3,3,3′,3′-Tetramethyl-2,2′-diphenyl-3<i>H</i>,3′<i>H</i>-5,5′-biindole

The palladium-catalyzed homocoupling of 5-iodo-3,3-dimethyl-2-phenyl-3<i>H</i>-indole afforded 3,3,3′,3′-tetramethyl-2,2′-diphenyl-3<i>H</i>,3′<i>H</i>-5,5′-biindole in 65% yield. This previously unreported compound was fully characterized by NMR, IR and HRMS data...

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Main Authors: Urtė Šachlevičiūtė, Gabrielė Varvuolytė, Aurimas Bieliauskas, Neringa Kleizienė, Asta Žukauskaitė, Algirdas Šačkus
Format: Article
Language:English
Published: MDPI AG 2020-07-01
Series:Molbank
Subjects:
Online Access:https://www.mdpi.com/1422-8599/2020/3/M1146
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author Urtė Šachlevičiūtė
Gabrielė Varvuolytė
Aurimas Bieliauskas
Neringa Kleizienė
Asta Žukauskaitė
Algirdas Šačkus
author_facet Urtė Šachlevičiūtė
Gabrielė Varvuolytė
Aurimas Bieliauskas
Neringa Kleizienė
Asta Žukauskaitė
Algirdas Šačkus
author_sort Urtė Šachlevičiūtė
collection DOAJ
description The palladium-catalyzed homocoupling of 5-iodo-3,3-dimethyl-2-phenyl-3<i>H</i>-indole afforded 3,3,3′,3′-tetramethyl-2,2′-diphenyl-3<i>H</i>,3′<i>H</i>-5,5′-biindole in 65% yield. This previously unreported compound was fully characterized by NMR, IR and HRMS data and its optical properties were studied by UV/vis and fluorescence spectroscopy.
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spelling doaj.art-d8b141f45232401bb0ebe8d91beb96552023-11-20T06:14:10ZengMDPI AGMolbank1422-85992020-07-0120203M114610.3390/M11463,3,3′,3′-Tetramethyl-2,2′-diphenyl-3<i>H</i>,3′<i>H</i>-5,5′-biindoleUrtė Šachlevičiūtė0Gabrielė Varvuolytė1Aurimas Bieliauskas2Neringa Kleizienė3Asta Žukauskaitė4Algirdas Šačkus5Institute of Synthetic Chemistry, Kaunas University of Technology, K. Baršausko g. 59, LT-51423 Kaunas, LithuaniaInstitute of Synthetic Chemistry, Kaunas University of Technology, K. Baršausko g. 59, LT-51423 Kaunas, LithuaniaInstitute of Synthetic Chemistry, Kaunas University of Technology, K. Baršausko g. 59, LT-51423 Kaunas, LithuaniaInstitute of Synthetic Chemistry, Kaunas University of Technology, K. Baršausko g. 59, LT-51423 Kaunas, LithuaniaLaboratory of Growth Regulators, Institute of Experimental Botany of the Czech Academy of Sciences & Palacký University, Šlechtitelů 27, CZ-78371 Olomouc, Czech RepublicInstitute of Synthetic Chemistry, Kaunas University of Technology, K. Baršausko g. 59, LT-51423 Kaunas, LithuaniaThe palladium-catalyzed homocoupling of 5-iodo-3,3-dimethyl-2-phenyl-3<i>H</i>-indole afforded 3,3,3′,3′-tetramethyl-2,2′-diphenyl-3<i>H</i>,3′<i>H</i>-5,5′-biindole in 65% yield. This previously unreported compound was fully characterized by NMR, IR and HRMS data and its optical properties were studied by UV/vis and fluorescence spectroscopy.https://www.mdpi.com/1422-8599/2020/3/M1146biheterocyclefluorescencehomocouplingindolepalladium-catalyzed
spellingShingle Urtė Šachlevičiūtė
Gabrielė Varvuolytė
Aurimas Bieliauskas
Neringa Kleizienė
Asta Žukauskaitė
Algirdas Šačkus
3,3,3′,3′-Tetramethyl-2,2′-diphenyl-3<i>H</i>,3′<i>H</i>-5,5′-biindole
Molbank
biheterocycle
fluorescence
homocoupling
indole
palladium-catalyzed
title 3,3,3′,3′-Tetramethyl-2,2′-diphenyl-3<i>H</i>,3′<i>H</i>-5,5′-biindole
title_full 3,3,3′,3′-Tetramethyl-2,2′-diphenyl-3<i>H</i>,3′<i>H</i>-5,5′-biindole
title_fullStr 3,3,3′,3′-Tetramethyl-2,2′-diphenyl-3<i>H</i>,3′<i>H</i>-5,5′-biindole
title_full_unstemmed 3,3,3′,3′-Tetramethyl-2,2′-diphenyl-3<i>H</i>,3′<i>H</i>-5,5′-biindole
title_short 3,3,3′,3′-Tetramethyl-2,2′-diphenyl-3<i>H</i>,3′<i>H</i>-5,5′-biindole
title_sort 3 3 3 3 tetramethyl 2 2 diphenyl 3 i h i 3 i h i 5 5 biindole
topic biheterocycle
fluorescence
homocoupling
indole
palladium-catalyzed
url https://www.mdpi.com/1422-8599/2020/3/M1146
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