EPR and dielectric spectroscopy of reorienting Cr<sup>3+</sup>-Li<sup>+</sup> pair centres in Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub> crystal
Earlier it has been shown that in the lithium heptagermanate Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub> structure the chromium doping ions substitute the germanium hosts and create Cr<sup>3+</sup>-Li<sup>+</sup> pair centres. In the paper E...
Main Authors: | , , |
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Format: | Article |
Language: | English |
Published: |
Institute for Condensed Matter Physics
2007-01-01
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Series: | Condensed Matter Physics |
Subjects: | |
Online Access: | http://dx.doi.org/10.5488/CMP.10.1.75 |
Summary: | Earlier it has been shown that in the lithium heptagermanate Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub> structure the chromium doping ions substitute the germanium hosts and create Cr<sup>3+</sup>-Li<sup>+</sup> pair centres. In the paper EPR and dielectric spectra of Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub>:Cr<sup>3+</sup> crystal are studied in the temperature range 300-500 K. The thermally activated reorientation of Cr<sup>3+</sup>-Li<sup>+</sup> pairs has been detected through EPR line width broadening and dielectric relaxation. |
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ISSN: | 1607-324X |