A step-for-step main-group replica of the Fischer carbene synthesis at a borylene carbonyl
Abstract The Fischer carbene synthesis, involving the conversion of a transition metal (TM)-bound CO ligand to a carbene ligand of the form [=C(OR’)R] (R, R’ = organyl groups), is one of the seminal reactions in the history of organometallic chemistry. Carbonyl complexes of p-block elements, of the...
Main Authors: | Marcel Härterich, Alexander Matler, Rian D. Dewhurst, Andreas Sachs, Kai Oppel, Andreas Stoy, Holger Braunschweig |
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Format: | Article |
Language: | English |
Published: |
Nature Portfolio
2023-05-01
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Series: | Nature Communications |
Online Access: | https://doi.org/10.1038/s41467-023-36251-3 |
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