Effects of precursor concentration and reaction time on sonochemically synthesized ZnO nanoparticles
The sonochemical reaction between Zn(NO3)2 and hexamethylenetetramine (HMT) resulted in different products depending on amounts of Zn(II) cations in the aqueous solution. Crystalline phase pure ZnO nanoparticles were obtained by using 0.05 M Zn(NO3)2-HMT. This single phase was formed by low power so...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)
2013-12-01
|
| Series: | Materials Research |
| Subjects: | |
| Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392014000200018&tlng=en |
| _version_ | 1798015604522745856 |
|---|---|
| author | Chat Pholnak Chitnarong Sirisathitkul Sumetha Suwanboon David James Harding |
| author_facet | Chat Pholnak Chitnarong Sirisathitkul Sumetha Suwanboon David James Harding |
| author_sort | Chat Pholnak |
| collection | DOAJ |
| description | The sonochemical reaction between Zn(NO3)2 and hexamethylenetetramine (HMT) resulted in different products depending on amounts of Zn(II) cations in the aqueous solution. Crystalline phase pure ZnO nanoparticles were obtained by using 0.05 M Zn(NO3)2-HMT. This single phase was formed by low power sonication for 20 min in an ultrasonic bath at ambient conditions and its morphology did not change for the next 60 min. Higher concentrations of precursors (0.1 and 0.5 M) led to a mixture of zinc compounds including plate-like Zn5(OH)8(NO3)2(H2O). In contrast, a mixed phase ZnO/Zn5(OH)6(CO3)2 and a single phase Zn5(OH)6(CO3)2 were formed when the precursor concentrations were decreased to 0.01 and 0.005 M, respectively. The resulting infrared absorption and ultraviolet/visible emission were dependent on the phases and defects in these zinc compounds. |
| first_indexed | 2024-04-11T15:36:12Z |
| format | Article |
| id | doaj.art-da570f88a98448808ce43a830e0d9a77 |
| institution | Directory Open Access Journal |
| issn | 1516-1439 |
| language | English |
| last_indexed | 2024-04-11T15:36:12Z |
| publishDate | 2013-12-01 |
| publisher | Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol) |
| record_format | Article |
| series | Materials Research |
| spelling | doaj.art-da570f88a98448808ce43a830e0d9a772022-12-22T04:15:57ZengAssociação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)Materials Research1516-14392013-12-0117240541110.1590/S1516-14392013005000192Effects of precursor concentration and reaction time on sonochemically synthesized ZnO nanoparticlesChat Pholnak0Chitnarong Sirisathitkul1Sumetha Suwanboon2David James Harding3Walailak UniversityWalailak UniversityPrince of Songkla UniversityWalailak UniversityThe sonochemical reaction between Zn(NO3)2 and hexamethylenetetramine (HMT) resulted in different products depending on amounts of Zn(II) cations in the aqueous solution. Crystalline phase pure ZnO nanoparticles were obtained by using 0.05 M Zn(NO3)2-HMT. This single phase was formed by low power sonication for 20 min in an ultrasonic bath at ambient conditions and its morphology did not change for the next 60 min. Higher concentrations of precursors (0.1 and 0.5 M) led to a mixture of zinc compounds including plate-like Zn5(OH)8(NO3)2(H2O). In contrast, a mixed phase ZnO/Zn5(OH)6(CO3)2 and a single phase Zn5(OH)6(CO3)2 were formed when the precursor concentrations were decreased to 0.01 and 0.005 M, respectively. The resulting infrared absorption and ultraviolet/visible emission were dependent on the phases and defects in these zinc compounds.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392014000200018&tlng=enZnOFTIRphotoluminescencesonochemistry |
| spellingShingle | Chat Pholnak Chitnarong Sirisathitkul Sumetha Suwanboon David James Harding Effects of precursor concentration and reaction time on sonochemically synthesized ZnO nanoparticles Materials Research ZnO FTIR photoluminescence sonochemistry |
| title | Effects of precursor concentration and reaction time on sonochemically synthesized ZnO nanoparticles |
| title_full | Effects of precursor concentration and reaction time on sonochemically synthesized ZnO nanoparticles |
| title_fullStr | Effects of precursor concentration and reaction time on sonochemically synthesized ZnO nanoparticles |
| title_full_unstemmed | Effects of precursor concentration and reaction time on sonochemically synthesized ZnO nanoparticles |
| title_short | Effects of precursor concentration and reaction time on sonochemically synthesized ZnO nanoparticles |
| title_sort | effects of precursor concentration and reaction time on sonochemically synthesized zno nanoparticles |
| topic | ZnO FTIR photoluminescence sonochemistry |
| url | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392014000200018&tlng=en |
| work_keys_str_mv | AT chatpholnak effectsofprecursorconcentrationandreactiontimeonsonochemicallysynthesizedznonanoparticles AT chitnarongsirisathitkul effectsofprecursorconcentrationandreactiontimeonsonochemicallysynthesizedznonanoparticles AT sumethasuwanboon effectsofprecursorconcentrationandreactiontimeonsonochemicallysynthesizedznonanoparticles AT davidjamesharding effectsofprecursorconcentrationandreactiontimeonsonochemicallysynthesizedznonanoparticles |