Optimizing soil washing remediation of mercury contaminated soil using various washing solutions and solid/liquid ratios

Most of the artisanal and small-scale gold miners in Indonesia as in the case of those who are in Banten Province, still use the amalgamation process in the gold extraction process. Therefore, mercury contamination could not be avoided. As a result, it was found that the concentration of mercury-con...

Full description

Bibliographic Details
Main Authors: Effendi Agus Jatnika, Lestari Vina, Irsyad Mohammad
Format: Article
Language:English
Published: EDP Sciences 2020-01-01
Series:E3S Web of Conferences
Subjects:
Online Access:https://www.e3s-conferences.org/articles/e3sconf/pdf/2020/08/e3sconf_etmc2020_05004.pdf
_version_ 1818827643735244800
author Effendi Agus Jatnika
Lestari Vina
Irsyad Mohammad
author_facet Effendi Agus Jatnika
Lestari Vina
Irsyad Mohammad
author_sort Effendi Agus Jatnika
collection DOAJ
description Most of the artisanal and small-scale gold miners in Indonesia as in the case of those who are in Banten Province, still use the amalgamation process in the gold extraction process. Therefore, mercury contamination could not be avoided. As a result, it was found that the concentration of mercury-contaminated soil in Lebak, Banten Province was detected as high as 136,9 mg/kg. Since the contamination process occurred for a long time, making the formation and mobility of complex mercury in soil increased by time. Soil washing is one remediation technology that can be applied in the recovery of mercury-contaminated soil. This study aims to determine the optimum conditions of the soil washing process: effect of pH, the concentration of washing solutions and ratio of solid/liquid. Furthermore, the value of the distribution coefficient, desorption of mercury in the soil and fractionation of mercury in the soil were also observed. Potassium Iodide was found to be the best washing solution among others used in this study. The optimum condition was obtained at pH 2, the concentration of washing solution at 0.25 M and the solid/liquid ratio of 1:15. Under these conditions, mercury desorption efficiency reached 86.9% with the value of the distribution coefficient of 0.185. Mercury fractionation analysis in the contaminated soil showed that the mobile > semi-mobile > non-mobile fractions. Potassium iodide was able to desorb at about 84% of mobile fractions, 97% of semi-mobile and 25% non-mobile mercury.
first_indexed 2024-12-19T00:46:49Z
format Article
id doaj.art-dad6a37a6f1f49cb9f928920cd14be73
institution Directory Open Access Journal
issn 2267-1242
language English
last_indexed 2024-12-19T00:46:49Z
publishDate 2020-01-01
publisher EDP Sciences
record_format Article
series E3S Web of Conferences
spelling doaj.art-dad6a37a6f1f49cb9f928920cd14be732022-12-21T20:44:15ZengEDP SciencesE3S Web of Conferences2267-12422020-01-011480500410.1051/e3sconf/202014805004e3sconf_etmc2020_05004Optimizing soil washing remediation of mercury contaminated soil using various washing solutions and solid/liquid ratiosEffendi Agus Jatnika0Lestari Vina1Irsyad Mohammad2Water & Wastewater Research Group, Faculty of Civil & Environmental Engineering – ITBWater & Wastewater Research Group, Faculty of Civil & Environmental Engineering – ITBAir & Solid Waste Management Research Group, Faculty of Civil & Environmental Engineering – ITBMost of the artisanal and small-scale gold miners in Indonesia as in the case of those who are in Banten Province, still use the amalgamation process in the gold extraction process. Therefore, mercury contamination could not be avoided. As a result, it was found that the concentration of mercury-contaminated soil in Lebak, Banten Province was detected as high as 136,9 mg/kg. Since the contamination process occurred for a long time, making the formation and mobility of complex mercury in soil increased by time. Soil washing is one remediation technology that can be applied in the recovery of mercury-contaminated soil. This study aims to determine the optimum conditions of the soil washing process: effect of pH, the concentration of washing solutions and ratio of solid/liquid. Furthermore, the value of the distribution coefficient, desorption of mercury in the soil and fractionation of mercury in the soil were also observed. Potassium Iodide was found to be the best washing solution among others used in this study. The optimum condition was obtained at pH 2, the concentration of washing solution at 0.25 M and the solid/liquid ratio of 1:15. Under these conditions, mercury desorption efficiency reached 86.9% with the value of the distribution coefficient of 0.185. Mercury fractionation analysis in the contaminated soil showed that the mobile > semi-mobile > non-mobile fractions. Potassium iodide was able to desorb at about 84% of mobile fractions, 97% of semi-mobile and 25% non-mobile mercury.https://www.e3s-conferences.org/articles/e3sconf/pdf/2020/08/e3sconf_etmc2020_05004.pdfsoil washingmercurydesorptiondistribution coefficientfractionation
spellingShingle Effendi Agus Jatnika
Lestari Vina
Irsyad Mohammad
Optimizing soil washing remediation of mercury contaminated soil using various washing solutions and solid/liquid ratios
E3S Web of Conferences
soil washing
mercury
desorption
distribution coefficient
fractionation
title Optimizing soil washing remediation of mercury contaminated soil using various washing solutions and solid/liquid ratios
title_full Optimizing soil washing remediation of mercury contaminated soil using various washing solutions and solid/liquid ratios
title_fullStr Optimizing soil washing remediation of mercury contaminated soil using various washing solutions and solid/liquid ratios
title_full_unstemmed Optimizing soil washing remediation of mercury contaminated soil using various washing solutions and solid/liquid ratios
title_short Optimizing soil washing remediation of mercury contaminated soil using various washing solutions and solid/liquid ratios
title_sort optimizing soil washing remediation of mercury contaminated soil using various washing solutions and solid liquid ratios
topic soil washing
mercury
desorption
distribution coefficient
fractionation
url https://www.e3s-conferences.org/articles/e3sconf/pdf/2020/08/e3sconf_etmc2020_05004.pdf
work_keys_str_mv AT effendiagusjatnika optimizingsoilwashingremediationofmercurycontaminatedsoilusingvariouswashingsolutionsandsolidliquidratios
AT lestarivina optimizingsoilwashingremediationofmercurycontaminatedsoilusingvariouswashingsolutionsandsolidliquidratios
AT irsyadmohammad optimizingsoilwashingremediationofmercurycontaminatedsoilusingvariouswashingsolutionsandsolidliquidratios