Crystal structure of benzyl(methyl)phenyl[(piperidin-1-ium-1-yl)methyl]silane bromide
The title compound, C20H29NSi+·Br−, contains a chiral silicon atom but crystallizes as a racemate. The C—Si—C bond angles in the range of 103.64 (8)–111.59 (9)° are usual for tetrahedral geometry. The piperidine ring shows a regular chair conformation with an equatorially positioned exocyclic N—C bo...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2015-10-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989015016965 |
| _version_ | 1818958743857004544 |
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| author | Eva Rebecca Barth Christopher Golz Stephan G. Koller Carsten Strohmann |
| author_facet | Eva Rebecca Barth Christopher Golz Stephan G. Koller Carsten Strohmann |
| author_sort | Eva Rebecca Barth |
| collection | DOAJ |
| description | The title compound, C20H29NSi+·Br−, contains a chiral silicon atom but crystallizes as a racemate. The C—Si—C bond angles in the range of 103.64 (8)–111.59 (9)° are usual for tetrahedral geometry. The piperidine ring shows a regular chair conformation with an equatorially positioned exocyclic N—C bond. In the crystal, there is a hydrogen bond between the ammonium cation and the bromide anion. The crystal packing shows the dominant intermolecular interaction to be the electrostatic attraction between the ammonium cation and the bromide anion. |
| first_indexed | 2024-12-20T11:30:36Z |
| format | Article |
| id | doaj.art-d9a0999745dc4b26bbca96decd73e2f5 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-20T11:30:36Z |
| publishDate | 2015-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-d9a0999745dc4b26bbca96decd73e2f52022-12-21T19:42:16ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-10-017110o759o75910.1107/S2056989015016965sj5471Crystal structure of benzyl(methyl)phenyl[(piperidin-1-ium-1-yl)methyl]silane bromideEva Rebecca Barth0Christopher Golz1Stephan G. Koller2Carsten Strohmann3Fakultät für Chemie und Chemische Biologie, Technische Universität Dortmund, Otto-Hahn-Strasse 6, 44227 Dortmund, GermanyFakultät für Chemie und Chemische Biologie, Technische Universität Dortmund, Otto-Hahn-Strasse 6, 44227 Dortmund, GermanyFakultät für Chemie und Chemische Biologie, Technische Universität Dortmund, Otto-Hahn-Strasse 6, 44227 Dortmund, GermanyFakultät für Chemie und Chemische Biologie, Technische Universität Dortmund, Otto-Hahn-Strasse 6, 44227 Dortmund, GermanyThe title compound, C20H29NSi+·Br−, contains a chiral silicon atom but crystallizes as a racemate. The C—Si—C bond angles in the range of 103.64 (8)–111.59 (9)° are usual for tetrahedral geometry. The piperidine ring shows a regular chair conformation with an equatorially positioned exocyclic N—C bond. In the crystal, there is a hydrogen bond between the ammonium cation and the bromide anion. The crystal packing shows the dominant intermolecular interaction to be the electrostatic attraction between the ammonium cation and the bromide anion.http://scripts.iucr.org/cgi-bin/paper?S2056989015016965crystal structurechiral organosilaneN—H...Br hydrogen bond |
| spellingShingle | Eva Rebecca Barth Christopher Golz Stephan G. Koller Carsten Strohmann Crystal structure of benzyl(methyl)phenyl[(piperidin-1-ium-1-yl)methyl]silane bromide Acta Crystallographica Section E: Crystallographic Communications crystal structure chiral organosilane N—H...Br hydrogen bond |
| title | Crystal structure of benzyl(methyl)phenyl[(piperidin-1-ium-1-yl)methyl]silane bromide |
| title_full | Crystal structure of benzyl(methyl)phenyl[(piperidin-1-ium-1-yl)methyl]silane bromide |
| title_fullStr | Crystal structure of benzyl(methyl)phenyl[(piperidin-1-ium-1-yl)methyl]silane bromide |
| title_full_unstemmed | Crystal structure of benzyl(methyl)phenyl[(piperidin-1-ium-1-yl)methyl]silane bromide |
| title_short | Crystal structure of benzyl(methyl)phenyl[(piperidin-1-ium-1-yl)methyl]silane bromide |
| title_sort | crystal structure of benzyl methyl phenyl piperidin 1 ium 1 yl methyl silane bromide |
| topic | crystal structure chiral organosilane N—H...Br hydrogen bond |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989015016965 |
| work_keys_str_mv | AT evarebeccabarth crystalstructureofbenzylmethylphenylpiperidin1ium1ylmethylsilanebromide AT christophergolz crystalstructureofbenzylmethylphenylpiperidin1ium1ylmethylsilanebromide AT stephangkoller crystalstructureofbenzylmethylphenylpiperidin1ium1ylmethylsilanebromide AT carstenstrohmann crystalstructureofbenzylmethylphenylpiperidin1ium1ylmethylsilanebromide |