(2E)-2-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-N-cyclohexylhydrazinecarbothioamide
The title compound, C15H20BrN3O2S, crystallizes in the thioamide form and adopts an E,E conformation with respect to the azomethine and hydrazinic bonds, respectively. The molecules are paired through N—H...O and O—H...S hydrogen bonds, leading to the formation of centros...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812007039 |
| _version_ | 1798024373770125312 |
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| author | Jinsa Mary Jacob M. R. Prathapachandra Kurup |
| author_facet | Jinsa Mary Jacob M. R. Prathapachandra Kurup |
| author_sort | Jinsa Mary Jacob |
| collection | DOAJ |
| description | The title compound, C15H20BrN3O2S, crystallizes in the thioamide form and adopts an E,E conformation with respect to the azomethine and hydrazinic bonds, respectively. The molecules are paired through N—H...O and O—H...S hydrogen bonds, leading to the formation of centrosymmetric dimers in the crystal. These dimers are stacked along the a axis and are interconnected through N—H...S hydrogen bonds to generate polymeric chains. The structure also features C—H...π interactions. An intramolecular O—H...O bond is also present. |
| first_indexed | 2024-04-11T18:02:33Z |
| format | Article |
| id | doaj.art-daf053c5bac943fe822b283b878d91e4 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T18:02:33Z |
| publishDate | 2012-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-daf053c5bac943fe822b283b878d91e42022-12-22T04:10:27ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-03-01683o836o83710.1107/S1600536812007039(2E)-2-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-N-cyclohexylhydrazinecarbothioamideJinsa Mary JacobM. R. Prathapachandra KurupThe title compound, C15H20BrN3O2S, crystallizes in the thioamide form and adopts an E,E conformation with respect to the azomethine and hydrazinic bonds, respectively. The molecules are paired through N—H...O and O—H...S hydrogen bonds, leading to the formation of centrosymmetric dimers in the crystal. These dimers are stacked along the a axis and are interconnected through N—H...S hydrogen bonds to generate polymeric chains. The structure also features C—H...π interactions. An intramolecular O—H...O bond is also present.http://scripts.iucr.org/cgi-bin/paper?S1600536812007039 |
| spellingShingle | Jinsa Mary Jacob M. R. Prathapachandra Kurup (2E)-2-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-N-cyclohexylhydrazinecarbothioamide Acta Crystallographica Section E |
| title | (2E)-2-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-N-cyclohexylhydrazinecarbothioamide |
| title_full | (2E)-2-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-N-cyclohexylhydrazinecarbothioamide |
| title_fullStr | (2E)-2-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-N-cyclohexylhydrazinecarbothioamide |
| title_full_unstemmed | (2E)-2-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-N-cyclohexylhydrazinecarbothioamide |
| title_short | (2E)-2-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-N-cyclohexylhydrazinecarbothioamide |
| title_sort | 2e 2 5 bromo 2 hydroxy 3 methoxybenzylidene n cyclohexylhydrazinecarbothioamide |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812007039 |
| work_keys_str_mv | AT jinsamaryjacob 2e25bromo2hydroxy3methoxybenzylidenencyclohexylhydrazinecarbothioamide AT mrprathapachandrakurup 2e25bromo2hydroxy3methoxybenzylidenencyclohexylhydrazinecarbothioamide |