EPR and dielectric spectroscopy of reorienting Cr<sup>3+</sup>-Li<sup>+</sup> pair centres in Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub> crystal
Earlier it has been shown that in the lithium heptagermanate Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub> structure the chromium doping ions substitute the germanium hosts and create Cr<sup>3+</sup>-Li<sup>+</sup> pair centres. In the paper E...
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Institute for Condensed Matter Physics
2007-01-01
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Online Access: | http://dx.doi.org/10.5488/CMP.10.1.75 |
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author | M.D.Volnianskii M.P.Trubitsyn Yahia A.H. Obaidat |
author_facet | M.D.Volnianskii M.P.Trubitsyn Yahia A.H. Obaidat |
author_sort | M.D.Volnianskii |
collection | DOAJ |
description | Earlier it has been shown that in the lithium heptagermanate Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub> structure the chromium doping ions substitute the germanium hosts and create Cr<sup>3+</sup>-Li<sup>+</sup> pair centres. In the paper EPR and dielectric spectra of Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub>:Cr<sup>3+</sup> crystal are studied in the temperature range 300-500 K. The thermally activated reorientation of Cr<sup>3+</sup>-Li<sup>+</sup> pairs has been detected through EPR line width broadening and dielectric relaxation. |
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spelling | doaj.art-db19477ffddc425997f5a9c12171e69c2022-12-21T23:20:42ZengInstitute for Condensed Matter PhysicsCondensed Matter Physics1607-324X2007-01-0110175EPR and dielectric spectroscopy of reorienting Cr<sup>3+</sup>-Li<sup>+</sup> pair centres in Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub> crystalM.D.VolnianskiiM.P.TrubitsynYahia A.H. ObaidatEarlier it has been shown that in the lithium heptagermanate Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub> structure the chromium doping ions substitute the germanium hosts and create Cr<sup>3+</sup>-Li<sup>+</sup> pair centres. In the paper EPR and dielectric spectra of Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub>:Cr<sup>3+</sup> crystal are studied in the temperature range 300-500 K. The thermally activated reorientation of Cr<sup>3+</sup>-Li<sup>+</sup> pairs has been detected through EPR line width broadening and dielectric relaxation.http://dx.doi.org/10.5488/CMP.10.1.75impurity ionselectron paramagnetic resonancedielectric loss and relaxation |
spellingShingle | M.D.Volnianskii M.P.Trubitsyn Yahia A.H. Obaidat EPR and dielectric spectroscopy of reorienting Cr<sup>3+</sup>-Li<sup>+</sup> pair centres in Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub> crystal Condensed Matter Physics impurity ions electron paramagnetic resonance dielectric loss and relaxation |
title | EPR and dielectric spectroscopy of reorienting Cr<sup>3+</sup>-Li<sup>+</sup> pair centres in Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub> crystal |
title_full | EPR and dielectric spectroscopy of reorienting Cr<sup>3+</sup>-Li<sup>+</sup> pair centres in Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub> crystal |
title_fullStr | EPR and dielectric spectroscopy of reorienting Cr<sup>3+</sup>-Li<sup>+</sup> pair centres in Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub> crystal |
title_full_unstemmed | EPR and dielectric spectroscopy of reorienting Cr<sup>3+</sup>-Li<sup>+</sup> pair centres in Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub> crystal |
title_short | EPR and dielectric spectroscopy of reorienting Cr<sup>3+</sup>-Li<sup>+</sup> pair centres in Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub> crystal |
title_sort | epr and dielectric spectroscopy of reorienting cr sup 3 sup li sup sup pair centres in li sub 2 sub ge sub 7 sub o sub 15 sub crystal |
topic | impurity ions electron paramagnetic resonance dielectric loss and relaxation |
url | http://dx.doi.org/10.5488/CMP.10.1.75 |
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