Improved efficiency of NiOx-based p-i-n perovskite solar cells by using PTEG-1 as electron transport layer

We present efficient p-i-n type perovskite solar cells using NiOx as the hole transport layer and a fulleropyrrolidine with a triethylene glycol monoethyl ether side chain (PTEG-1) as electron transport layer. This electron transport layer leads to higher power conversi...

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Main Authors: Bart G. H. M. Groeneveld, Mehrdad Najafi, Bauke Steensma, Sampson Adjokatse, Hong-Hua Fang, Fatemeh Jahani, Li Qiu, Gert H. ten Brink, Jan C. Hummelen, Maria Antonietta Loi
Format: Article
Language:English
Published: AIP Publishing LLC 2017-07-01
Series:APL Materials
Online Access:http://dx.doi.org/10.1063/1.4992783
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author Bart G. H. M. Groeneveld
Mehrdad Najafi
Bauke Steensma
Sampson Adjokatse
Hong-Hua Fang
Fatemeh Jahani
Li Qiu
Gert H. ten Brink
Jan C. Hummelen
Maria Antonietta Loi
author_facet Bart G. H. M. Groeneveld
Mehrdad Najafi
Bauke Steensma
Sampson Adjokatse
Hong-Hua Fang
Fatemeh Jahani
Li Qiu
Gert H. ten Brink
Jan C. Hummelen
Maria Antonietta Loi
author_sort Bart G. H. M. Groeneveld
collection DOAJ
description We present efficient p-i-n type perovskite solar cells using NiOx as the hole transport layer and a fulleropyrrolidine with a triethylene glycol monoethyl ether side chain (PTEG-1) as electron transport layer. This electron transport layer leads to higher power conversion efficiencies compared to perovskite solar cells with PCBM (phenyl-C61-butyric acid methyl ester). The improved performance of PTEG-1 devices is attributed to the reduced trap-assisted recombination and improved charge extraction in these solar cells, as determined by light intensity dependence and photoluminescence measurements. Through optimization of the hole and electron transport layers, the power conversion efficiency of the NiOx/perovskite/PTEG-1 solar cells was increased up to 16.1%.
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spelling doaj.art-d8c35b3f3d984e699bc7907ccbdbd4a72022-12-21T18:21:19ZengAIP Publishing LLCAPL Materials2166-532X2017-07-0157076103076103-510.1063/1.4992783004707APMImproved efficiency of NiOx-based p-i-n perovskite solar cells by using PTEG-1 as electron transport layerBart G. H. M. Groeneveld0Mehrdad Najafi1Bauke Steensma2Sampson Adjokatse3Hong-Hua Fang4Fatemeh Jahani5Li Qiu6Gert H. ten Brink7Jan C. Hummelen8Maria Antonietta Loi9Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The NetherlandsZernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The NetherlandsZernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The NetherlandsZernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The NetherlandsZernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The NetherlandsStratingh Institute for Chemistry, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The NetherlandsStratingh Institute for Chemistry, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The NetherlandsZernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The NetherlandsStratingh Institute for Chemistry, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The NetherlandsZernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The NetherlandsWe present efficient p-i-n type perovskite solar cells using NiOx as the hole transport layer and a fulleropyrrolidine with a triethylene glycol monoethyl ether side chain (PTEG-1) as electron transport layer. This electron transport layer leads to higher power conversion efficiencies compared to perovskite solar cells with PCBM (phenyl-C61-butyric acid methyl ester). The improved performance of PTEG-1 devices is attributed to the reduced trap-assisted recombination and improved charge extraction in these solar cells, as determined by light intensity dependence and photoluminescence measurements. Through optimization of the hole and electron transport layers, the power conversion efficiency of the NiOx/perovskite/PTEG-1 solar cells was increased up to 16.1%.http://dx.doi.org/10.1063/1.4992783
spellingShingle Bart G. H. M. Groeneveld
Mehrdad Najafi
Bauke Steensma
Sampson Adjokatse
Hong-Hua Fang
Fatemeh Jahani
Li Qiu
Gert H. ten Brink
Jan C. Hummelen
Maria Antonietta Loi
Improved efficiency of NiOx-based p-i-n perovskite solar cells by using PTEG-1 as electron transport layer
APL Materials
title Improved efficiency of NiOx-based p-i-n perovskite solar cells by using PTEG-1 as electron transport layer
title_full Improved efficiency of NiOx-based p-i-n perovskite solar cells by using PTEG-1 as electron transport layer
title_fullStr Improved efficiency of NiOx-based p-i-n perovskite solar cells by using PTEG-1 as electron transport layer
title_full_unstemmed Improved efficiency of NiOx-based p-i-n perovskite solar cells by using PTEG-1 as electron transport layer
title_short Improved efficiency of NiOx-based p-i-n perovskite solar cells by using PTEG-1 as electron transport layer
title_sort improved efficiency of niox based p i n perovskite solar cells by using pteg 1 as electron transport layer
url http://dx.doi.org/10.1063/1.4992783
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