Redução catalítica seletiva de óxidos de nitrogênio sobre hematita contendo cobre The selective catalytic reduction of no over copper-containing hematite
<abstract language="eng">The activity of copper-doped hematite in the SCR with propane, in the presence of oxygen, was evaluated in this work. It was found that copper sulfate led to the production of solids with different specific surface areas depending on the amount of copper. The...
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Language: | English |
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Sociedade Brasileira de Química
2007-06-01
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Series: | Química Nova |
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Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422007000300021 |
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author | Hadma Sousa Ferreira Soraia Jesus Oliveira Maria do Carmo Rangel Ernesto A. Urquieta-González Leandro Martins José Luís Garcia Fierro Sérgio G. Marchetti |
author_facet | Hadma Sousa Ferreira Soraia Jesus Oliveira Maria do Carmo Rangel Ernesto A. Urquieta-González Leandro Martins José Luís Garcia Fierro Sérgio G. Marchetti |
author_sort | Hadma Sousa Ferreira |
collection | DOAJ |
description | <abstract language="eng">The activity of copper-doped hematite in the SCR with propane, in the presence of oxygen, was evaluated in this work. It was found that copper sulfate led to the production of solids with different specific surface areas depending on the amount of copper. The sulfur and copper species were mainly located on the surface. The copper-containing catalysts were more active in the reduction of nitrogen oxides and less active in the propane oxidation as compared to pure hematite. This behavior was assigned to an association of both sulfur and copper species to produce new sites active for NO reduction. |
first_indexed | 2024-12-23T20:26:55Z |
format | Article |
id | doaj.art-dadc4038222644e09f308dca43f701dc |
institution | Directory Open Access Journal |
issn | 0100-4042 1678-7064 |
language | English |
last_indexed | 2024-12-23T20:26:55Z |
publishDate | 2007-06-01 |
publisher | Sociedade Brasileira de Química |
record_format | Article |
series | Química Nova |
spelling | doaj.art-dadc4038222644e09f308dca43f701dc2022-12-21T17:32:22ZengSociedade Brasileira de QuímicaQuímica Nova0100-40421678-70642007-06-0130361161510.1590/S0100-40422007000300021Redução catalítica seletiva de óxidos de nitrogênio sobre hematita contendo cobre The selective catalytic reduction of no over copper-containing hematiteHadma Sousa FerreiraSoraia Jesus OliveiraMaria do Carmo RangelErnesto A. Urquieta-GonzálezLeandro MartinsJosé Luís Garcia FierroSérgio G. Marchetti<abstract language="eng">The activity of copper-doped hematite in the SCR with propane, in the presence of oxygen, was evaluated in this work. It was found that copper sulfate led to the production of solids with different specific surface areas depending on the amount of copper. The sulfur and copper species were mainly located on the surface. The copper-containing catalysts were more active in the reduction of nitrogen oxides and less active in the propane oxidation as compared to pure hematite. This behavior was assigned to an association of both sulfur and copper species to produce new sites active for NO reduction.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422007000300021hematitecoppernitrogen oxides |
spellingShingle | Hadma Sousa Ferreira Soraia Jesus Oliveira Maria do Carmo Rangel Ernesto A. Urquieta-González Leandro Martins José Luís Garcia Fierro Sérgio G. Marchetti Redução catalítica seletiva de óxidos de nitrogênio sobre hematita contendo cobre The selective catalytic reduction of no over copper-containing hematite Química Nova hematite copper nitrogen oxides |
title | Redução catalítica seletiva de óxidos de nitrogênio sobre hematita contendo cobre The selective catalytic reduction of no over copper-containing hematite |
title_full | Redução catalítica seletiva de óxidos de nitrogênio sobre hematita contendo cobre The selective catalytic reduction of no over copper-containing hematite |
title_fullStr | Redução catalítica seletiva de óxidos de nitrogênio sobre hematita contendo cobre The selective catalytic reduction of no over copper-containing hematite |
title_full_unstemmed | Redução catalítica seletiva de óxidos de nitrogênio sobre hematita contendo cobre The selective catalytic reduction of no over copper-containing hematite |
title_short | Redução catalítica seletiva de óxidos de nitrogênio sobre hematita contendo cobre The selective catalytic reduction of no over copper-containing hematite |
title_sort | reducao catalitica seletiva de oxidos de nitrogenio sobre hematita contendo cobre the selective catalytic reduction of no over copper containing hematite |
topic | hematite copper nitrogen oxides |
url | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422007000300021 |
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