The Investigation of High Quality PEDOT:PSS Film by Multilayer-Processing and Acid Treatment
In this study, we have investigated the performance of multilayer films of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) treated with one of the perfluorinated carboxylic acids, named trifluoroacetic acid (TFA). According to the increased density of the PEDOT chain under unit a...
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MDPI AG
2017-05-01
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Online Access: | http://www.mdpi.com/1996-1073/10/5/716 |
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author | Po-Wen Sze Kuan-Wei Lee Pin-Chiao Huang Dei-Wei Chou Bing-Siang Kao Chien-Jung Huang |
author_facet | Po-Wen Sze Kuan-Wei Lee Pin-Chiao Huang Dei-Wei Chou Bing-Siang Kao Chien-Jung Huang |
author_sort | Po-Wen Sze |
collection | DOAJ |
description | In this study, we have investigated the performance of multilayer films of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) treated with one of the perfluorinated carboxylic acids, named trifluoroacetic acid (TFA). According to the increased density of the PEDOT chain under unit area conditions, the sheet resistance (Rsq) has improved from 300 to 65 Ω/sq through additional processing of PEDOT:PSS from single layer to multilayer. After the further treatment with TFA, however, the Rsq of the multilayer PEDOT:PSS was enhanced to 45 Ω/sq, leading to the decline of film thickness from 400 to 270 nm. Both conductivity and work function based on X-ray photoelectron spectroscopy results have built a breakthrough by double-processing because of the higher density of conductive PEDOT chains and the increase of 0.4 eV alternatives to typical indium tin oxide substrate, respectively. This improvement is contributed to the development of more effective transparent electrodes. |
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institution | Directory Open Access Journal |
issn | 1996-1073 |
language | English |
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spelling | doaj.art-da4559a19bc642898e11a2c0f134b7ae2022-12-22T02:17:57ZengMDPI AGEnergies1996-10732017-05-0110571610.3390/en10050716en10050716The Investigation of High Quality PEDOT:PSS Film by Multilayer-Processing and Acid TreatmentPo-Wen Sze0Kuan-Wei Lee1Pin-Chiao Huang2Dei-Wei Chou3Bing-Siang Kao4Chien-Jung Huang5Department of Electrical Engineering, Kao-Yuan University, Kaohsiung 821, TaiwanDepartment of Electronic Engineering, I-Shou University, Kaohsiung 84008, TaiwanDepartment of Electrical Engineering, National Chung Hsing University, Taichung 40227, TaiwanDepartment of Aviation & Communication Electronics, Air Force Institute of Technology, Kaohsiung 820, TaiwanDepartment of Applied Physics, National University of Kaohsiung, Kaohsiung 81148, TaiwanDepartment of Applied Physics, National University of Kaohsiung, Kaohsiung 81148, TaiwanIn this study, we have investigated the performance of multilayer films of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) treated with one of the perfluorinated carboxylic acids, named trifluoroacetic acid (TFA). According to the increased density of the PEDOT chain under unit area conditions, the sheet resistance (Rsq) has improved from 300 to 65 Ω/sq through additional processing of PEDOT:PSS from single layer to multilayer. After the further treatment with TFA, however, the Rsq of the multilayer PEDOT:PSS was enhanced to 45 Ω/sq, leading to the decline of film thickness from 400 to 270 nm. Both conductivity and work function based on X-ray photoelectron spectroscopy results have built a breakthrough by double-processing because of the higher density of conductive PEDOT chains and the increase of 0.4 eV alternatives to typical indium tin oxide substrate, respectively. This improvement is contributed to the development of more effective transparent electrodes.http://www.mdpi.com/1996-1073/10/5/716double processingorganic solar cellstransparent electrodesheet resistance |
spellingShingle | Po-Wen Sze Kuan-Wei Lee Pin-Chiao Huang Dei-Wei Chou Bing-Siang Kao Chien-Jung Huang The Investigation of High Quality PEDOT:PSS Film by Multilayer-Processing and Acid Treatment Energies double processing organic solar cells transparent electrode sheet resistance |
title | The Investigation of High Quality PEDOT:PSS Film by Multilayer-Processing and Acid Treatment |
title_full | The Investigation of High Quality PEDOT:PSS Film by Multilayer-Processing and Acid Treatment |
title_fullStr | The Investigation of High Quality PEDOT:PSS Film by Multilayer-Processing and Acid Treatment |
title_full_unstemmed | The Investigation of High Quality PEDOT:PSS Film by Multilayer-Processing and Acid Treatment |
title_short | The Investigation of High Quality PEDOT:PSS Film by Multilayer-Processing and Acid Treatment |
title_sort | investigation of high quality pedot pss film by multilayer processing and acid treatment |
topic | double processing organic solar cells transparent electrode sheet resistance |
url | http://www.mdpi.com/1996-1073/10/5/716 |
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