Crystal structure of N-[(methylsulfanyl)carbonyl]urea
The almost planar (r.m.s. deviation = 0.055 Å) title compound, (MeS)C(O)NHC(O)NH2, was formed during an attempted crystallization of dimethyl cyanocarbonimidodithioate with CrO2Cl2; an unexpected redox reaction converted the cyanocarbonimido moiety to a urea group and removed one methylthiol group....
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Format: | Article |
Language: | English |
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International Union of Crystallography
2016-03-01
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Series: | Acta Crystallographica Section E: Crystallographic Communications |
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Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989016002322 |
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author | Mouhamadou Birame Diop Libasse Diop Allen G. Oliver |
author_facet | Mouhamadou Birame Diop Libasse Diop Allen G. Oliver |
author_sort | Mouhamadou Birame Diop |
collection | DOAJ |
description | The almost planar (r.m.s. deviation = 0.055 Å) title compound, (MeS)C(O)NHC(O)NH2, was formed during an attempted crystallization of dimethyl cyanocarbonimidodithioate with CrO2Cl2; an unexpected redox reaction converted the cyanocarbonimido moiety to a urea group and removed one methylthiol group. In the crystal, hydrogen-bonding interactions from the amide and amido N—H groups to carbonyl O atoms of neighbouring molecules result in [010] ribbon-like chains. |
first_indexed | 2024-12-10T16:48:40Z |
format | Article |
id | doaj.art-d8d6b1c84885420ab7efb7b0c657ef78 |
institution | Directory Open Access Journal |
issn | 2056-9890 |
language | English |
last_indexed | 2024-12-10T16:48:40Z |
publishDate | 2016-03-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E: Crystallographic Communications |
spelling | doaj.art-d8d6b1c84885420ab7efb7b0c657ef782022-12-22T01:40:58ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902016-03-0172332532710.1107/S2056989016002322hb7563Crystal structure of N-[(methylsulfanyl)carbonyl]ureaMouhamadou Birame Diop0Libasse Diop1Allen G. Oliver2Laboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, SenegalLaboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, SenegalDepartment of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46557-5670, USAThe almost planar (r.m.s. deviation = 0.055 Å) title compound, (MeS)C(O)NHC(O)NH2, was formed during an attempted crystallization of dimethyl cyanocarbonimidodithioate with CrO2Cl2; an unexpected redox reaction converted the cyanocarbonimido moiety to a urea group and removed one methylthiol group. In the crystal, hydrogen-bonding interactions from the amide and amido N—H groups to carbonyl O atoms of neighbouring molecules result in [010] ribbon-like chains.http://scripts.iucr.org/cgi-bin/paper?S2056989016002322crystal structurehydrogen bondsone-dimensional structure |
spellingShingle | Mouhamadou Birame Diop Libasse Diop Allen G. Oliver Crystal structure of N-[(methylsulfanyl)carbonyl]urea Acta Crystallographica Section E: Crystallographic Communications crystal structure hydrogen bonds one-dimensional structure |
title | Crystal structure of N-[(methylsulfanyl)carbonyl]urea |
title_full | Crystal structure of N-[(methylsulfanyl)carbonyl]urea |
title_fullStr | Crystal structure of N-[(methylsulfanyl)carbonyl]urea |
title_full_unstemmed | Crystal structure of N-[(methylsulfanyl)carbonyl]urea |
title_short | Crystal structure of N-[(methylsulfanyl)carbonyl]urea |
title_sort | crystal structure of n methylsulfanyl carbonyl urea |
topic | crystal structure hydrogen bonds one-dimensional structure |
url | http://scripts.iucr.org/cgi-bin/paper?S2056989016002322 |
work_keys_str_mv | AT mouhamadoubiramediop crystalstructureofnmethylsulfanylcarbonylurea AT libassediop crystalstructureofnmethylsulfanylcarbonylurea AT allengoliver crystalstructureofnmethylsulfanylcarbonylurea |