pH-based colorimetric detection of monofunctional aldehydes in liquid and gas phases

An ammonium chloride–Congo red (NH4Cl-CR) solution is presented as a potential sensing solution for aldehydes. Monofunctional aldehydes such as formaldehyde, acetaldehyde, benzaldehyde, and isobutyraldehyde caused changes in the pH of the sensing solution, producing a color transition from red-orang...

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Main Authors: dela Cruz Ma. Carmela P., Organo Voltaire G.
Format: Article
Language:English
Published: De Gruyter 2024-04-01
Series:Open Chemistry
Subjects:
Online Access:https://doi.org/10.1515/chem-2024-0011
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author dela Cruz Ma. Carmela P.
Organo Voltaire G.
author_facet dela Cruz Ma. Carmela P.
Organo Voltaire G.
author_sort dela Cruz Ma. Carmela P.
collection DOAJ
description An ammonium chloride–Congo red (NH4Cl-CR) solution is presented as a potential sensing solution for aldehydes. Monofunctional aldehydes such as formaldehyde, acetaldehyde, benzaldehyde, and isobutyraldehyde caused changes in the pH of the sensing solution, producing a color transition from red-orange to violet to blue. This distinguished them from the other compounds, thereby acting as a qualitative test for the functional group. The NH4Cl-CR solution was also employed in making filter paper-based and silica gel-based sensors for formaldehyde and acetaldehyde vapors. These sensors responded positively towards the aldehyde gases through a color transition from pink to blue. The NH4Cl-CR mixture provides a simple and easy-to-handle reagent for the detection of both liquid and gaseous aldehydes which has potential applications in environmental monitoring.
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spelling doaj.art-dae1111961914d28958a55d50992a2112024-04-08T07:35:36ZengDe GruyterOpen Chemistry2391-54202024-04-01221283410.1515/chem-2024-0011pH-based colorimetric detection of monofunctional aldehydes in liquid and gas phasesdela Cruz Ma. Carmela P.0Organo Voltaire G.1Department of Physical Sciences and Mathematics, College of Arts and Sciences, University of the Philippines, Manila 1000, PhilippinesDepartment of Physical Sciences and Mathematics, College of Arts and Sciences, University of the Philippines, Manila 1000, PhilippinesAn ammonium chloride–Congo red (NH4Cl-CR) solution is presented as a potential sensing solution for aldehydes. Monofunctional aldehydes such as formaldehyde, acetaldehyde, benzaldehyde, and isobutyraldehyde caused changes in the pH of the sensing solution, producing a color transition from red-orange to violet to blue. This distinguished them from the other compounds, thereby acting as a qualitative test for the functional group. The NH4Cl-CR solution was also employed in making filter paper-based and silica gel-based sensors for formaldehyde and acetaldehyde vapors. These sensors responded positively towards the aldehyde gases through a color transition from pink to blue. The NH4Cl-CR mixture provides a simple and easy-to-handle reagent for the detection of both liquid and gaseous aldehydes which has potential applications in environmental monitoring.https://doi.org/10.1515/chem-2024-0011ph indicatorcolorimetricaldehydesformaldehydepaper stripscongo red
spellingShingle dela Cruz Ma. Carmela P.
Organo Voltaire G.
pH-based colorimetric detection of monofunctional aldehydes in liquid and gas phases
Open Chemistry
ph indicator
colorimetric
aldehydes
formaldehyde
paper strips
congo red
title pH-based colorimetric detection of monofunctional aldehydes in liquid and gas phases
title_full pH-based colorimetric detection of monofunctional aldehydes in liquid and gas phases
title_fullStr pH-based colorimetric detection of monofunctional aldehydes in liquid and gas phases
title_full_unstemmed pH-based colorimetric detection of monofunctional aldehydes in liquid and gas phases
title_short pH-based colorimetric detection of monofunctional aldehydes in liquid and gas phases
title_sort ph based colorimetric detection of monofunctional aldehydes in liquid and gas phases
topic ph indicator
colorimetric
aldehydes
formaldehyde
paper strips
congo red
url https://doi.org/10.1515/chem-2024-0011
work_keys_str_mv AT delacruzmacarmelap phbasedcolorimetricdetectionofmonofunctionalaldehydesinliquidandgasphases
AT organovoltaireg phbasedcolorimetricdetectionofmonofunctionalaldehydesinliquidandgasphases