Effects of Pine Rosin on the Degradation of Mechanical Performance in Flax-Reinforced Polymeric Composites after Soil Burial at Low Temperatures

The effect of pine rosin (RO) was studied relative to the biodegradation of poly(lactic acid) (PLA), starch-based polymer (Mater-Bi), and PLA-flax composites. It was hypothesized that rosin can alter – either speed up or slow down – biodegradation in plastics depending on the specific species of pol...

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Main Authors: Lauri Jutila, Rama Layek, Farzin Javanshour, Lijo George, Essi Sarlin, Mikko Kanerva
Format: Article
Language:English
Published: North Carolina State University 2022-12-01
Series:BioResources
Subjects:
Online Access:https://ojs.cnr.ncsu.edu/index.php/BRJ/article/view/22300
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author Lauri Jutila
Rama Layek
Farzin Javanshour
Lijo George
Essi Sarlin
Mikko Kanerva
author_facet Lauri Jutila
Rama Layek
Farzin Javanshour
Lijo George
Essi Sarlin
Mikko Kanerva
author_sort Lauri Jutila
collection DOAJ
description The effect of pine rosin (RO) was studied relative to the biodegradation of poly(lactic acid) (PLA), starch-based polymer (Mater-Bi), and PLA-flax composites. It was hypothesized that rosin can alter – either speed up or slow down – biodegradation in plastics depending on the specific species of polymer. The biodegradation was brought about by soil burial over 56 days. First, the effect of rosin was studied alone without any effects of soil burial. Second, the effects of soil burial were studied in terms of biodegradation. The results showed that RO increased the degree of crystallinity (+100%) and Young’s modulus (+14%) of PLA. For Mater-Bi, RO decreased the strength by 22% and led to brittleness (56% lower ultimate strain) of the specimens. After 56 days of soil burial, the presence of RO in PLA was found to speed up the degradation when compared to pure PLA (the decrease of strength was 9.3% and 6.6%, respectively). For Mater-Bi, the RO blending led to 2.1% slower biodegradation of strength during 56 days of soil burial. The effect of RO, in terms of affecting the biodegradation, was comparable in flax-reinforced and non-reinforced PLA. The strength of the fiber-matrix bonding remained equal for RO-impregnated fibers compared to the as-received flax fibers.
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spelling doaj.art-daf0a3a86d22473d97b6b561de9896342023-06-26T18:43:50ZengNorth Carolina State UniversityBioResources1930-21262022-12-01181899925302Effects of Pine Rosin on the Degradation of Mechanical Performance in Flax-Reinforced Polymeric Composites after Soil Burial at Low TemperaturesLauri Jutila0Rama Layek1Farzin Javanshour2Lijo George3Essi Sarlin4Mikko Kanerva5Unit of Materials Science and Environmental Engineering, Tampere UniversitySeparation Sciences Department, LUT UniversityMaterials Science and Environmental Engineering, Tampere UniversityMaterials Science and Environmental Engineering, Tampere UniversityMaterials Science and Environmental Engineering, Tampere UniversityMaterials Science and Environmental Engineering, Tampere UniversityThe effect of pine rosin (RO) was studied relative to the biodegradation of poly(lactic acid) (PLA), starch-based polymer (Mater-Bi), and PLA-flax composites. It was hypothesized that rosin can alter – either speed up or slow down – biodegradation in plastics depending on the specific species of polymer. The biodegradation was brought about by soil burial over 56 days. First, the effect of rosin was studied alone without any effects of soil burial. Second, the effects of soil burial were studied in terms of biodegradation. The results showed that RO increased the degree of crystallinity (+100%) and Young’s modulus (+14%) of PLA. For Mater-Bi, RO decreased the strength by 22% and led to brittleness (56% lower ultimate strain) of the specimens. After 56 days of soil burial, the presence of RO in PLA was found to speed up the degradation when compared to pure PLA (the decrease of strength was 9.3% and 6.6%, respectively). For Mater-Bi, the RO blending led to 2.1% slower biodegradation of strength during 56 days of soil burial. The effect of RO, in terms of affecting the biodegradation, was comparable in flax-reinforced and non-reinforced PLA. The strength of the fiber-matrix bonding remained equal for RO-impregnated fibers compared to the as-received flax fibers.https://ojs.cnr.ncsu.edu/index.php/BRJ/article/view/22300compositeflaxrosinsoil burialinterface
spellingShingle Lauri Jutila
Rama Layek
Farzin Javanshour
Lijo George
Essi Sarlin
Mikko Kanerva
Effects of Pine Rosin on the Degradation of Mechanical Performance in Flax-Reinforced Polymeric Composites after Soil Burial at Low Temperatures
BioResources
composite
flax
rosin
soil burial
interface
title Effects of Pine Rosin on the Degradation of Mechanical Performance in Flax-Reinforced Polymeric Composites after Soil Burial at Low Temperatures
title_full Effects of Pine Rosin on the Degradation of Mechanical Performance in Flax-Reinforced Polymeric Composites after Soil Burial at Low Temperatures
title_fullStr Effects of Pine Rosin on the Degradation of Mechanical Performance in Flax-Reinforced Polymeric Composites after Soil Burial at Low Temperatures
title_full_unstemmed Effects of Pine Rosin on the Degradation of Mechanical Performance in Flax-Reinforced Polymeric Composites after Soil Burial at Low Temperatures
title_short Effects of Pine Rosin on the Degradation of Mechanical Performance in Flax-Reinforced Polymeric Composites after Soil Burial at Low Temperatures
title_sort effects of pine rosin on the degradation of mechanical performance in flax reinforced polymeric composites after soil burial at low temperatures
topic composite
flax
rosin
soil burial
interface
url https://ojs.cnr.ncsu.edu/index.php/BRJ/article/view/22300
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