Static and Kinetic Studies of the Adsorption/Desorption of H and OH Ions on Alumina in Aqueous NaNO Solution
The adsorption/desorption of H + and OH − ions under static conditions on to alumina in aqueous NaNO 3 solution was studied at 30°C by potentiometric titration and calculations undertaken using the triple layer model (TLM). Intrinsic dissociation constants and intrinsic complexation constants at 30°...
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Format: | Article |
Language: | English |
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SAGE Publications
1997-05-01
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Series: | Adsorption Science & Technology |
Online Access: | https://doi.org/10.1177/026361749701500503 |
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author | Chu Taiwei Du Jinzhou Tao Zuyi |
author_facet | Chu Taiwei Du Jinzhou Tao Zuyi |
author_sort | Chu Taiwei |
collection | DOAJ |
description | The adsorption/desorption of H + and OH − ions under static conditions on to alumina in aqueous NaNO 3 solution was studied at 30°C by potentiometric titration and calculations undertaken using the triple layer model (TLM). Intrinsic dissociation constants and intrinsic complexation constants at 30°C were used to calculate surface charge density, surface potential and surface species as a function of pH and ionic strength (I). Related adsorption/desorption studies of H + and OH − ions under dynamic conditions on to alumina in aqueous NaNO 3 solution were studied by means of the concentration-jump technique. Mechanistic information regarding H + and OH − ion adsorption/desorption on to alumina was discussed using the experimental data in conjunction with the TLM. |
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format | Article |
id | doaj.art-db2b189611ea4c2eae573a85c2d11c73 |
institution | Directory Open Access Journal |
issn | 0263-6174 2048-4038 |
language | English |
last_indexed | 2024-03-07T17:54:14Z |
publishDate | 1997-05-01 |
publisher | SAGE Publications |
record_format | Article |
series | Adsorption Science & Technology |
spelling | doaj.art-db2b189611ea4c2eae573a85c2d11c732024-03-02T13:22:11ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40381997-05-011510.1177/026361749701500503Static and Kinetic Studies of the Adsorption/Desorption of H and OH Ions on Alumina in Aqueous NaNO SolutionChu TaiweiDu JinzhouTao ZuyiThe adsorption/desorption of H + and OH − ions under static conditions on to alumina in aqueous NaNO 3 solution was studied at 30°C by potentiometric titration and calculations undertaken using the triple layer model (TLM). Intrinsic dissociation constants and intrinsic complexation constants at 30°C were used to calculate surface charge density, surface potential and surface species as a function of pH and ionic strength (I). Related adsorption/desorption studies of H + and OH − ions under dynamic conditions on to alumina in aqueous NaNO 3 solution were studied by means of the concentration-jump technique. Mechanistic information regarding H + and OH − ion adsorption/desorption on to alumina was discussed using the experimental data in conjunction with the TLM.https://doi.org/10.1177/026361749701500503 |
spellingShingle | Chu Taiwei Du Jinzhou Tao Zuyi Static and Kinetic Studies of the Adsorption/Desorption of H and OH Ions on Alumina in Aqueous NaNO Solution Adsorption Science & Technology |
title | Static and Kinetic Studies of the Adsorption/Desorption of H and OH Ions on Alumina in Aqueous NaNO Solution |
title_full | Static and Kinetic Studies of the Adsorption/Desorption of H and OH Ions on Alumina in Aqueous NaNO Solution |
title_fullStr | Static and Kinetic Studies of the Adsorption/Desorption of H and OH Ions on Alumina in Aqueous NaNO Solution |
title_full_unstemmed | Static and Kinetic Studies of the Adsorption/Desorption of H and OH Ions on Alumina in Aqueous NaNO Solution |
title_short | Static and Kinetic Studies of the Adsorption/Desorption of H and OH Ions on Alumina in Aqueous NaNO Solution |
title_sort | static and kinetic studies of the adsorption desorption of h and oh ions on alumina in aqueous nano solution |
url | https://doi.org/10.1177/026361749701500503 |
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