Static and Kinetic Studies of the Adsorption/Desorption of H and OH Ions on Alumina in Aqueous NaNO Solution

The adsorption/desorption of H + and OH − ions under static conditions on to alumina in aqueous NaNO 3 solution was studied at 30°C by potentiometric titration and calculations undertaken using the triple layer model (TLM). Intrinsic dissociation constants and intrinsic complexation constants at 30°...

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Main Authors: Chu Taiwei, Du Jinzhou, Tao Zuyi
Format: Article
Language:English
Published: SAGE Publications 1997-05-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1177/026361749701500503
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author Chu Taiwei
Du Jinzhou
Tao Zuyi
author_facet Chu Taiwei
Du Jinzhou
Tao Zuyi
author_sort Chu Taiwei
collection DOAJ
description The adsorption/desorption of H + and OH − ions under static conditions on to alumina in aqueous NaNO 3 solution was studied at 30°C by potentiometric titration and calculations undertaken using the triple layer model (TLM). Intrinsic dissociation constants and intrinsic complexation constants at 30°C were used to calculate surface charge density, surface potential and surface species as a function of pH and ionic strength (I). Related adsorption/desorption studies of H + and OH − ions under dynamic conditions on to alumina in aqueous NaNO 3 solution were studied by means of the concentration-jump technique. Mechanistic information regarding H + and OH − ion adsorption/desorption on to alumina was discussed using the experimental data in conjunction with the TLM.
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spelling doaj.art-db2b189611ea4c2eae573a85c2d11c732024-03-02T13:22:11ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40381997-05-011510.1177/026361749701500503Static and Kinetic Studies of the Adsorption/Desorption of H and OH Ions on Alumina in Aqueous NaNO SolutionChu TaiweiDu JinzhouTao ZuyiThe adsorption/desorption of H + and OH − ions under static conditions on to alumina in aqueous NaNO 3 solution was studied at 30°C by potentiometric titration and calculations undertaken using the triple layer model (TLM). Intrinsic dissociation constants and intrinsic complexation constants at 30°C were used to calculate surface charge density, surface potential and surface species as a function of pH and ionic strength (I). Related adsorption/desorption studies of H + and OH − ions under dynamic conditions on to alumina in aqueous NaNO 3 solution were studied by means of the concentration-jump technique. Mechanistic information regarding H + and OH − ion adsorption/desorption on to alumina was discussed using the experimental data in conjunction with the TLM.https://doi.org/10.1177/026361749701500503
spellingShingle Chu Taiwei
Du Jinzhou
Tao Zuyi
Static and Kinetic Studies of the Adsorption/Desorption of H and OH Ions on Alumina in Aqueous NaNO Solution
Adsorption Science & Technology
title Static and Kinetic Studies of the Adsorption/Desorption of H and OH Ions on Alumina in Aqueous NaNO Solution
title_full Static and Kinetic Studies of the Adsorption/Desorption of H and OH Ions on Alumina in Aqueous NaNO Solution
title_fullStr Static and Kinetic Studies of the Adsorption/Desorption of H and OH Ions on Alumina in Aqueous NaNO Solution
title_full_unstemmed Static and Kinetic Studies of the Adsorption/Desorption of H and OH Ions on Alumina in Aqueous NaNO Solution
title_short Static and Kinetic Studies of the Adsorption/Desorption of H and OH Ions on Alumina in Aqueous NaNO Solution
title_sort static and kinetic studies of the adsorption desorption of h and oh ions on alumina in aqueous nano solution
url https://doi.org/10.1177/026361749701500503
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AT dujinzhou staticandkineticstudiesoftheadsorptiondesorptionofhandohionsonaluminainaqueousnanosolution
AT taozuyi staticandkineticstudiesoftheadsorptiondesorptionofhandohionsonaluminainaqueousnanosolution