Measurement and evaluation of cement paste porosity by electrochemical impedance spectroscopy

Porosity is an important part of cement paste microstructure, which significantly influences the mechanical properties (especially durability and strength) of cement-based materials. Electrochemical impedance spectroscopy (EIS) is a non-destructive method used to measure the pore system utilizing a...

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Main Authors: Jana Chalupová, Jiří Němeček, Vojtěch Hybášek, Vojtěch Pommer
Format: Article
Language:English
Published: CTU Central Library 2023-07-01
Series:Acta Polytechnica CTU Proceedings
Subjects:
Online Access:https://ojs.cvut.cz/ojs/index.php/APP/article/view/9213
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author Jana Chalupová
Jiří Němeček
Vojtěch Hybášek
Vojtěch Pommer
Jiří Němeček
author_facet Jana Chalupová
Jiří Němeček
Vojtěch Hybášek
Vojtěch Pommer
Jiří Němeček
author_sort Jana Chalupová
collection DOAJ
description Porosity is an important part of cement paste microstructure, which significantly influences the mechanical properties (especially durability and strength) of cement-based materials. Electrochemical impedance spectroscopy (EIS) is a non-destructive method used to measure the pore system utilizing a range of frequencies of electric current, which is fed to the cement paste by stainless steel electrodes. The pore volume is obtained from the pore resistance and the matrix capacitance measured by EIS. This paper deals with the evaluation of porosity based on resistance values from EIS on a sample of pure CEM I 42.5R Portland cement paste at 3 different hydration times (age 7, 14, 28 days).
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spelling doaj.art-d90e6f7799da4d7c804c1911e2ffbabd2023-08-14T12:14:27ZengCTU Central LibraryActa Polytechnica CTU Proceedings2336-53822023-07-014010.14311/APP.2023.40.0015Measurement and evaluation of cement paste porosity by electrochemical impedance spectroscopyJana Chalupová0Jiří Němeček1Vojtěch Hybášek2Vojtěch Pommer3Jiří Němeček4Czech Technical University in Prague, Faculty of Civil Engineering, Department of Mechanics, Thákurova 7, 166 29 Prague 6, Czech RepublicCzech Technical University in Prague, Faculty of Civil Engineering, Department of Mechanics, Thákurova 7, 166 29 Prague 6, Czech RepublicUniversity of Chemistry and Technology, Department of Metals and Corrosion Engineering, Technická 5, 166 28 Prague 6, Czech RepublicCzech Technical University in Prague, Faculty of Civil Engineering, Department of Material Engineering and Chemistry, Thákurova 7, 166 29 Prague 6, Czech RepublicCzech Technical University in Prague, Faculty of Civil Engineering, Department of Mechanics, Thákurova 7, 166 29 Prague 6, Czech Republic Porosity is an important part of cement paste microstructure, which significantly influences the mechanical properties (especially durability and strength) of cement-based materials. Electrochemical impedance spectroscopy (EIS) is a non-destructive method used to measure the pore system utilizing a range of frequencies of electric current, which is fed to the cement paste by stainless steel electrodes. The pore volume is obtained from the pore resistance and the matrix capacitance measured by EIS. This paper deals with the evaluation of porosity based on resistance values from EIS on a sample of pure CEM I 42.5R Portland cement paste at 3 different hydration times (age 7, 14, 28 days). https://ojs.cvut.cz/ojs/index.php/APP/article/view/9213electrochemical impedance spectroscopycement pasteporosity
spellingShingle Jana Chalupová
Jiří Němeček
Vojtěch Hybášek
Vojtěch Pommer
Jiří Němeček
Measurement and evaluation of cement paste porosity by electrochemical impedance spectroscopy
Acta Polytechnica CTU Proceedings
electrochemical impedance spectroscopy
cement paste
porosity
title Measurement and evaluation of cement paste porosity by electrochemical impedance spectroscopy
title_full Measurement and evaluation of cement paste porosity by electrochemical impedance spectroscopy
title_fullStr Measurement and evaluation of cement paste porosity by electrochemical impedance spectroscopy
title_full_unstemmed Measurement and evaluation of cement paste porosity by electrochemical impedance spectroscopy
title_short Measurement and evaluation of cement paste porosity by electrochemical impedance spectroscopy
title_sort measurement and evaluation of cement paste porosity by electrochemical impedance spectroscopy
topic electrochemical impedance spectroscopy
cement paste
porosity
url https://ojs.cvut.cz/ojs/index.php/APP/article/view/9213
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