Growth of Lu<sub>2</sub>O<sub>3</sub> and HfO<sub>2</sub> Based High Melting Temperature Single Crystals by Indirect Heating Method Using Arc Plasma

A novel single-crystal growth method was developed, using arc plasma and metal melt, for a quick survey of high melting point materials. Single crystals of Yb-doped Lu<sub>2</sub>O<sub>3</sub>, Lu<sub>0.388</sub>Hf<sub>0.612</sub>O<sub>1.806</...

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Bibliographic Details
Main Authors: Kyoung Jin Kim, Kei Kamada, Rikito Murakami, Takahiko Horiai, Shiori Ishikawa, Vladimir V. Kochurikhin, Masao Yoshino, Akihiro Yamaji, Yasuhiro Shoji, Shunsuke Kurosawa, Satoshi Toyoda, Hiroki Sato, Yuui Yokota, Yuji Ohashi, Akira Yoshikawa
Format: Article
Language:English
Published: MDPI AG 2020-07-01
Series:Crystals
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Online Access:https://www.mdpi.com/2073-4352/10/7/619
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Summary:A novel single-crystal growth method was developed, using arc plasma and metal melt, for a quick survey of high melting point materials. Single crystals of Yb-doped Lu<sub>2</sub>O<sub>3</sub>, Lu<sub>0.388</sub>Hf<sub>0.612</sub>O<sub>1.806</sub>, and Lu<sub>0.18</sub>Hf<sub>0.82</sub>O<sub>1.91</sub>, with melting points of 2460, 2900, and 2840 °C, respectively, were grown by an indirect heating method using arc plasma. We refer to this indirect heating growth method as the core heating (CH) method. The CH-grown Yb1%-doped Lu<sub>2</sub>O<sub>3</sub> sample showed a full width at half maximum of 286 arcsec in the X-ray rocking curve. This value is better than the 393 arcsec obtained for the crystal grown by the micro-pulling-down (μ-PD) method. The Yb charge transfer state (CTS) emission was observed at 350 nm in the Yb1%-doped Lu<sub>2</sub>O<sub>3</sub> and Lu<sub>0.18</sub>Hf<sub>0.82</sub>O<sub>1.91</sub>. In the case of the μ-PD method, using a rhenium (Re) crucible, absorption due to Re contamination and a resulting reduction in the Yb CTS emission were confirmed. However, contamination did not influence the properties observed in the crystals grown by the CH method.
ISSN:2073-4352