LASER SYNTHESIS OF SELENIUM NANOPARTICLES IN LIQUID MONOMERS
The paper presents the results of selenium nanoparticles synthesis in various liquid monomers by laser ablation. The following substances were selected as the condensation liquids for laser ablation: isodecyl acrylate (IDA, Isodecylacrylate, Aldrich), carboxyethyl acrylate (2Car, 2-carboxyethyl acr...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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Saint Petersburg National Research University of Information Technologies, Mechanics and Optics (ITMO University)
2018-05-01
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| Series: | Naučno-tehničeskij Vestnik Informacionnyh Tehnologij, Mehaniki i Optiki |
| Subjects: | |
| Online Access: | http://ntv.ifmo.ru/file/article/17777.pdf |
| _version_ | 1818535482510802944 |
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| author | N. A. Zulina, M. I. Fokina, E. G. Cherkashina T. N. Nosenko |
| author_facet | N. A. Zulina, M. I. Fokina, E. G. Cherkashina T. N. Nosenko |
| author_sort | N. A. Zulina, |
| collection | DOAJ |
| description | The paper presents the results of selenium nanoparticles synthesis in various liquid monomers by laser ablation. The following substances were selected as the condensation liquids for laser ablation: isodecyl acrylate (IDA, Isodecylacrylate, Aldrich), carboxyethyl acrylate (2Car, 2-carboxyethyl acrylate, Aldrich), ethylene glycol phenyl acrylate (Aldrich), ethylene glycol phenyl acrylate, an available blend of Ebecryl monomers (Cytec Industries Inc.), currently one of the possible components of modern lacquer coatings for nail plates. Thus, a method is proposed for simultaneous synthesis and incorporation of selenium nanoparticles into a polymer matrix. It is established by scanning microscopy method that the sizes of the obtained nanoparticles are from 50 to 200 nm. Infrared spectroscopy results of obtained colloidal solutions showed zero interactions of selenium nanoparticles with monomers. Stable colloidal solutions of selenium nanoparticles were obtained, and solid polymer films promising for biomedical applications were synthesized. The polymerization of colloidal solutions with added monomers and/or mixtures of oligomers was carried out using photo initiator of polymerization 2.2-dimethoxy-2-fenilatsetofenol, sensitive in the UV region (365 nm). The results of IR spectroscopy of the obtained colloidal solutions and polymer nanocomposites showed the absence of interactions of selenium nanoparticles with monomers and polymer matrices. Such nanocomposites could be perspective for biomedical applications, for example, as fungicidal coatings of different surfaces. |
| first_indexed | 2024-12-11T18:25:28Z |
| format | Article |
| id | doaj.art-db5b245784c34b99be745e5f521fa222 |
| institution | Directory Open Access Journal |
| issn | 2226-1494 2500-0373 |
| language | English |
| last_indexed | 2024-12-11T18:25:28Z |
| publishDate | 2018-05-01 |
| publisher | Saint Petersburg National Research University of Information Technologies, Mechanics and Optics (ITMO University) |
| record_format | Article |
| series | Naučno-tehničeskij Vestnik Informacionnyh Tehnologij, Mehaniki i Optiki |
| spelling | doaj.art-db5b245784c34b99be745e5f521fa2222022-12-22T00:55:06ZengSaint Petersburg National Research University of Information Technologies, Mechanics and Optics (ITMO University)Naučno-tehničeskij Vestnik Informacionnyh Tehnologij, Mehaniki i Optiki2226-14942500-03732018-05-0118341642010.17586/2226-1494-2018-18-3-416-420LASER SYNTHESIS OF SELENIUM NANOPARTICLES IN LIQUID MONOMERSN. A. Zulina, M. I. Fokina, E. G. CherkashinaT. N. NosenkoThe paper presents the results of selenium nanoparticles synthesis in various liquid monomers by laser ablation. The following substances were selected as the condensation liquids for laser ablation: isodecyl acrylate (IDA, Isodecylacrylate, Aldrich), carboxyethyl acrylate (2Car, 2-carboxyethyl acrylate, Aldrich), ethylene glycol phenyl acrylate (Aldrich), ethylene glycol phenyl acrylate, an available blend of Ebecryl monomers (Cytec Industries Inc.), currently one of the possible components of modern lacquer coatings for nail plates. Thus, a method is proposed for simultaneous synthesis and incorporation of selenium nanoparticles into a polymer matrix. It is established by scanning microscopy method that the sizes of the obtained nanoparticles are from 50 to 200 nm. Infrared spectroscopy results of obtained colloidal solutions showed zero interactions of selenium nanoparticles with monomers. Stable colloidal solutions of selenium nanoparticles were obtained, and solid polymer films promising for biomedical applications were synthesized. The polymerization of colloidal solutions with added monomers and/or mixtures of oligomers was carried out using photo initiator of polymerization 2.2-dimethoxy-2-fenilatsetofenol, sensitive in the UV region (365 nm). The results of IR spectroscopy of the obtained colloidal solutions and polymer nanocomposites showed the absence of interactions of selenium nanoparticles with monomers and polymer matrices. Such nanocomposites could be perspective for biomedical applications, for example, as fungicidal coatings of different surfaces.http://ntv.ifmo.ru/file/article/17777.pdflaser ablationselenium nanoparticlespolymer nanocompositesliquid monomercolloid |
| spellingShingle | N. A. Zulina, M. I. Fokina, E. G. Cherkashina T. N. Nosenko LASER SYNTHESIS OF SELENIUM NANOPARTICLES IN LIQUID MONOMERS Naučno-tehničeskij Vestnik Informacionnyh Tehnologij, Mehaniki i Optiki laser ablation selenium nanoparticles polymer nanocomposites liquid monomer colloid |
| title | LASER SYNTHESIS OF SELENIUM NANOPARTICLES IN LIQUID MONOMERS |
| title_full | LASER SYNTHESIS OF SELENIUM NANOPARTICLES IN LIQUID MONOMERS |
| title_fullStr | LASER SYNTHESIS OF SELENIUM NANOPARTICLES IN LIQUID MONOMERS |
| title_full_unstemmed | LASER SYNTHESIS OF SELENIUM NANOPARTICLES IN LIQUID MONOMERS |
| title_short | LASER SYNTHESIS OF SELENIUM NANOPARTICLES IN LIQUID MONOMERS |
| title_sort | laser synthesis of selenium nanoparticles in liquid monomers |
| topic | laser ablation selenium nanoparticles polymer nanocomposites liquid monomer colloid |
| url | http://ntv.ifmo.ru/file/article/17777.pdf |
| work_keys_str_mv | AT nazulina lasersynthesisofseleniumnanoparticlesinliquidmonomers AT mifokina lasersynthesisofseleniumnanoparticlesinliquidmonomers AT egcherkashina lasersynthesisofseleniumnanoparticlesinliquidmonomers AT tnnosenko lasersynthesisofseleniumnanoparticlesinliquidmonomers |