Kinetics and energetics of metal halide perovskite conversion reactions at the nanoscale

Metal halide to perovskite phase conversion is a facile approach for synthesizing high-quality perovskite semiconductors for optoelectronic applications. Here, these reactions are investigated at the nanoscale via in-situ x-ray scattering, revealing links between reaction kinetics, structure and com...

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Main Authors: Neha Arora, Alessandro Greco, Simone Meloni, Alexander Hinderhofer, Alessandro Mattoni, Ursula Rothlisberger, Jan Hagenlocher, Claudia Caddeo, Shaik M. Zakeeruddin, Frank Schreiber, Michael Graetzel, Richard H. Friend, M. Ibrahim Dar
Format: Article
Language:English
Published: Nature Portfolio 2022-04-01
Series:Communications Materials
Online Access:https://doi.org/10.1038/s43246-022-00239-1
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author Neha Arora
Alessandro Greco
Simone Meloni
Alexander Hinderhofer
Alessandro Mattoni
Ursula Rothlisberger
Jan Hagenlocher
Claudia Caddeo
Shaik M. Zakeeruddin
Frank Schreiber
Michael Graetzel
Richard H. Friend
M. Ibrahim Dar
author_facet Neha Arora
Alessandro Greco
Simone Meloni
Alexander Hinderhofer
Alessandro Mattoni
Ursula Rothlisberger
Jan Hagenlocher
Claudia Caddeo
Shaik M. Zakeeruddin
Frank Schreiber
Michael Graetzel
Richard H. Friend
M. Ibrahim Dar
author_sort Neha Arora
collection DOAJ
description Metal halide to perovskite phase conversion is a facile approach for synthesizing high-quality perovskite semiconductors for optoelectronic applications. Here, these reactions are investigated at the nanoscale via in-situ x-ray scattering, revealing links between reaction kinetics, structure and composition.
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spelling doaj.art-d96754d288c14e90817ee5b52a6bb7cb2022-12-22T01:16:04ZengNature PortfolioCommunications Materials2662-44432022-04-01311810.1038/s43246-022-00239-1Kinetics and energetics of metal halide perovskite conversion reactions at the nanoscaleNeha Arora0Alessandro Greco1Simone Meloni2Alexander Hinderhofer3Alessandro Mattoni4Ursula Rothlisberger5Jan Hagenlocher6Claudia Caddeo7Shaik M. Zakeeruddin8Frank Schreiber9Michael Graetzel10Richard H. Friend11M. Ibrahim Dar12Cavendish Laboratory, Department of Physics, University of Cambridge, JJ Thomson AvenueInstitut für Angewandte Physik, Universität TübingenDipartimento di Scienze Chimiche e Farmaceutiche (DipSCF), Università degli Studi di Ferrara (Unife)Institut für Angewandte Physik, Universität TübingenConsiglio Nazionale delle Ricerche, Istituto Officina dei Materiali, CNR-IOM, Cagliari, Cittadella UniversitariaLaboratoire de Chimie et Biochimie Computationnelles, ISIC, FSB-BCH, Ecole Polytechnique Fédérale de Lausanne (EPFL)Institut für Angewandte Physik, Universität TübingenConsiglio Nazionale delle Ricerche, Istituto Officina dei Materiali, CNR-IOM, Cagliari, Cittadella UniversitariaLaboratory of Photonics and Interfaces, Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de LausanneInstitut für Angewandte Physik, Universität TübingenLaboratory of Photonics and Interfaces, Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de LausanneCavendish Laboratory, Department of Physics, University of Cambridge, JJ Thomson AvenueCavendish Laboratory, Department of Physics, University of Cambridge, JJ Thomson AvenueMetal halide to perovskite phase conversion is a facile approach for synthesizing high-quality perovskite semiconductors for optoelectronic applications. Here, these reactions are investigated at the nanoscale via in-situ x-ray scattering, revealing links between reaction kinetics, structure and composition.https://doi.org/10.1038/s43246-022-00239-1
spellingShingle Neha Arora
Alessandro Greco
Simone Meloni
Alexander Hinderhofer
Alessandro Mattoni
Ursula Rothlisberger
Jan Hagenlocher
Claudia Caddeo
Shaik M. Zakeeruddin
Frank Schreiber
Michael Graetzel
Richard H. Friend
M. Ibrahim Dar
Kinetics and energetics of metal halide perovskite conversion reactions at the nanoscale
Communications Materials
title Kinetics and energetics of metal halide perovskite conversion reactions at the nanoscale
title_full Kinetics and energetics of metal halide perovskite conversion reactions at the nanoscale
title_fullStr Kinetics and energetics of metal halide perovskite conversion reactions at the nanoscale
title_full_unstemmed Kinetics and energetics of metal halide perovskite conversion reactions at the nanoscale
title_short Kinetics and energetics of metal halide perovskite conversion reactions at the nanoscale
title_sort kinetics and energetics of metal halide perovskite conversion reactions at the nanoscale
url https://doi.org/10.1038/s43246-022-00239-1
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