[2-(2-Carboxyphenyl)benzoato]bis(1,10-phenanthroline)zinc(II) 2-(2-carboxyphenyl)benzoate monohydrate
In the title compound, [Zn(C14H9O4)(C12H8N2)2](C14H9O4)·H2O, the ZnII atom of the complex cation is six-coordinated in an octahedral geometry by four N atoms from two 1,10-phenanthroline ligands and two O atoms of a carboxylate group from a singly deprotonated diphenic acid. The phenanthrol...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808005862 |
| _version_ | 1798019039641993216 |
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| author | Shi-Ping Yang Wei-Wei Huang |
| author_facet | Shi-Ping Yang Wei-Wei Huang |
| author_sort | Shi-Ping Yang |
| collection | DOAJ |
| description | In the title compound, [Zn(C14H9O4)(C12H8N2)2](C14H9O4)·H2O, the ZnII atom of the complex cation is six-coordinated in an octahedral geometry by four N atoms from two 1,10-phenanthroline ligands and two O atoms of a carboxylate group from a singly deprotonated diphenic acid. The phenanthroline and carboxylate ligands act as chelating ligands. The dihedral angles between the two benzene rings in the deprotonated diphenic acid groups are 81.05 (2) (ligand) and 89.10 (2)° (anion). O—H...O and C—H...O hydrogen bonds link the components into a three-dimensional network. |
| first_indexed | 2024-04-11T16:34:14Z |
| format | Article |
| id | doaj.art-d9b1e46e83424a74bed96f96d13351c3 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:34:14Z |
| publishDate | 2008-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-d9b1e46e83424a74bed96f96d13351c32022-12-22T04:13:55ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-04-01644m525m52610.1107/S1600536808005862[2-(2-Carboxyphenyl)benzoato]bis(1,10-phenanthroline)zinc(II) 2-(2-carboxyphenyl)benzoate monohydrateShi-Ping YangWei-Wei HuangIn the title compound, [Zn(C14H9O4)(C12H8N2)2](C14H9O4)·H2O, the ZnII atom of the complex cation is six-coordinated in an octahedral geometry by four N atoms from two 1,10-phenanthroline ligands and two O atoms of a carboxylate group from a singly deprotonated diphenic acid. The phenanthroline and carboxylate ligands act as chelating ligands. The dihedral angles between the two benzene rings in the deprotonated diphenic acid groups are 81.05 (2) (ligand) and 89.10 (2)° (anion). O—H...O and C—H...O hydrogen bonds link the components into a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536808005862 |
| spellingShingle | Shi-Ping Yang Wei-Wei Huang [2-(2-Carboxyphenyl)benzoato]bis(1,10-phenanthroline)zinc(II) 2-(2-carboxyphenyl)benzoate monohydrate Acta Crystallographica Section E |
| title | [2-(2-Carboxyphenyl)benzoato]bis(1,10-phenanthroline)zinc(II) 2-(2-carboxyphenyl)benzoate monohydrate |
| title_full | [2-(2-Carboxyphenyl)benzoato]bis(1,10-phenanthroline)zinc(II) 2-(2-carboxyphenyl)benzoate monohydrate |
| title_fullStr | [2-(2-Carboxyphenyl)benzoato]bis(1,10-phenanthroline)zinc(II) 2-(2-carboxyphenyl)benzoate monohydrate |
| title_full_unstemmed | [2-(2-Carboxyphenyl)benzoato]bis(1,10-phenanthroline)zinc(II) 2-(2-carboxyphenyl)benzoate monohydrate |
| title_short | [2-(2-Carboxyphenyl)benzoato]bis(1,10-phenanthroline)zinc(II) 2-(2-carboxyphenyl)benzoate monohydrate |
| title_sort | 2 2 carboxyphenyl benzoato bis 1 10 phenanthroline zinc ii 2 2 carboxyphenyl benzoate monohydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808005862 |
| work_keys_str_mv | AT shipingyang 22carboxyphenylbenzoatobis110phenanthrolinezincii22carboxyphenylbenzoatemonohydrate AT weiweihuang 22carboxyphenylbenzoatobis110phenanthrolinezincii22carboxyphenylbenzoatemonohydrate |