High Temperature Stable Separator for Lithium Batteries Based on SiO2 and Hydroxypropyl Guar Gum

A novel membrane based on silicon dioxide (SiO2) and hydroxypropyl guar gum (HPG) as binder is presented and tested as a separator for lithium-ion batteries. The separator is made with renewable and low cost materials and an environmentally friendly manufacturing processing using only water as solve...

Full description

Bibliographic Details
Main Authors: Diogo Vieira Carvalho, Nicholas Loeffler, Guk-Tae Kim, Stefano Passerini
Format: Article
Language:English
Published: MDPI AG 2015-10-01
Series:Membranes
Subjects:
Online Access:http://www.mdpi.com/2077-0375/5/4/632
_version_ 1827850426085539840
author Diogo Vieira Carvalho
Nicholas Loeffler
Guk-Tae Kim
Stefano Passerini
author_facet Diogo Vieira Carvalho
Nicholas Loeffler
Guk-Tae Kim
Stefano Passerini
author_sort Diogo Vieira Carvalho
collection DOAJ
description A novel membrane based on silicon dioxide (SiO2) and hydroxypropyl guar gum (HPG) as binder is presented and tested as a separator for lithium-ion batteries. The separator is made with renewable and low cost materials and an environmentally friendly manufacturing processing using only water as solvent. The separator offers superior wettability and high electrolyte uptake due to the optimized porosity and the good affinity of SiO2 and guar gum microstructure towards organic liquid electrolytes. Additionally, the separator shows high thermal stability and no dimensional-shrinkage at high temperatures due to the use of the ceramic filler and the thermally stable natural polymer. The electrochemical tests show the good electrochemical stability of the separator in a wide range of potential, as well as its outstanding cycle performance.
first_indexed 2024-03-12T10:18:09Z
format Article
id doaj.art-dbd7e46835a8468181f123db949c6e65
institution Directory Open Access Journal
issn 2077-0375
language English
last_indexed 2024-03-12T10:18:09Z
publishDate 2015-10-01
publisher MDPI AG
record_format Article
series Membranes
spelling doaj.art-dbd7e46835a8468181f123db949c6e652023-09-02T10:23:50ZengMDPI AGMembranes2077-03752015-10-015463264510.3390/membranes5040632membranes5040632High Temperature Stable Separator for Lithium Batteries Based on SiO2 and Hydroxypropyl Guar GumDiogo Vieira Carvalho0Nicholas Loeffler1Guk-Tae Kim2Stefano Passerini3Helmholtz Institute Ulm (HIU), Helmholtzstrasse 11, 89081 Ulm, GermanyHelmholtz Institute Ulm (HIU), Helmholtzstrasse 11, 89081 Ulm, GermanyHelmholtz Institute Ulm (HIU), Helmholtzstrasse 11, 89081 Ulm, GermanyHelmholtz Institute Ulm (HIU), Helmholtzstrasse 11, 89081 Ulm, GermanyA novel membrane based on silicon dioxide (SiO2) and hydroxypropyl guar gum (HPG) as binder is presented and tested as a separator for lithium-ion batteries. The separator is made with renewable and low cost materials and an environmentally friendly manufacturing processing using only water as solvent. The separator offers superior wettability and high electrolyte uptake due to the optimized porosity and the good affinity of SiO2 and guar gum microstructure towards organic liquid electrolytes. Additionally, the separator shows high thermal stability and no dimensional-shrinkage at high temperatures due to the use of the ceramic filler and the thermally stable natural polymer. The electrochemical tests show the good electrochemical stability of the separator in a wide range of potential, as well as its outstanding cycle performance.http://www.mdpi.com/2077-0375/5/4/632separatorhydroxypropyl guar gum (HPG)silicon dioxide (SiO2)lithium batteriesaqueous processingthermal stability
spellingShingle Diogo Vieira Carvalho
Nicholas Loeffler
Guk-Tae Kim
Stefano Passerini
High Temperature Stable Separator for Lithium Batteries Based on SiO2 and Hydroxypropyl Guar Gum
Membranes
separator
hydroxypropyl guar gum (HPG)
silicon dioxide (SiO2)
lithium batteries
aqueous processing
thermal stability
title High Temperature Stable Separator for Lithium Batteries Based on SiO2 and Hydroxypropyl Guar Gum
title_full High Temperature Stable Separator for Lithium Batteries Based on SiO2 and Hydroxypropyl Guar Gum
title_fullStr High Temperature Stable Separator for Lithium Batteries Based on SiO2 and Hydroxypropyl Guar Gum
title_full_unstemmed High Temperature Stable Separator for Lithium Batteries Based on SiO2 and Hydroxypropyl Guar Gum
title_short High Temperature Stable Separator for Lithium Batteries Based on SiO2 and Hydroxypropyl Guar Gum
title_sort high temperature stable separator for lithium batteries based on sio2 and hydroxypropyl guar gum
topic separator
hydroxypropyl guar gum (HPG)
silicon dioxide (SiO2)
lithium batteries
aqueous processing
thermal stability
url http://www.mdpi.com/2077-0375/5/4/632
work_keys_str_mv AT diogovieiracarvalho hightemperaturestableseparatorforlithiumbatteriesbasedonsio2andhydroxypropylguargum
AT nicholasloeffler hightemperaturestableseparatorforlithiumbatteriesbasedonsio2andhydroxypropylguargum
AT guktaekim hightemperaturestableseparatorforlithiumbatteriesbasedonsio2andhydroxypropylguargum
AT stefanopasserini hightemperaturestableseparatorforlithiumbatteriesbasedonsio2andhydroxypropylguargum