Optical Properties of Blown Films of PA6/MMT Nanocomposites

In this work blown films of polyamide 6 (PA6) nanocomposites were produced at different processing conditions, with the addition of montmorillonite (MMT), pure and surface modified by an organic salt. The films' optical properties were evaluated according to ASTM D-1003 and the results correlat...

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Main Authors: Juliano Marini, Rosario Elida Suman Bretas
Format: Article
Language:English
Published: Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol) 2017-10-01
Series:Materials Research
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392017000700053&tlng=en
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author Juliano Marini
Rosario Elida Suman Bretas
author_facet Juliano Marini
Rosario Elida Suman Bretas
author_sort Juliano Marini
collection DOAJ
description In this work blown films of polyamide 6 (PA6) nanocomposites were produced at different processing conditions, with the addition of montmorillonite (MMT), pure and surface modified by an organic salt. The films' optical properties were evaluated according to ASTM D-1003 and the results correlated with the degree of crystallinity, nanoparticle's dispersion state and processing conditions. It was observed that the thinner the film, the lower the haze and higher the clarity, due to the presence of less internal scattering structures in the direction of the incident light. The PA6 films with the unmodified MMT had the lowest clarity values, due to nanoparticles' agglomeration. The organic modification of the montmorillonite led to its exfoliating through the PA6 matrix, resulting in an optimization of the films' optical properties (decreased haze and increased clarity) when compared to the pure PA6 films.
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spelling doaj.art-da0b874a2a984f48ba62df6fd194feb62022-12-21T17:33:42ZengAssociação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)Materials Research1516-14392017-10-0120suppl 1536010.1590/1980-5373-mr-2017-0280Optical Properties of Blown Films of PA6/MMT NanocompositesJuliano MariniRosario Elida Suman BretasIn this work blown films of polyamide 6 (PA6) nanocomposites were produced at different processing conditions, with the addition of montmorillonite (MMT), pure and surface modified by an organic salt. The films' optical properties were evaluated according to ASTM D-1003 and the results correlated with the degree of crystallinity, nanoparticle's dispersion state and processing conditions. It was observed that the thinner the film, the lower the haze and higher the clarity, due to the presence of less internal scattering structures in the direction of the incident light. The PA6 films with the unmodified MMT had the lowest clarity values, due to nanoparticles' agglomeration. The organic modification of the montmorillonite led to its exfoliating through the PA6 matrix, resulting in an optimization of the films' optical properties (decreased haze and increased clarity) when compared to the pure PA6 films.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392017000700053&tlng=enoptical propertiesnanocompositesblown films
spellingShingle Juliano Marini
Rosario Elida Suman Bretas
Optical Properties of Blown Films of PA6/MMT Nanocomposites
Materials Research
optical properties
nanocomposites
blown films
title Optical Properties of Blown Films of PA6/MMT Nanocomposites
title_full Optical Properties of Blown Films of PA6/MMT Nanocomposites
title_fullStr Optical Properties of Blown Films of PA6/MMT Nanocomposites
title_full_unstemmed Optical Properties of Blown Films of PA6/MMT Nanocomposites
title_short Optical Properties of Blown Films of PA6/MMT Nanocomposites
title_sort optical properties of blown films of pa6 mmt nanocomposites
topic optical properties
nanocomposites
blown films
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392017000700053&tlng=en
work_keys_str_mv AT julianomarini opticalpropertiesofblownfilmsofpa6mmtnanocomposites
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