Study of the structural, electrokinetic and magnetic characteristics of the Er1-xZrxNiSb semiconductor

Peculiarities of the structural, electrokinetic, energetic, and magnetic characteristics of Er1-xZrxNiSb semiconductive solid solution, х=0–0.10, were studied. It was suggested that when Zr (4d25s2) atoms were introduced into the structure of the ErNiSb half-Heusler phase by substitution of Er (5d06...

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Bibliographic Details
Main Authors: V.A. Romaka, Yu. Stadnyk, L. Romaka, V. Krayovskyy, A. Нoryn, P. Klyzub, V. Pashkevych
Format: Article
Language:English
Published: Vasyl Stefanyk Precarpathian National University 2020-12-01
Series:Фізика і хімія твердого тіла
Subjects:
Online Access:https://journals.pnu.edu.ua/index.php/pcss/article/view/4330
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Summary:Peculiarities of the structural, electrokinetic, energetic, and magnetic characteristics of Er1-xZrxNiSb semiconductive solid solution, х=0–0.10, were studied. It was suggested that when Zr (4d25s2) atoms were introduced into the structure of the ErNiSb half-Heusler phase by substitution of Er (5d06s2) atoms in 4a position, Zr atoms can also simultaneously occupy the 4c position of Ni (3d84s2) atoms. As a result, in Er1-xZrxNiSb semiconductor, the structural defects of donor nature in position 4a and ones of acceptor nature in position 4c were generated simultaneously. In this case, in the band gap of Er1-xZrxNiSb, the energy states of impurity donor  and acceptor  bands (donor-acceptor pairs) appear and determine the electrical conductivity mechanism of the semiconductor.
ISSN:1729-4428
2309-8589