Improved efficiency of NiOx-based p-i-n perovskite solar cells by using PTEG-1 as electron transport layer
We present efficient p-i-n type perovskite solar cells using NiOx as the hole transport layer and a fulleropyrrolidine with a triethylene glycol monoethyl ether side chain (PTEG-1) as electron transport layer. This electron transport layer leads to higher power conversi...
Main Authors: | , , , , , , , , , |
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Format: | Article |
Language: | English |
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AIP Publishing LLC
2017-07-01
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Series: | APL Materials |
Online Access: | http://dx.doi.org/10.1063/1.4992783 |
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author | Bart G. H. M. Groeneveld Mehrdad Najafi Bauke Steensma Sampson Adjokatse Hong-Hua Fang Fatemeh Jahani Li Qiu Gert H. ten Brink Jan C. Hummelen Maria Antonietta Loi |
author_facet | Bart G. H. M. Groeneveld Mehrdad Najafi Bauke Steensma Sampson Adjokatse Hong-Hua Fang Fatemeh Jahani Li Qiu Gert H. ten Brink Jan C. Hummelen Maria Antonietta Loi |
author_sort | Bart G. H. M. Groeneveld |
collection | DOAJ |
description | We present efficient p-i-n type perovskite solar cells using NiOx as the hole
transport layer and a fulleropyrrolidine with a triethylene glycol monoethyl ether side
chain (PTEG-1) as electron transport layer. This electron transport layer leads to higher
power conversion efficiencies compared to perovskite solar cells with PCBM
(phenyl-C61-butyric acid methyl ester). The improved performance of PTEG-1
devices is attributed to the reduced trap-assisted recombination and improved charge
extraction in these solar cells, as determined by light intensity dependence and
photoluminescence measurements. Through optimization of the hole and electron transport
layers, the power conversion efficiency of the NiOx/perovskite/PTEG-1 solar
cells was increased up to 16.1%. |
first_indexed | 2024-12-22T15:33:04Z |
format | Article |
id | doaj.art-d8c35b3f3d984e699bc7907ccbdbd4a7 |
institution | Directory Open Access Journal |
issn | 2166-532X |
language | English |
last_indexed | 2024-12-22T15:33:04Z |
publishDate | 2017-07-01 |
publisher | AIP Publishing LLC |
record_format | Article |
series | APL Materials |
spelling | doaj.art-d8c35b3f3d984e699bc7907ccbdbd4a72022-12-21T18:21:19ZengAIP Publishing LLCAPL Materials2166-532X2017-07-0157076103076103-510.1063/1.4992783004707APMImproved efficiency of NiOx-based p-i-n perovskite solar cells by using PTEG-1 as electron transport layerBart G. H. M. Groeneveld0Mehrdad Najafi1Bauke Steensma2Sampson Adjokatse3Hong-Hua Fang4Fatemeh Jahani5Li Qiu6Gert H. ten Brink7Jan C. Hummelen8Maria Antonietta Loi9Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The NetherlandsZernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The NetherlandsZernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The NetherlandsZernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The NetherlandsZernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The NetherlandsStratingh Institute for Chemistry, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The NetherlandsStratingh Institute for Chemistry, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The NetherlandsZernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The NetherlandsStratingh Institute for Chemistry, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The NetherlandsZernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The NetherlandsWe present efficient p-i-n type perovskite solar cells using NiOx as the hole transport layer and a fulleropyrrolidine with a triethylene glycol monoethyl ether side chain (PTEG-1) as electron transport layer. This electron transport layer leads to higher power conversion efficiencies compared to perovskite solar cells with PCBM (phenyl-C61-butyric acid methyl ester). The improved performance of PTEG-1 devices is attributed to the reduced trap-assisted recombination and improved charge extraction in these solar cells, as determined by light intensity dependence and photoluminescence measurements. Through optimization of the hole and electron transport layers, the power conversion efficiency of the NiOx/perovskite/PTEG-1 solar cells was increased up to 16.1%.http://dx.doi.org/10.1063/1.4992783 |
spellingShingle | Bart G. H. M. Groeneveld Mehrdad Najafi Bauke Steensma Sampson Adjokatse Hong-Hua Fang Fatemeh Jahani Li Qiu Gert H. ten Brink Jan C. Hummelen Maria Antonietta Loi Improved efficiency of NiOx-based p-i-n perovskite solar cells by using PTEG-1 as electron transport layer APL Materials |
title | Improved efficiency of NiOx-based p-i-n perovskite solar cells by
using PTEG-1 as electron transport layer |
title_full | Improved efficiency of NiOx-based p-i-n perovskite solar cells by
using PTEG-1 as electron transport layer |
title_fullStr | Improved efficiency of NiOx-based p-i-n perovskite solar cells by
using PTEG-1 as electron transport layer |
title_full_unstemmed | Improved efficiency of NiOx-based p-i-n perovskite solar cells by
using PTEG-1 as electron transport layer |
title_short | Improved efficiency of NiOx-based p-i-n perovskite solar cells by
using PTEG-1 as electron transport layer |
title_sort | improved efficiency of niox based p i n perovskite solar cells by using pteg 1 as electron transport layer |
url | http://dx.doi.org/10.1063/1.4992783 |
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