Preparation of polymeric vesicles via redox-initiated RAFT dispersion polymerization
2-(diisopropylamino) ethyl methacrylate (DIPEMA) and glycidyl methacrylate (GlyMA) were used for the investigation of the redox-initiated reversible addition-fragmentation chain transfer (RAFT) dispersion polymerization, by using poly (ethylene oxide)-4-(4-Cyanopentanoic acid) dithiobenzoate (mPEG-C...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
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EDP Sciences
2023-01-01
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| Series: | E3S Web of Conferences |
| Subjects: | |
| Online Access: | https://www.e3s-conferences.org/articles/e3sconf/pdf/2023/75/e3sconf_apee2023_01020.pdf |
| _version_ | 1797634927676620800 |
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| author | Zhang Fen Yao Qian Niu Yanling Li Yantao Zhou Haijun Chen Xiaoqi Bai Lu |
| author_facet | Zhang Fen Yao Qian Niu Yanling Li Yantao Zhou Haijun Chen Xiaoqi Bai Lu |
| author_sort | Zhang Fen |
| collection | DOAJ |
| description | 2-(diisopropylamino) ethyl methacrylate (DIPEMA) and glycidyl methacrylate (GlyMA) were used for the investigation of the redox-initiated reversible addition-fragmentation chain transfer (RAFT) dispersion polymerization, by using poly (ethylene oxide)-4-(4-Cyanopentanoic acid) dithiobenzoate (mPEG-CPADB) as the macro-chain-transfer agent (macro-CTA). The particle growth process study indicated that the particles changed from spheres to worms, and then to vesicles during the polymerization process. The degree of polymerization (DP) of the hydrophobic block P(DIPEMA-co-GlyMA) affected the particle morphology, particle diameter and molecular weight significantly. Pure polymeric vesicles could be obtained when DP was equal to or higher than 60, and with increasing of the DP of the hydrophobic block, the diameter and the molecular weight of the particles both increased. |
| first_indexed | 2024-03-11T12:15:10Z |
| format | Article |
| id | doaj.art-d92c3939cfa1476fb16fcbe048ef64ed |
| institution | Directory Open Access Journal |
| issn | 2267-1242 |
| language | English |
| last_indexed | 2024-03-11T12:15:10Z |
| publishDate | 2023-01-01 |
| publisher | EDP Sciences |
| record_format | Article |
| series | E3S Web of Conferences |
| spelling | doaj.art-d92c3939cfa1476fb16fcbe048ef64ed2023-11-07T10:19:50ZengEDP SciencesE3S Web of Conferences2267-12422023-01-014380102010.1051/e3sconf/202343801020e3sconf_apee2023_01020Preparation of polymeric vesicles via redox-initiated RAFT dispersion polymerizationZhang Fen0Yao Qian1Niu Yanling2Li Yantao3Zhou Haijun4Chen Xiaoqi5Bai Lu6Institute of Energy Resources, Hebei Academy of SciencesInstitute of Energy Resources, Hebei Academy of SciencesInstitute of Energy Resources, Hebei Academy of SciencesInstitute of Energy Resources, Hebei Academy of SciencesInstitute of Energy Resources, Hebei Academy of SciencesInstitute of Energy Resources, Hebei Academy of SciencesInstitute of Energy Resources, Hebei Academy of Sciences2-(diisopropylamino) ethyl methacrylate (DIPEMA) and glycidyl methacrylate (GlyMA) were used for the investigation of the redox-initiated reversible addition-fragmentation chain transfer (RAFT) dispersion polymerization, by using poly (ethylene oxide)-4-(4-Cyanopentanoic acid) dithiobenzoate (mPEG-CPADB) as the macro-chain-transfer agent (macro-CTA). The particle growth process study indicated that the particles changed from spheres to worms, and then to vesicles during the polymerization process. The degree of polymerization (DP) of the hydrophobic block P(DIPEMA-co-GlyMA) affected the particle morphology, particle diameter and molecular weight significantly. Pure polymeric vesicles could be obtained when DP was equal to or higher than 60, and with increasing of the DP of the hydrophobic block, the diameter and the molecular weight of the particles both increased.https://www.e3s-conferences.org/articles/e3sconf/pdf/2023/75/e3sconf_apee2023_01020.pdfpolymeric vesiclesredox-initiatedreversible addition-fragmentation chain transfer (raft)dispersion polymerization |
| spellingShingle | Zhang Fen Yao Qian Niu Yanling Li Yantao Zhou Haijun Chen Xiaoqi Bai Lu Preparation of polymeric vesicles via redox-initiated RAFT dispersion polymerization E3S Web of Conferences polymeric vesicles redox-initiated reversible addition-fragmentation chain transfer (raft) dispersion polymerization |
| title | Preparation of polymeric vesicles via redox-initiated RAFT dispersion polymerization |
| title_full | Preparation of polymeric vesicles via redox-initiated RAFT dispersion polymerization |
| title_fullStr | Preparation of polymeric vesicles via redox-initiated RAFT dispersion polymerization |
| title_full_unstemmed | Preparation of polymeric vesicles via redox-initiated RAFT dispersion polymerization |
| title_short | Preparation of polymeric vesicles via redox-initiated RAFT dispersion polymerization |
| title_sort | preparation of polymeric vesicles via redox initiated raft dispersion polymerization |
| topic | polymeric vesicles redox-initiated reversible addition-fragmentation chain transfer (raft) dispersion polymerization |
| url | https://www.e3s-conferences.org/articles/e3sconf/pdf/2023/75/e3sconf_apee2023_01020.pdf |
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