Symmetry-Based Balance Equation for Local Entropy Density in a Dissipative Multibaker Chain System

In this study, the balance equation for local entropy density defined on each partition is obtained by the decomposition of the time-evolution operator for local entropy density, on the level of the master equation, by using symmetric and antisymmetric properties for the inversion of partition, dens...

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Main Author: Hideshi Ishida
Format: Article
Language:English
Published: MDPI AG 2013-10-01
Series:Entropy
Subjects:
Online Access:http://www.mdpi.com/1099-4300/15/10/4345
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author Hideshi Ishida
author_facet Hideshi Ishida
author_sort Hideshi Ishida
collection DOAJ
description In this study, the balance equation for local entropy density defined on each partition is obtained by the decomposition of the time-evolution operator for local entropy density, on the level of the master equation, by using symmetric and antisymmetric properties for the inversion of partition, density pairs and a given drift velocity. The resultant equation includes the following terms: convection, diffusion, entropy flow due to a thermostat and entropy production. The averaging of the four terms recover the corresponding terms in a balance equation for the macroscopic entropy density of irreversible thermodynamics for a thermostated system. Moreover, an empirical law of order estimation is introduced to explain the limiting behavior of the averaged quantities in the macroscopic limit for the bulk system. The law makes it possible to separate some minor contributions from the major four terms and, for example, to explain the positive entropy production rate in a nonequilibrium state for volume-preserving systems, even if the state is far from steady state. They are numerically confirmed on an invertible, dissipative multibaker chain system, named a circuit model. These properties are independent of partitioning.
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spelling doaj.art-db2f5bf29836409098e8c8655b8eca2a2022-12-22T04:24:18ZengMDPI AGEntropy1099-43002013-10-0115104345437510.3390/e15104345Symmetry-Based Balance Equation for Local Entropy Density in a Dissipative Multibaker Chain SystemHideshi IshidaIn this study, the balance equation for local entropy density defined on each partition is obtained by the decomposition of the time-evolution operator for local entropy density, on the level of the master equation, by using symmetric and antisymmetric properties for the inversion of partition, density pairs and a given drift velocity. The resultant equation includes the following terms: convection, diffusion, entropy flow due to a thermostat and entropy production. The averaging of the four terms recover the corresponding terms in a balance equation for the macroscopic entropy density of irreversible thermodynamics for a thermostated system. Moreover, an empirical law of order estimation is introduced to explain the limiting behavior of the averaged quantities in the macroscopic limit for the bulk system. The law makes it possible to separate some minor contributions from the major four terms and, for example, to explain the positive entropy production rate in a nonequilibrium state for volume-preserving systems, even if the state is far from steady state. They are numerically confirmed on an invertible, dissipative multibaker chain system, named a circuit model. These properties are independent of partitioning.http://www.mdpi.com/1099-4300/15/10/4345symmetry-based decompositionlocal entropy densitycoarse grainingdissipative systempositive entropy productionlaw of order estimationmultibaker map
spellingShingle Hideshi Ishida
Symmetry-Based Balance Equation for Local Entropy Density in a Dissipative Multibaker Chain System
Entropy
symmetry-based decomposition
local entropy density
coarse graining
dissipative system
positive entropy production
law of order estimation
multibaker map
title Symmetry-Based Balance Equation for Local Entropy Density in a Dissipative Multibaker Chain System
title_full Symmetry-Based Balance Equation for Local Entropy Density in a Dissipative Multibaker Chain System
title_fullStr Symmetry-Based Balance Equation for Local Entropy Density in a Dissipative Multibaker Chain System
title_full_unstemmed Symmetry-Based Balance Equation for Local Entropy Density in a Dissipative Multibaker Chain System
title_short Symmetry-Based Balance Equation for Local Entropy Density in a Dissipative Multibaker Chain System
title_sort symmetry based balance equation for local entropy density in a dissipative multibaker chain system
topic symmetry-based decomposition
local entropy density
coarse graining
dissipative system
positive entropy production
law of order estimation
multibaker map
url http://www.mdpi.com/1099-4300/15/10/4345
work_keys_str_mv AT hideshiishida symmetrybasedbalanceequationforlocalentropydensityinadissipativemultibakerchainsystem