Summary: | The hole transport material (HTM)-free perovskite solar cells (PSCs) have attracted widespread interest due to enhanced stability and lowered cost as compared to the sandwich-type PSCs with an organic hole conductor. For the absorber layer, CsPbI _3 has become a competitive candidate for its good chemical-components stability, excellent optoelectronic properties and most proper bandgap among inorganic halide perovskites. However, the power conversion efficiency of CsPbI _3 -based HTM-free PSCs is still much inferior to that of conventional ones. In this work, an all-inorganic-perovskite-heterojunction CsPbI _3 /CsSnI _3 is proposed as the absorber and the HTM-free CsPbI _3 /CsSnI _3 PSCs are investigated systematically through numerical simulation by using SCAPS-1D. Compared with the HTM-free PSCs employing a single CsPbI _3 absorbing layer, the HTM-free CsPbI _3 /CsSnI _3 PSCs have the extended absorption range and enhanced performance. The best cell efficiency is increased from 15.60% to 19.99% and from 13.87% to 19.59% for the cell with a back-front Au electrode and a back-front C electrode, respectively. It reveals that for the HTM-free CsPbI _3 /CsSnI _3 heterojunction cells, C is a good choice for back-front electrode as it can achieve desirable cell performance with improved stability and lowered fabrication cost. These results indicate that the proposed HTM-free CsPbI _3 /CsSnI _3 heterojunction cells are promising for photovoltaic applications.
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