Observation of Josephson-like Tunneling Junction Characteristics and Positive Magnetoresistance in Oxygen Deficient Nickelate Films of Nd<sub>0.8</sub>Sr<sub>0.2</sub>NiO<sub>3−<i>δ</i></sub>

Nickelate films have recently attracted broad attention due to the observation of superconductivity in the infinite layer phase of Nd<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow>...

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Bibliographic Details
Main Authors: Gad Koren, Anna Eyal, Leonid Iomin, Yuval Nitzav
Format: Article
Language:English
Published: MDPI AG 2021-12-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/14/24/7689
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Summary:Nickelate films have recently attracted broad attention due to the observation of superconductivity in the infinite layer phase of Nd<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mrow><mn>0.8</mn></mrow></msub></semantics></math></inline-formula>Sr<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mrow><mn>0.2</mn></mrow></msub></semantics></math></inline-formula>NiO<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>2</mn></msub></semantics></math></inline-formula> (obtained by reducing Sr doped NdNiO<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>3</mn></msub></semantics></math></inline-formula> films) and their similarity to the cuprates high temperature superconductors. Here, we report on the observation of a new type of transport in oxygen poor Nd<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mrow><mn>0.8</mn></mrow></msub></semantics></math></inline-formula>Sr<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mrow><mn>0.2</mn></mrow></msub></semantics></math></inline-formula>NiO<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mrow><mn>3</mn><mo>−</mo><mi>δ</mi></mrow></msub></semantics></math></inline-formula> films. At high temperatures, variable range hopping is observed while at low temperatures a novel tunneling behavior is found where a Josephson-like tunneling junction characteristic with serial resistance is revealed. We attribute this phenomenon to coupling between superconductive (S) surfaces of the grains in our Oxygen poor films via the insulating (I) grain boundaries, which yields SIS junctions in series with the normal (N) resistance of the grains themselves. The similarity of the observed conductance spectra to the tunneling junction characteristic with Josephson-like current is striking, and seems to support the existence of superconductivity in our samples.
ISSN:1996-1944