EPR and dielectric spectroscopy of reorienting Cr<sup>3+</sup>-Li<sup>+</sup> pair centres in Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub> crystal

Earlier it has been shown that in the lithium heptagermanate Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub> structure the chromium doping ions substitute the germanium hosts and create Cr<sup>3+</sup>-Li<sup>+</sup> pair centres. In the paper E...

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Main Authors: M.D.Volnianskii, M.P.Trubitsyn, Yahia A.H. Obaidat
Format: Article
Language:English
Published: Institute for Condensed Matter Physics 2007-01-01
Series:Condensed Matter Physics
Subjects:
Online Access:http://dx.doi.org/10.5488/CMP.10.1.75
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author M.D.Volnianskii
M.P.Trubitsyn
Yahia A.H. Obaidat
author_facet M.D.Volnianskii
M.P.Trubitsyn
Yahia A.H. Obaidat
author_sort M.D.Volnianskii
collection DOAJ
description Earlier it has been shown that in the lithium heptagermanate Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub> structure the chromium doping ions substitute the germanium hosts and create Cr<sup>3+</sup>-Li<sup>+</sup> pair centres. In the paper EPR and dielectric spectra of Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub>:Cr<sup>3+</sup> crystal are studied in the temperature range 300-500 K. The thermally activated reorientation of Cr<sup>3+</sup>-Li<sup>+</sup> pairs has been detected through EPR line width broadening and dielectric relaxation.
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spelling doaj.art-db19477ffddc425997f5a9c12171e69c2022-12-21T23:20:42ZengInstitute for Condensed Matter PhysicsCondensed Matter Physics1607-324X2007-01-0110175EPR and dielectric spectroscopy of reorienting Cr<sup>3+</sup>-Li<sup>+</sup> pair centres in Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub> crystalM.D.VolnianskiiM.P.TrubitsynYahia A.H. ObaidatEarlier it has been shown that in the lithium heptagermanate Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub> structure the chromium doping ions substitute the germanium hosts and create Cr<sup>3+</sup>-Li<sup>+</sup> pair centres. In the paper EPR and dielectric spectra of Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub>:Cr<sup>3+</sup> crystal are studied in the temperature range 300-500 K. The thermally activated reorientation of Cr<sup>3+</sup>-Li<sup>+</sup> pairs has been detected through EPR line width broadening and dielectric relaxation.http://dx.doi.org/10.5488/CMP.10.1.75impurity ionselectron paramagnetic resonancedielectric loss and relaxation
spellingShingle M.D.Volnianskii
M.P.Trubitsyn
Yahia A.H. Obaidat
EPR and dielectric spectroscopy of reorienting Cr<sup>3+</sup>-Li<sup>+</sup> pair centres in Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub> crystal
Condensed Matter Physics
impurity ions
electron paramagnetic resonance
dielectric loss and relaxation
title EPR and dielectric spectroscopy of reorienting Cr<sup>3+</sup>-Li<sup>+</sup> pair centres in Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub> crystal
title_full EPR and dielectric spectroscopy of reorienting Cr<sup>3+</sup>-Li<sup>+</sup> pair centres in Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub> crystal
title_fullStr EPR and dielectric spectroscopy of reorienting Cr<sup>3+</sup>-Li<sup>+</sup> pair centres in Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub> crystal
title_full_unstemmed EPR and dielectric spectroscopy of reorienting Cr<sup>3+</sup>-Li<sup>+</sup> pair centres in Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub> crystal
title_short EPR and dielectric spectroscopy of reorienting Cr<sup>3+</sup>-Li<sup>+</sup> pair centres in Li<sub>2</sub>Ge<sub>7</sub>O<sub>15</sub> crystal
title_sort epr and dielectric spectroscopy of reorienting cr sup 3 sup li sup sup pair centres in li sub 2 sub ge sub 7 sub o sub 15 sub crystal
topic impurity ions
electron paramagnetic resonance
dielectric loss and relaxation
url http://dx.doi.org/10.5488/CMP.10.1.75
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