Physics of ferroelectric differential capacitance based upon free energy, and implications for use in electronic devices

In this paper, it is shown that for stable, steady state operation of devices typical of microwave and millimeter wave electronics, no negative differential capacitance is possible with conventional thinking. However, it may be possible, with strain engineering of materials, to obtain some if not al...

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Main Author: C. M. Krowne
Format: Article
Language:English
Published: World Scientific Publishing 2019-02-01
Series:Journal of Advanced Dielectrics
Subjects:
Online Access:http://www.worldscientific.com/doi/pdf/10.1142/S2010135X19500024
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author C. M. Krowne
author_facet C. M. Krowne
author_sort C. M. Krowne
collection DOAJ
description In this paper, it is shown that for stable, steady state operation of devices typical of microwave and millimeter wave electronics, no negative differential capacitance is possible with conventional thinking. However, it may be possible, with strain engineering of materials, to obtain some if not all elements of the differential capacitance tensor which are negative. Rigorous derivations are provided based upon analyzing the physics using thermodynamic phenomenological free energy. It should be emphasized that, even with strain engineering, and possible discovery of some negative capacitive elements, stable operation will not be obtained because the thermodynamics precludes it.
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spelling doaj.art-da05639dc2004d4f81024ec9431ed7b92022-12-21T18:39:47ZengWorld Scientific PublishingJournal of Advanced Dielectrics2010-135X2010-13682019-02-01911950002-11950002-1610.1142/S2010135X1950002410.1142/S2010135X19500024Physics of ferroelectric differential capacitance based upon free energy, and implications for use in electronic devicesC. M. Krowne0Electromagnetics Technology Branch, Electronics Science & Technology Division, Naval Research Laboratory, 20375, Washington D.C., USAIn this paper, it is shown that for stable, steady state operation of devices typical of microwave and millimeter wave electronics, no negative differential capacitance is possible with conventional thinking. However, it may be possible, with strain engineering of materials, to obtain some if not all elements of the differential capacitance tensor which are negative. Rigorous derivations are provided based upon analyzing the physics using thermodynamic phenomenological free energy. It should be emphasized that, even with strain engineering, and possible discovery of some negative capacitive elements, stable operation will not be obtained because the thermodynamics precludes it.http://www.worldscientific.com/doi/pdf/10.1142/S2010135X19500024Gibbs and Helmholtz thermodynamic free energiesphenomenological physical modelstresses and strainsnegative and positive differential capacitancespolarizationpermittivity and inverse permittivity tensors
spellingShingle C. M. Krowne
Physics of ferroelectric differential capacitance based upon free energy, and implications for use in electronic devices
Journal of Advanced Dielectrics
Gibbs and Helmholtz thermodynamic free energies
phenomenological physical model
stresses and strains
negative and positive differential capacitances
polarization
permittivity and inverse permittivity tensors
title Physics of ferroelectric differential capacitance based upon free energy, and implications for use in electronic devices
title_full Physics of ferroelectric differential capacitance based upon free energy, and implications for use in electronic devices
title_fullStr Physics of ferroelectric differential capacitance based upon free energy, and implications for use in electronic devices
title_full_unstemmed Physics of ferroelectric differential capacitance based upon free energy, and implications for use in electronic devices
title_short Physics of ferroelectric differential capacitance based upon free energy, and implications for use in electronic devices
title_sort physics of ferroelectric differential capacitance based upon free energy and implications for use in electronic devices
topic Gibbs and Helmholtz thermodynamic free energies
phenomenological physical model
stresses and strains
negative and positive differential capacitances
polarization
permittivity and inverse permittivity tensors
url http://www.worldscientific.com/doi/pdf/10.1142/S2010135X19500024
work_keys_str_mv AT cmkrowne physicsofferroelectricdifferentialcapacitancebaseduponfreeenergyandimplicationsforuseinelectronicdevices