title_short | Modification, Characterization, and Catalytic Application of Mesolite for One Pot Synthesis of 3-Methyl-4-arylmethylene-isoxazol-5(4H)-ones |
| title_sort | modification characterization and catalytic application of mesolite for one pot synthesis of 3 methyl 4 arylmethylene isoxazol 5 4h ones |
| topic | 3-methyl-4-arylmethylene-isoxazol-5(4h)-ones benzaldehyde ethylacetoacetate hyroxylaminehydrochloride modification of mesolite natural zeolite |
| url | https://journal.bcrec.id/index.php/bcrec/article/view/655 |
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