Novel Proton-Conducting Layered Perovskites Based on BaLa<sub>2</sub>In<sub>2</sub>O<sub>7</sub> Produced by Cationic Co-Doping
Proton conducting materials are used in electrochemical devices such as proton conducting fuel cells and proton conducting electrolyzers. These devices belong to the hydrogen energy field and serve the goals of clean energy and sustainable environmental development. Layered perovskites are a promisi...
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2023-03-01
|
| Series: | Applied Sciences |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2076-3417/13/6/3449 |
| _version_ | 1797613741890600960 |
|---|---|
| author | Nataliia Tarasova Anzhelika Bedarkova Irina Animitsa Ekaterina Abakumova Alexey Trofimov Evgeniya Verinkina |
| author_facet | Nataliia Tarasova Anzhelika Bedarkova Irina Animitsa Ekaterina Abakumova Alexey Trofimov Evgeniya Verinkina |
| author_sort | Nataliia Tarasova |
| collection | DOAJ |
| description | Proton conducting materials are used in electrochemical devices such as proton conducting fuel cells and proton conducting electrolyzers. These devices belong to the hydrogen energy field and serve the goals of clean energy and sustainable environmental development. Layered perovskites are a promising class of proton conducting electrolytes. Cationic co-doping is a well-known method to improve the transport properties of classical perovskite ABO<sub>3</sub>. However, data on the application of this method to layered perovskites are limited. In this work, the bilayered perovskites BaLa<sub>1.9−<i>x</i></sub>Sr<i><sub>x</sub></i>Gd<sub>0.1</sub>In<sub>2</sub>O<sub>7−0.5<i>x</i></sub> have been prepared and studied for the first time. The possibility of oxygen-ionic and proton transport was demonstrated. Cationic co-doping was shown to increase the proton conductivity values by up to 1.5 orders of magnitude. |
| first_indexed | 2024-03-11T06:59:59Z |
| format | Article |
| id | doaj.art-d9db18d0678347bcb6828b53bd93804b |
| institution | Directory Open Access Journal |
| issn | 2076-3417 |
| language | English |
| last_indexed | 2024-03-11T06:59:59Z |
| publishDate | 2023-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Applied Sciences |
| spelling | doaj.art-d9db18d0678347bcb6828b53bd93804b2023-11-17T09:21:52ZengMDPI AGApplied Sciences2076-34172023-03-01136344910.3390/app13063449Novel Proton-Conducting Layered Perovskites Based on BaLa<sub>2</sub>In<sub>2</sub>O<sub>7</sub> Produced by Cationic Co-DopingNataliia Tarasova0Anzhelika Bedarkova1Irina Animitsa2Ekaterina Abakumova3Alexey Trofimov4Evgeniya Verinkina5The Institute of High Temperature Electrochemistry of the Ural Branch, Russian Academy of Sciences, 620016 Yekaterinburg, RussiaThe Institute of High Temperature Electrochemistry of the Ural Branch, Russian Academy of Sciences, 620016 Yekaterinburg, RussiaThe Institute of High Temperature Electrochemistry of the Ural Branch, Russian Academy of Sciences, 620016 Yekaterinburg, RussiaThe Institute of High Temperature Electrochemistry of the Ural Branch, Russian Academy of Sciences, 620016 Yekaterinburg, RussiaThe Institute of High Temperature Electrochemistry of the Ural Branch, Russian Academy of Sciences, 620016 Yekaterinburg, RussiaInstitute of Hydrogen Energy, Ural Federal University, 620000 Yekaterinburg, RussiaProton conducting materials are used in electrochemical devices such as proton conducting fuel cells and proton conducting electrolyzers. These devices belong to the hydrogen energy field and serve the goals of clean energy and sustainable environmental development. Layered perovskites are a promising class of proton conducting electrolytes. Cationic co-doping is a well-known method to improve the transport properties of classical perovskite ABO<sub>3</sub>. However, data on the application of this method to layered perovskites are limited. In this work, the bilayered perovskites BaLa<sub>1.9−<i>x</i></sub>Sr<i><sub>x</sub></i>Gd<sub>0.1</sub>In<sub>2</sub>O<sub>7−0.5<i>x</i></sub> have been prepared and studied for the first time. The possibility of oxygen-ionic and proton transport was demonstrated. Cationic co-doping was shown to increase the proton conductivity values by up to 1.5 orders of magnitude.https://www.mdpi.com/2076-3417/13/6/3449layered perovskiteoxygen-ion conductivityproton conductivityhydrogen energyRuddlesden–Popper structure |
| spellingShingle | Nataliia Tarasova Anzhelika Bedarkova Irina Animitsa Ekaterina Abakumova Alexey Trofimov Evgeniya Verinkina Novel Proton-Conducting Layered Perovskites Based on BaLa<sub>2</sub>In<sub>2</sub>O<sub>7</sub> Produced by Cationic Co-Doping Applied Sciences layered perovskite oxygen-ion conductivity proton conductivity hydrogen energy Ruddlesden–Popper structure |
| title | Novel Proton-Conducting Layered Perovskites Based on BaLa<sub>2</sub>In<sub>2</sub>O<sub>7</sub> Produced by Cationic Co-Doping |
| title_full | Novel Proton-Conducting Layered Perovskites Based on BaLa<sub>2</sub>In<sub>2</sub>O<sub>7</sub> Produced by Cationic Co-Doping |
| title_fullStr | Novel Proton-Conducting Layered Perovskites Based on BaLa<sub>2</sub>In<sub>2</sub>O<sub>7</sub> Produced by Cationic Co-Doping |
| title_full_unstemmed | Novel Proton-Conducting Layered Perovskites Based on BaLa<sub>2</sub>In<sub>2</sub>O<sub>7</sub> Produced by Cationic Co-Doping |
| title_short | Novel Proton-Conducting Layered Perovskites Based on BaLa<sub>2</sub>In<sub>2</sub>O<sub>7</sub> Produced by Cationic Co-Doping |
| title_sort | novel proton conducting layered perovskites based on bala sub 2 sub in sub 2 sub o sub 7 sub produced by cationic co doping |
| topic | layered perovskite oxygen-ion conductivity proton conductivity hydrogen energy Ruddlesden–Popper structure |
| url | https://www.mdpi.com/2076-3417/13/6/3449 |
| work_keys_str_mv | AT nataliiatarasova novelprotonconductinglayeredperovskitesbasedonbalasub2subinsub2subosub7subproducedbycationiccodoping AT anzhelikabedarkova novelprotonconductinglayeredperovskitesbasedonbalasub2subinsub2subosub7subproducedbycationiccodoping AT irinaanimitsa novelprotonconductinglayeredperovskitesbasedonbalasub2subinsub2subosub7subproducedbycationiccodoping AT ekaterinaabakumova novelprotonconductinglayeredperovskitesbasedonbalasub2subinsub2subosub7subproducedbycationiccodoping AT alexeytrofimov novelprotonconductinglayeredperovskitesbasedonbalasub2subinsub2subosub7subproducedbycationiccodoping AT evgeniyaverinkina novelprotonconductinglayeredperovskitesbasedonbalasub2subinsub2subosub7subproducedbycationiccodoping |