Monolayer Quantum-Dot Based Light-Sensor by a Photo-Electrochemical Mechanism

Monolayer nanocrystal-based light sensors with cadmium-selenium thin film electrodes have been investigated using electrochemical cyclic voltammetry tests. An indium tin oxide electrode system, with a monolayer of homogeneously deposited cadmium-selenium quantum dots was proven to work as a photo-se...

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Main Authors: Sitansu Sekhar Nanda, Minjik Kim, Sung Jong Yoo, Georgia C. Papaefthymiou, Dong Kee Yi
Format: Article
Language:English
Published: MDPI AG 2020-08-01
Series:Micromachines
Subjects:
Online Access:https://www.mdpi.com/2072-666X/11/9/817
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author Sitansu Sekhar Nanda
Minjik Kim
Sung Jong Yoo
Georgia C. Papaefthymiou
Dong Kee Yi
author_facet Sitansu Sekhar Nanda
Minjik Kim
Sung Jong Yoo
Georgia C. Papaefthymiou
Dong Kee Yi
author_sort Sitansu Sekhar Nanda
collection DOAJ
description Monolayer nanocrystal-based light sensors with cadmium-selenium thin film electrodes have been investigated using electrochemical cyclic voltammetry tests. An indium tin oxide electrode system, with a monolayer of homogeneously deposited cadmium-selenium quantum dots was proven to work as a photo-sensor via an electrochemical cell mechanism; it was possible to tune current densities under light illumination. Electrochemical tests on a quantum dot capacitor, using different sized (red, yellow and green) cadmium-selenium quantum dots on indium tin oxide substrates, showed typical capacitive behavior of cyclic voltammetry curves in 2M H<sub>2</sub>SO<sub>4</sub> aqueous solutions. This arrangement provides a beneficial effect in, both, charge separation and light sensory characteristics. Importantly, the photocurrent density depended on quantum yield rendering tunable photo-sensing properties.
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spelling doaj.art-db6f3a95b30449febcb0ae45ca4d6af42023-11-20T11:47:32ZengMDPI AGMicromachines2072-666X2020-08-0111981710.3390/mi11090817Monolayer Quantum-Dot Based Light-Sensor by a Photo-Electrochemical MechanismSitansu Sekhar Nanda0Minjik Kim1Sung Jong Yoo2Georgia C. Papaefthymiou3Dong Kee Yi4Department of Chemistry, Myongji University, Yongin-si 17058, KoreaDepartment of Chemistry, Myongji University, Yongin-si 17058, KoreaCenter for Hydrogen·Fuel Cell Research, Korea Institute of Science and Technology, Hwarang-ro, 14-gil, Seoul 02792, KoreaDepartment of Physics, Villanova University, Villanova, PA 19085, USADepartment of Chemistry, Myongji University, Yongin-si 17058, KoreaMonolayer nanocrystal-based light sensors with cadmium-selenium thin film electrodes have been investigated using electrochemical cyclic voltammetry tests. An indium tin oxide electrode system, with a monolayer of homogeneously deposited cadmium-selenium quantum dots was proven to work as a photo-sensor via an electrochemical cell mechanism; it was possible to tune current densities under light illumination. Electrochemical tests on a quantum dot capacitor, using different sized (red, yellow and green) cadmium-selenium quantum dots on indium tin oxide substrates, showed typical capacitive behavior of cyclic voltammetry curves in 2M H<sub>2</sub>SO<sub>4</sub> aqueous solutions. This arrangement provides a beneficial effect in, both, charge separation and light sensory characteristics. Importantly, the photocurrent density depended on quantum yield rendering tunable photo-sensing properties.https://www.mdpi.com/2072-666X/11/9/817CdSequantum dotscapacitorsemiconductor electrodephoto-sensor
spellingShingle Sitansu Sekhar Nanda
Minjik Kim
Sung Jong Yoo
Georgia C. Papaefthymiou
Dong Kee Yi
Monolayer Quantum-Dot Based Light-Sensor by a Photo-Electrochemical Mechanism
Micromachines
CdSe
quantum dots
capacitor
semiconductor electrode
photo-sensor
title Monolayer Quantum-Dot Based Light-Sensor by a Photo-Electrochemical Mechanism
title_full Monolayer Quantum-Dot Based Light-Sensor by a Photo-Electrochemical Mechanism
title_fullStr Monolayer Quantum-Dot Based Light-Sensor by a Photo-Electrochemical Mechanism
title_full_unstemmed Monolayer Quantum-Dot Based Light-Sensor by a Photo-Electrochemical Mechanism
title_short Monolayer Quantum-Dot Based Light-Sensor by a Photo-Electrochemical Mechanism
title_sort monolayer quantum dot based light sensor by a photo electrochemical mechanism
topic CdSe
quantum dots
capacitor
semiconductor electrode
photo-sensor
url https://www.mdpi.com/2072-666X/11/9/817
work_keys_str_mv AT sitansusekharnanda monolayerquantumdotbasedlightsensorbyaphotoelectrochemicalmechanism
AT minjikkim monolayerquantumdotbasedlightsensorbyaphotoelectrochemicalmechanism
AT sungjongyoo monolayerquantumdotbasedlightsensorbyaphotoelectrochemicalmechanism
AT georgiacpapaefthymiou monolayerquantumdotbasedlightsensorbyaphotoelectrochemicalmechanism
AT dongkeeyi monolayerquantumdotbasedlightsensorbyaphotoelectrochemicalmechanism