Impact of water saturation and cation concentrations on wettability alteration and oil recovery of carbonate rocks using low-salinity water

Abstract In this study, the effect of initial water saturation on the oil recovery for carbonate rocks is investigated using spontaneous imbibition experiments. The experiments are performed using 20 times diluted sea water as imbibing fluid and the sea water as initial water. In addition, the impac...

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Main Authors: Mohammad Reza Zaeri, Hamidreza Shahverdi, Rohallah Hashemi, Mohsen Mohammadi
Format: Article
Language:English
Published: SpringerOpen 2018-09-01
Series:Journal of Petroleum Exploration and Production Technology
Subjects:
Online Access:http://link.springer.com/article/10.1007/s13202-018-0552-2
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author Mohammad Reza Zaeri
Hamidreza Shahverdi
Rohallah Hashemi
Mohsen Mohammadi
author_facet Mohammad Reza Zaeri
Hamidreza Shahverdi
Rohallah Hashemi
Mohsen Mohammadi
author_sort Mohammad Reza Zaeri
collection DOAJ
description Abstract In this study, the effect of initial water saturation on the oil recovery for carbonate rocks is investigated using spontaneous imbibition experiments. The experiments are performed using 20 times diluted sea water as imbibing fluid and the sea water as initial water. In addition, the impact of pH and Ca2+, Mg2+, Na+, and K+ cations concentration change of imbibing fluid are investigated during tests. These results help to identify the active cations in the wettability alteration process of carbonate rocks during the low-salinity water injection. A mechanism is proposed to describe the effect of initial water saturation on the oil recovery by low-salinity water injection. The impact of initial water saturation on the wettability alteration might be positive or negative depending on its value and the rock permeability. The comparison of divalent cations concentrations shows that the minimum adsorption of Ca2+ and maximum desorption of Mg2+ lead to maximum oil recovery of spontaneous imbibition. The results confirm that three cations of Ca2+, Mg2+, and Na+ are active for wettability alteration of carbonate rocks in the presence of sea water as initial water and diluted sea as imbibing fluid, whilst the amounts of potassium remain constant.
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spelling doaj.art-db36fa5a7e0244718a8ee1e43a8f2e432022-12-22T04:32:50ZengSpringerOpenJournal of Petroleum Exploration and Production Technology2190-05582190-05662018-09-01921185119610.1007/s13202-018-0552-2Impact of water saturation and cation concentrations on wettability alteration and oil recovery of carbonate rocks using low-salinity waterMohammad Reza Zaeri0Hamidreza Shahverdi1Rohallah Hashemi2Mohsen Mohammadi3Department of Chemical Engineering, Isfahan University of TechnologyDepartment of Chemical Engineering, Isfahan University of TechnologyDepartment of Chemical Engineering, Isfahan University of TechnologyDepartment of Chemical Engineering, Isfahan University of TechnologyAbstract In this study, the effect of initial water saturation on the oil recovery for carbonate rocks is investigated using spontaneous imbibition experiments. The experiments are performed using 20 times diluted sea water as imbibing fluid and the sea water as initial water. In addition, the impact of pH and Ca2+, Mg2+, Na+, and K+ cations concentration change of imbibing fluid are investigated during tests. These results help to identify the active cations in the wettability alteration process of carbonate rocks during the low-salinity water injection. A mechanism is proposed to describe the effect of initial water saturation on the oil recovery by low-salinity water injection. The impact of initial water saturation on the wettability alteration might be positive or negative depending on its value and the rock permeability. The comparison of divalent cations concentrations shows that the minimum adsorption of Ca2+ and maximum desorption of Mg2+ lead to maximum oil recovery of spontaneous imbibition. The results confirm that three cations of Ca2+, Mg2+, and Na+ are active for wettability alteration of carbonate rocks in the presence of sea water as initial water and diluted sea as imbibing fluid, whilst the amounts of potassium remain constant.http://link.springer.com/article/10.1007/s13202-018-0552-2EORLow-salinity water injectionCarbonate rocksSpontaneous imbibitionWater saturationCation exchange
spellingShingle Mohammad Reza Zaeri
Hamidreza Shahverdi
Rohallah Hashemi
Mohsen Mohammadi
Impact of water saturation and cation concentrations on wettability alteration and oil recovery of carbonate rocks using low-salinity water
Journal of Petroleum Exploration and Production Technology
EOR
Low-salinity water injection
Carbonate rocks
Spontaneous imbibition
Water saturation
Cation exchange
title Impact of water saturation and cation concentrations on wettability alteration and oil recovery of carbonate rocks using low-salinity water
title_full Impact of water saturation and cation concentrations on wettability alteration and oil recovery of carbonate rocks using low-salinity water
title_fullStr Impact of water saturation and cation concentrations on wettability alteration and oil recovery of carbonate rocks using low-salinity water
title_full_unstemmed Impact of water saturation and cation concentrations on wettability alteration and oil recovery of carbonate rocks using low-salinity water
title_short Impact of water saturation and cation concentrations on wettability alteration and oil recovery of carbonate rocks using low-salinity water
title_sort impact of water saturation and cation concentrations on wettability alteration and oil recovery of carbonate rocks using low salinity water
topic EOR
Low-salinity water injection
Carbonate rocks
Spontaneous imbibition
Water saturation
Cation exchange
url http://link.springer.com/article/10.1007/s13202-018-0552-2
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AT hamidrezashahverdi impactofwatersaturationandcationconcentrationsonwettabilityalterationandoilrecoveryofcarbonaterocksusinglowsalinitywater
AT rohallahhashemi impactofwatersaturationandcationconcentrationsonwettabilityalterationandoilrecoveryofcarbonaterocksusinglowsalinitywater
AT mohsenmohammadi impactofwatersaturationandcationconcentrationsonwettabilityalterationandoilrecoveryofcarbonaterocksusinglowsalinitywater