Synthesis of Tetra Dentate N2O2 and their Complexes With Cu[II), Zn[II), Cd[II) and Hg[II) Ions.
A Schiff base ligand 1,2-[Bis-(1-phenyl-2-hydroxy-2-phenyl)-amino] benzene [H2L] and its complexes with (Cu(II), Zn(II), Cd(II) and Hg(II)) ions are reported. The ligand was prepared by condensation reaction of ortho-phenylenediamine in methanol under reflux with benzoin to give the mentioned ligan...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
University of Baghdad
2017-04-01
|
| Series: | Ibn Al-Haitham Journal for Pure and Applied Sciences |
| Subjects: | |
| Online Access: | https://jih.uobaghdad.edu.iq/index.php/j/article/view/305 |
| _version_ | 1818243928050106368 |
|---|---|
| author | Maysoon. T. Tawfiq Ahlaam. J. Zaier Muna . I . Khalaf |
| author_facet | Maysoon. T. Tawfiq Ahlaam. J. Zaier Muna . I . Khalaf |
| author_sort | Maysoon. T. Tawfiq |
| collection | DOAJ |
| description |
A Schiff base ligand 1,2-[Bis-(1-phenyl-2-hydroxy-2-phenyl)-amino] benzene [H2L] and its complexes with (Cu(II), Zn(II), Cd(II) and Hg(II)) ions are reported. The ligand was prepared by condensation reaction of ortho-phenylenediamine in methanol under reflux with benzoin to give the mentioned ligand. Then the complexes were synthesized by adding corresponding metal salts to the solution of the ligand in methanol under reflux with 1:1 metal to ligand ratio. On the basis of molar conductance I.R., U.V-Vis, HPLC, chloride content and atomic absorption the complexes may be formulated as K2[M(L)Cl2][MII = Cu, Zn, Cd and Hg]. The data of these measurements suggest a tetrahedral geometry to complexes Cu, Zn, Cd and Hg.
|
| first_indexed | 2024-12-12T14:08:55Z |
| format | Article |
| id | doaj.art-d944f19e09694e20a84ebf2114331118 |
| institution | Directory Open Access Journal |
| issn | 1609-4042 2521-3407 |
| language | English |
| last_indexed | 2024-12-12T14:08:55Z |
| publishDate | 2017-04-01 |
| publisher | University of Baghdad |
| record_format | Article |
| series | Ibn Al-Haitham Journal for Pure and Applied Sciences |
| spelling | doaj.art-d944f19e09694e20a84ebf21143311182022-12-22T00:22:08ZengUniversity of BaghdadIbn Al-Haitham Journal for Pure and Applied Sciences1609-40422521-34072017-04-01273Synthesis of Tetra Dentate N2O2 and their Complexes With Cu[II), Zn[II), Cd[II) and Hg[II) Ions.Maysoon. T. TawfiqAhlaam. J. ZaierMuna . I . Khalaf A Schiff base ligand 1,2-[Bis-(1-phenyl-2-hydroxy-2-phenyl)-amino] benzene [H2L] and its complexes with (Cu(II), Zn(II), Cd(II) and Hg(II)) ions are reported. The ligand was prepared by condensation reaction of ortho-phenylenediamine in methanol under reflux with benzoin to give the mentioned ligand. Then the complexes were synthesized by adding corresponding metal salts to the solution of the ligand in methanol under reflux with 1:1 metal to ligand ratio. On the basis of molar conductance I.R., U.V-Vis, HPLC, chloride content and atomic absorption the complexes may be formulated as K2[M(L)Cl2][MII = Cu, Zn, Cd and Hg]. The data of these measurements suggest a tetrahedral geometry to complexes Cu, Zn, Cd and Hg. https://jih.uobaghdad.edu.iq/index.php/j/article/view/305Synthesis, Schiff bases, Tetra dentate ligand. |
| spellingShingle | Maysoon. T. Tawfiq Ahlaam. J. Zaier Muna . I . Khalaf Synthesis of Tetra Dentate N2O2 and their Complexes With Cu[II), Zn[II), Cd[II) and Hg[II) Ions. Ibn Al-Haitham Journal for Pure and Applied Sciences Synthesis, Schiff bases, Tetra dentate ligand. |
| title | Synthesis of Tetra Dentate N2O2 and their Complexes With Cu[II), Zn[II), Cd[II) and Hg[II) Ions. |
| title_full | Synthesis of Tetra Dentate N2O2 and their Complexes With Cu[II), Zn[II), Cd[II) and Hg[II) Ions. |
| title_fullStr | Synthesis of Tetra Dentate N2O2 and their Complexes With Cu[II), Zn[II), Cd[II) and Hg[II) Ions. |
| title_full_unstemmed | Synthesis of Tetra Dentate N2O2 and their Complexes With Cu[II), Zn[II), Cd[II) and Hg[II) Ions. |
| title_short | Synthesis of Tetra Dentate N2O2 and their Complexes With Cu[II), Zn[II), Cd[II) and Hg[II) Ions. |
| title_sort | synthesis of tetra dentate n2o2 and their complexes with cu ii zn ii cd ii and hg ii ions |
| topic | Synthesis, Schiff bases, Tetra dentate ligand. |
| url | https://jih.uobaghdad.edu.iq/index.php/j/article/view/305 |
| work_keys_str_mv | AT maysoonttawfiq synthesisoftetradentaten2o2andtheircomplexeswithcuiizniicdiiandhgiiions AT ahlaamjzaier synthesisoftetradentaten2o2andtheircomplexeswithcuiizniicdiiandhgiiions AT munaikhalaf synthesisoftetradentaten2o2andtheircomplexeswithcuiizniicdiiandhgiiions |