Green Hydrogen Production through Ammonia Decomposition Using Non-Thermal Plasma

Liquid hydrogen carriers will soon play a significant role in transporting energy. The key factors that are considered when assessing the applicability of ammonia cracking in large-scale projects are as follows: high energy density, easy storage and distribution, the simplicity of the overall proces...

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Main Authors: Julia Moszczyńska, Xinying Liu, Marek Wiśniewski
Format: Article
Language:English
Published: MDPI AG 2023-09-01
Series:International Journal of Molecular Sciences
Subjects:
Online Access:https://www.mdpi.com/1422-0067/24/18/14397
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author Julia Moszczyńska
Xinying Liu
Marek Wiśniewski
author_facet Julia Moszczyńska
Xinying Liu
Marek Wiśniewski
author_sort Julia Moszczyńska
collection DOAJ
description Liquid hydrogen carriers will soon play a significant role in transporting energy. The key factors that are considered when assessing the applicability of ammonia cracking in large-scale projects are as follows: high energy density, easy storage and distribution, the simplicity of the overall process, and a low or zero-carbon footprint. Thermal systems used for recovering H<sub>2</sub> from ammonia require a reaction unit and catalyst that operates at a high temperature (550–800 °C) for the complete conversion of ammonia, which has a negative effect on the economics of the process. A non-thermal plasma (NTP) solution is the answer to this problem. Ammonia becomes a reliable hydrogen carrier and, in combination with NTP, offers the high conversion of the dehydrogenation process at a relatively low temperature so that zero-carbon pure hydrogen can be transported over long distances. This paper provides a critical overview of ammonia decomposition systems that focus on non-thermal methods, especially under plasma conditions. The review shows that the process has various positive aspects and is an innovative process that has only been reported to a limited extent.
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spelling doaj.art-d9d0932785cb437ab2cfc3c3fb67167c2023-11-19T11:12:09ZengMDPI AGInternational Journal of Molecular Sciences1661-65961422-00672023-09-0124181439710.3390/ijms241814397Green Hydrogen Production through Ammonia Decomposition Using Non-Thermal PlasmaJulia Moszczyńska0Xinying Liu1Marek Wiśniewski2Department of Materials Chemistry, Adsorption and Catalysis, Faculty of Chemistry, Nicolaus Copernicus University in Torun, Gagarina 7, 87-100 Torun, PolandInstitute for Catalysis and Energy Solutions, University of South Africa, Private Bag X6, Florida 1710, South AfricaDepartment of Materials Chemistry, Adsorption and Catalysis, Faculty of Chemistry, Nicolaus Copernicus University in Torun, Gagarina 7, 87-100 Torun, PolandLiquid hydrogen carriers will soon play a significant role in transporting energy. The key factors that are considered when assessing the applicability of ammonia cracking in large-scale projects are as follows: high energy density, easy storage and distribution, the simplicity of the overall process, and a low or zero-carbon footprint. Thermal systems used for recovering H<sub>2</sub> from ammonia require a reaction unit and catalyst that operates at a high temperature (550–800 °C) for the complete conversion of ammonia, which has a negative effect on the economics of the process. A non-thermal plasma (NTP) solution is the answer to this problem. Ammonia becomes a reliable hydrogen carrier and, in combination with NTP, offers the high conversion of the dehydrogenation process at a relatively low temperature so that zero-carbon pure hydrogen can be transported over long distances. This paper provides a critical overview of ammonia decomposition systems that focus on non-thermal methods, especially under plasma conditions. The review shows that the process has various positive aspects and is an innovative process that has only been reported to a limited extent.https://www.mdpi.com/1422-0067/24/18/14397hydrogen storagegreen hydrogen synthesisnon-thermal plasmaammonia splittingcatalysis
spellingShingle Julia Moszczyńska
Xinying Liu
Marek Wiśniewski
Green Hydrogen Production through Ammonia Decomposition Using Non-Thermal Plasma
International Journal of Molecular Sciences
hydrogen storage
green hydrogen synthesis
non-thermal plasma
ammonia splitting
catalysis
title Green Hydrogen Production through Ammonia Decomposition Using Non-Thermal Plasma
title_full Green Hydrogen Production through Ammonia Decomposition Using Non-Thermal Plasma
title_fullStr Green Hydrogen Production through Ammonia Decomposition Using Non-Thermal Plasma
title_full_unstemmed Green Hydrogen Production through Ammonia Decomposition Using Non-Thermal Plasma
title_short Green Hydrogen Production through Ammonia Decomposition Using Non-Thermal Plasma
title_sort green hydrogen production through ammonia decomposition using non thermal plasma
topic hydrogen storage
green hydrogen synthesis
non-thermal plasma
ammonia splitting
catalysis
url https://www.mdpi.com/1422-0067/24/18/14397
work_keys_str_mv AT juliamoszczynska greenhydrogenproductionthroughammoniadecompositionusingnonthermalplasma
AT xinyingliu greenhydrogenproductionthroughammoniadecompositionusingnonthermalplasma
AT marekwisniewski greenhydrogenproductionthroughammoniadecompositionusingnonthermalplasma