Iridium-catalyzed asymmetric ring-opening reactions of oxabicyclic alkenes with secondary amine nucleophiles

Iridium-catalyzed asymmetric ring-opening reactions of oxabicyclic alkenes with secondary amine nucleophiles

Iridium-catalyzed asymmetric ring-opening reactions of oxabicyclic alkenes with various aliphatic and aromatic secondary amines are reported for the first time. The reaction gave the corresponding trans-1,2-dihydronaphthalenol derivatives in good yields with moderate enantioselectivities in the pres...

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Bibliographic Details
Main Authors: Dingqiao Yang, Ping Hu, Yuhua Long, Yujuan Wu, Heping Zeng, Hui Wang, Xiongjun Zuo
Format: Article
Language:English
Published: Beilstein-Institut 2009-10-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
chiral bisphosphine ligand
iridium catalyst
oxabicyclic alkenes
ring-opening reaction
Online Access:https://doi.org/10.3762/bjoc.5.53

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