A Comprehensive Study of Polyurethane Potting Compounds Doped with Magnesium Oxide Nanoparticles

Recently, polyurethanes (PURs) have become a very promising group of materials with considerable utilization and innovation potential. This work presents a comprehensive analysis of the changes in material properties important for PUR applications in the electrical industry due to the incorporation...

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Main Authors: Jaroslav Hornak, Jakub Černohous, Pavel Prosr, Pavel Rous, Pavel Trnka, Anton Baran, Štefan Hardoň
Format: Article
Language:English
Published: MDPI AG 2023-03-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/15/6/1532
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author Jaroslav Hornak
Jakub Černohous
Pavel Prosr
Pavel Rous
Pavel Trnka
Anton Baran
Štefan Hardoň
author_facet Jaroslav Hornak
Jakub Černohous
Pavel Prosr
Pavel Rous
Pavel Trnka
Anton Baran
Štefan Hardoň
author_sort Jaroslav Hornak
collection DOAJ
description Recently, polyurethanes (PURs) have become a very promising group of materials with considerable utilization and innovation potential. This work presents a comprehensive analysis of the changes in material properties important for PUR applications in the electrical industry due to the incorporation of magnesium oxide (MgO) nanoparticles at different weight ratios. From the results of the investigations carried out, it is evident that the incorporation of MgO improves the volume (by up to +0.5 order of magnitude) and surface (+1 order of magnitude) resistivities, reduces the dielectric losses at higher temperatures (−62%), improves the thermal stability of the material, and slows the decomposition reaction of polyurethane at specific temperatures (+30 °C). In contrast, the incorporation of MgO results in a slight decrease in the dielectric strength (−15%) and a significant decrease in the mechanical strength (−37%).
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spelling doaj.art-db78a4f655ef48eaab8ccc139dd959582023-11-17T13:26:51ZengMDPI AGPolymers2073-43602023-03-01156153210.3390/polym15061532A Comprehensive Study of Polyurethane Potting Compounds Doped with Magnesium Oxide NanoparticlesJaroslav Hornak0Jakub Černohous1Pavel Prosr2Pavel Rous3Pavel Trnka4Anton Baran5Štefan Hardoň6Department of Materials and Technology, Faculty of Electrical Engineering, University of West Bohemia, 306 14 Pilsen, Czech RepublicDepartment of Materials and Technology, Faculty of Electrical Engineering, University of West Bohemia, 306 14 Pilsen, Czech RepublicDepartment of Materials and Technology, Faculty of Electrical Engineering, University of West Bohemia, 306 14 Pilsen, Czech RepublicDepartment of Materials and Technology, Faculty of Electrical Engineering, University of West Bohemia, 306 14 Pilsen, Czech RepublicDepartment of Materials and Technology, Faculty of Electrical Engineering, University of West Bohemia, 306 14 Pilsen, Czech RepublicDepartment of Physics, Faculty of Electrical Engineering and Informatics, Technical University of Košice, Park Komenského 2, 042 00 Košice, SlovakiaDepartment of Physics, Faculty of Electrical Engineering and Information Technology, University of Žilina, 010 26 Žilina, SlovakiaRecently, polyurethanes (PURs) have become a very promising group of materials with considerable utilization and innovation potential. This work presents a comprehensive analysis of the changes in material properties important for PUR applications in the electrical industry due to the incorporation of magnesium oxide (MgO) nanoparticles at different weight ratios. From the results of the investigations carried out, it is evident that the incorporation of MgO improves the volume (by up to +0.5 order of magnitude) and surface (+1 order of magnitude) resistivities, reduces the dielectric losses at higher temperatures (−62%), improves the thermal stability of the material, and slows the decomposition reaction of polyurethane at specific temperatures (+30 °C). In contrast, the incorporation of MgO results in a slight decrease in the dielectric strength (−15%) and a significant decrease in the mechanical strength (−37%).https://www.mdpi.com/2073-4360/15/6/1532broadband dielectric spectroscopydielectric relaxationmagnesium oxidenanocompositesnuclear magnetic resonancepolyurethane
spellingShingle Jaroslav Hornak
Jakub Černohous
Pavel Prosr
Pavel Rous
Pavel Trnka
Anton Baran
Štefan Hardoň
A Comprehensive Study of Polyurethane Potting Compounds Doped with Magnesium Oxide Nanoparticles
Polymers
broadband dielectric spectroscopy
dielectric relaxation
magnesium oxide
nanocomposites
nuclear magnetic resonance
polyurethane
title A Comprehensive Study of Polyurethane Potting Compounds Doped with Magnesium Oxide Nanoparticles
title_full A Comprehensive Study of Polyurethane Potting Compounds Doped with Magnesium Oxide Nanoparticles
title_fullStr A Comprehensive Study of Polyurethane Potting Compounds Doped with Magnesium Oxide Nanoparticles
title_full_unstemmed A Comprehensive Study of Polyurethane Potting Compounds Doped with Magnesium Oxide Nanoparticles
title_short A Comprehensive Study of Polyurethane Potting Compounds Doped with Magnesium Oxide Nanoparticles
title_sort comprehensive study of polyurethane potting compounds doped with magnesium oxide nanoparticles
topic broadband dielectric spectroscopy
dielectric relaxation
magnesium oxide
nanocomposites
nuclear magnetic resonance
polyurethane
url https://www.mdpi.com/2073-4360/15/6/1532
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