Multifunctional Materials Based on the Solid Solutions of the (Na, K, Cd<sub>0.5</sub>)NbO<sub>3</sub> (KNN-Cd) System Modified with Rare Earth Elements: Crystal Structure, Microstructure, and Macroresponses

Ceramic samples of polycomponent solid solutions (SSs) Na<sub>0.90</sub>K<sub>0.05</sub>Cd<sub>0.05</sub>NbO<sub>3</sub> (Cd-modified KNN) and [(Na<sub>0.90</sub>K<sub>0.05</sub>Cd<sub>0.05</sub>)<sub>0.95</...

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Main Authors: Andryushin Konstantin, Mikhail Palatnikov, Lidiya Shilkina, Alexandr Nagaenko, Olga Shcherbina, Maxim Smirnov, Nikolay Sidorov, Stanislav Kubrin, Anzhela Rudskaya, Daniil Rudskiy, Larisa Reznichenko
Format: Article
Language:English
Published: MDPI AG 2023-02-01
Series:Ceramics
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Online Access:https://www.mdpi.com/2571-6131/6/1/21
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author Andryushin Konstantin
Mikhail Palatnikov
Lidiya Shilkina
Alexandr Nagaenko
Olga Shcherbina
Maxim Smirnov
Nikolay Sidorov
Stanislav Kubrin
Anzhela Rudskaya
Daniil Rudskiy
Larisa Reznichenko
author_facet Andryushin Konstantin
Mikhail Palatnikov
Lidiya Shilkina
Alexandr Nagaenko
Olga Shcherbina
Maxim Smirnov
Nikolay Sidorov
Stanislav Kubrin
Anzhela Rudskaya
Daniil Rudskiy
Larisa Reznichenko
author_sort Andryushin Konstantin
collection DOAJ
description Ceramic samples of polycomponent solid solutions (SSs) Na<sub>0.90</sub>K<sub>0.05</sub>Cd<sub>0.05</sub>NbO<sub>3</sub> (Cd-modified KNN) and [(Na<sub>0.90</sub>K<sub>0.05</sub>Cd<sub>0.05</sub>)<sub>0.95</sub>REE<sub>0.05</sub>]NbO<sub>3</sub>, where REE = La, Pr, Tb, Dy, Ho, were obtained by the uniaxial hot pressing (UHP) method. The crystal lattice structures, morphological features of the microstructure, and dielectric and thermophysical properties of these ceramics have been investigated. For the first time, their strength characteristics (Young’s modulus) and the critical stress intensity factor of the mode I K<sub>ic</sub> have been estimated. Photoluminescent properties have been compared in SSs [(Na<sub>0.90</sub>K<sub>0.05</sub>Cd<sub>0.05</sub>)<sub>0.95</sub>REE<sub>0.05</sub>]NbO<sub>3</sub> in the visible wavelength range.
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spelling doaj.art-dbb51d511fb24560a1f83a2e46d694f62023-11-17T10:14:45ZengMDPI AGCeramics2571-61312023-02-016134236310.3390/ceramics6010021Multifunctional Materials Based on the Solid Solutions of the (Na, K, Cd<sub>0.5</sub>)NbO<sub>3</sub> (KNN-Cd) System Modified with Rare Earth Elements: Crystal Structure, Microstructure, and MacroresponsesAndryushin Konstantin0Mikhail Palatnikov1Lidiya Shilkina2Alexandr Nagaenko3Olga Shcherbina4Maxim Smirnov5Nikolay Sidorov6Stanislav Kubrin7Anzhela Rudskaya8Daniil Rudskiy9Larisa Reznichenko10Research Institute of Physics, Southern Federal University, Rostov-on-Don 344002, RussiaTananaev Institute of Chemistry—Subdivision of the Federal Research Centre, Kola Science Centre of the Russian Academy of Sciences, Apatity 184209, RussiaResearch Institute of Physics, Southern Federal University, Rostov-on-Don 344002, RussiaInstitute of High Technology and Piezo Technic, Southern Federal University, Rostov-on-Don 344002, RussiaTananaev Institute of Chemistry—Subdivision of the Federal Research Centre, Kola Science Centre of the Russian Academy of Sciences, Apatity 184209, RussiaTananaev Institute of Chemistry—Subdivision of the Federal Research Centre, Kola Science Centre of the Russian Academy of Sciences, Apatity 184209, RussiaTananaev Institute of Chemistry—Subdivision of the Federal Research Centre, Kola Science Centre of the Russian Academy of Sciences, Apatity 184209, RussiaResearch Institute of Physics, Southern Federal University, Rostov-on-Don 344002, RussiaFaculty of Physics, Southern Federal University, Rostov-on-Don 344002, RussiaResearch Institute of Physics, Southern Federal University, Rostov-on-Don 344002, RussiaResearch Institute of Physics, Southern Federal University, Rostov-on-Don 344002, RussiaCeramic samples of polycomponent solid solutions (SSs) Na<sub>0.90</sub>K<sub>0.05</sub>Cd<sub>0.05</sub>NbO<sub>3</sub> (Cd-modified KNN) and [(Na<sub>0.90</sub>K<sub>0.05</sub>Cd<sub>0.05</sub>)<sub>0.95</sub>REE<sub>0.05</sub>]NbO<sub>3</sub>, where REE = La, Pr, Tb, Dy, Ho, were obtained by the uniaxial hot pressing (UHP) method. The crystal lattice structures, morphological features of the microstructure, and dielectric and thermophysical properties of these ceramics have been investigated. For the first time, their strength characteristics (Young’s modulus) and the critical stress intensity factor of the mode I K<sub>ic</sub> have been estimated. Photoluminescent properties have been compared in SSs [(Na<sub>0.90</sub>K<sub>0.05</sub>Cd<sub>0.05</sub>)<sub>0.95</sub>REE<sub>0.05</sub>]NbO<sub>3</sub> in the visible wavelength range.https://www.mdpi.com/2571-6131/6/1/21solid solutionsperovskiteuniaxial hot pressingmicrostructuredielectric and thermophysical propertiesmicrohardness
spellingShingle Andryushin Konstantin
Mikhail Palatnikov
Lidiya Shilkina
Alexandr Nagaenko
Olga Shcherbina
Maxim Smirnov
Nikolay Sidorov
Stanislav Kubrin
Anzhela Rudskaya
Daniil Rudskiy
Larisa Reznichenko
Multifunctional Materials Based on the Solid Solutions of the (Na, K, Cd<sub>0.5</sub>)NbO<sub>3</sub> (KNN-Cd) System Modified with Rare Earth Elements: Crystal Structure, Microstructure, and Macroresponses
Ceramics
solid solutions
perovskite
uniaxial hot pressing
microstructure
dielectric and thermophysical properties
microhardness
title Multifunctional Materials Based on the Solid Solutions of the (Na, K, Cd<sub>0.5</sub>)NbO<sub>3</sub> (KNN-Cd) System Modified with Rare Earth Elements: Crystal Structure, Microstructure, and Macroresponses
title_full Multifunctional Materials Based on the Solid Solutions of the (Na, K, Cd<sub>0.5</sub>)NbO<sub>3</sub> (KNN-Cd) System Modified with Rare Earth Elements: Crystal Structure, Microstructure, and Macroresponses
title_fullStr Multifunctional Materials Based on the Solid Solutions of the (Na, K, Cd<sub>0.5</sub>)NbO<sub>3</sub> (KNN-Cd) System Modified with Rare Earth Elements: Crystal Structure, Microstructure, and Macroresponses
title_full_unstemmed Multifunctional Materials Based on the Solid Solutions of the (Na, K, Cd<sub>0.5</sub>)NbO<sub>3</sub> (KNN-Cd) System Modified with Rare Earth Elements: Crystal Structure, Microstructure, and Macroresponses
title_short Multifunctional Materials Based on the Solid Solutions of the (Na, K, Cd<sub>0.5</sub>)NbO<sub>3</sub> (KNN-Cd) System Modified with Rare Earth Elements: Crystal Structure, Microstructure, and Macroresponses
title_sort multifunctional materials based on the solid solutions of the na k cd sub 0 5 sub nbo sub 3 sub knn cd system modified with rare earth elements crystal structure microstructure and macroresponses
topic solid solutions
perovskite
uniaxial hot pressing
microstructure
dielectric and thermophysical properties
microhardness
url https://www.mdpi.com/2571-6131/6/1/21
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