The Investigation of High Quality PEDOT:PSS Film by Multilayer-Processing and Acid Treatment

In this study, we have investigated the performance of multilayer films of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) treated with one of the perfluorinated carboxylic acids, named trifluoroacetic acid (TFA). According to the increased density of the PEDOT chain under unit a...

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Main Authors: Po-Wen Sze, Kuan-Wei Lee, Pin-Chiao Huang, Dei-Wei Chou, Bing-Siang Kao, Chien-Jung Huang
Format: Article
Language:English
Published: MDPI AG 2017-05-01
Series:Energies
Subjects:
Online Access:http://www.mdpi.com/1996-1073/10/5/716
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author Po-Wen Sze
Kuan-Wei Lee
Pin-Chiao Huang
Dei-Wei Chou
Bing-Siang Kao
Chien-Jung Huang
author_facet Po-Wen Sze
Kuan-Wei Lee
Pin-Chiao Huang
Dei-Wei Chou
Bing-Siang Kao
Chien-Jung Huang
author_sort Po-Wen Sze
collection DOAJ
description In this study, we have investigated the performance of multilayer films of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) treated with one of the perfluorinated carboxylic acids, named trifluoroacetic acid (TFA). According to the increased density of the PEDOT chain under unit area conditions, the sheet resistance (Rsq) has improved from 300 to 65 Ω/sq through additional processing of PEDOT:PSS from single layer to multilayer. After the further treatment with TFA, however, the Rsq of the multilayer PEDOT:PSS was enhanced to 45 Ω/sq, leading to the decline of film thickness from 400 to 270 nm. Both conductivity and work function based on X-ray photoelectron spectroscopy results have built a breakthrough by double-processing because of the higher density of conductive PEDOT chains and the increase of 0.4 eV alternatives to typical indium tin oxide substrate, respectively. This improvement is contributed to the development of more effective transparent electrodes.
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spelling doaj.art-da4559a19bc642898e11a2c0f134b7ae2022-12-22T02:17:57ZengMDPI AGEnergies1996-10732017-05-0110571610.3390/en10050716en10050716The Investigation of High Quality PEDOT:PSS Film by Multilayer-Processing and Acid TreatmentPo-Wen Sze0Kuan-Wei Lee1Pin-Chiao Huang2Dei-Wei Chou3Bing-Siang Kao4Chien-Jung Huang5Department of Electrical Engineering, Kao-Yuan University, Kaohsiung 821, TaiwanDepartment of Electronic Engineering, I-Shou University, Kaohsiung 84008, TaiwanDepartment of Electrical Engineering, National Chung Hsing University, Taichung 40227, TaiwanDepartment of Aviation & Communication Electronics, Air Force Institute of Technology, Kaohsiung 820, TaiwanDepartment of Applied Physics, National University of Kaohsiung, Kaohsiung 81148, TaiwanDepartment of Applied Physics, National University of Kaohsiung, Kaohsiung 81148, TaiwanIn this study, we have investigated the performance of multilayer films of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) treated with one of the perfluorinated carboxylic acids, named trifluoroacetic acid (TFA). According to the increased density of the PEDOT chain under unit area conditions, the sheet resistance (Rsq) has improved from 300 to 65 Ω/sq through additional processing of PEDOT:PSS from single layer to multilayer. After the further treatment with TFA, however, the Rsq of the multilayer PEDOT:PSS was enhanced to 45 Ω/sq, leading to the decline of film thickness from 400 to 270 nm. Both conductivity and work function based on X-ray photoelectron spectroscopy results have built a breakthrough by double-processing because of the higher density of conductive PEDOT chains and the increase of 0.4 eV alternatives to typical indium tin oxide substrate, respectively. This improvement is contributed to the development of more effective transparent electrodes.http://www.mdpi.com/1996-1073/10/5/716double processingorganic solar cellstransparent electrodesheet resistance
spellingShingle Po-Wen Sze
Kuan-Wei Lee
Pin-Chiao Huang
Dei-Wei Chou
Bing-Siang Kao
Chien-Jung Huang
The Investigation of High Quality PEDOT:PSS Film by Multilayer-Processing and Acid Treatment
Energies
double processing
organic solar cells
transparent electrode
sheet resistance
title The Investigation of High Quality PEDOT:PSS Film by Multilayer-Processing and Acid Treatment
title_full The Investigation of High Quality PEDOT:PSS Film by Multilayer-Processing and Acid Treatment
title_fullStr The Investigation of High Quality PEDOT:PSS Film by Multilayer-Processing and Acid Treatment
title_full_unstemmed The Investigation of High Quality PEDOT:PSS Film by Multilayer-Processing and Acid Treatment
title_short The Investigation of High Quality PEDOT:PSS Film by Multilayer-Processing and Acid Treatment
title_sort investigation of high quality pedot pss film by multilayer processing and acid treatment
topic double processing
organic solar cells
transparent electrode
sheet resistance
url http://www.mdpi.com/1996-1073/10/5/716
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