Synthesis and Characterization of Tetraphenylethene AIEgen-Based Push–Pull Chromophores for Photothermal Applications: Could the Cycloaddition–Retroelectrocyclization Click Reaction Make Any Molecule Photothermally Active?

Synthesis and Characterization of Tetraphenylethene AIEgen-Based Push–Pull Chromophores for Photothermal Applications: Could the Cycloaddition–Retroelectrocyclization Click Reaction Make Any Molecule Photothermally Active?

Three new tetraphenylethene (TPE) push–pull chromophores exhibiting strong intramolecular charge transfer (ICT) are described. They were obtained via [2 + 2] cycloaddition–retroelectrocyclization (CA-RE) click reactions on an electron-rich alkyne-tetrafunctionalized TPE (TPE-alkyne) using both 1,1,2...

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Bibliographic Details
Main Authors: Maxime Roger, Yann Bretonnière, Yann Trolez, Antoine Vacher, Imane Arbouch, Jérôme Cornil, Gautier Félix, Julien De Winter, Sébastien Richeter, Sébastien Clément, Philippe Gerbier
Format: Article
Language:English
Published: MDPI AG 2023-05-01
Series:International Journal of Molecular Sciences
Subjects:
TPE
AIEgen
cycloaddition-retroelectrocyclization
click chemistry
photothermal applications
Online Access:https://www.mdpi.com/1422-0067/24/10/8715

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