Evaluation of Corrosion Damage Obtained During the Combustion Process in a Boiler. Case Study: Ferritic Steel ASTM A335 P91

The corrosive effects developed on Fe-9Cr-1Mo steel in a typical combustion environment were evaluated. For this, steel samples were submitted in a pirotubular horizontal boiler, through the design of a coupon holder. With the experimental conditions characterized, the theoretical corrosion products...

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Main Authors: Anibal Alviz-Meza, Viatcheslav Kafarov, Dario Y. Pena-Ballesteros
Format: Article
Language:English
Published: AIDIC Servizi S.r.l. 2018-08-01
Series:Chemical Engineering Transactions
Online Access:https://www.cetjournal.it/index.php/cet/article/view/613
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author Anibal Alviz-Meza
Viatcheslav Kafarov
Dario Y. Pena-Ballesteros
author_facet Anibal Alviz-Meza
Viatcheslav Kafarov
Dario Y. Pena-Ballesteros
author_sort Anibal Alviz-Meza
collection DOAJ
description The corrosive effects developed on Fe-9Cr-1Mo steel in a typical combustion environment were evaluated. For this, steel samples were submitted in a pirotubular horizontal boiler, through the design of a coupon holder. With the experimental conditions characterized, the theoretical corrosion products were simulated; which showed similarity with SEM-EDS and DRX analysis, in the formation of hematite, magnetite and chromite. On the other hand, the oxide layers morphology deposited on the substrate, indicated the appearance of multiple efforts in them: cracks, pores, voids and detachments were observed. To complement these observations, the kinetic study was carried out, which allowed to determine a semi-protective behaviour from the oxide layers formed on Fe-9Cr-1Mo steel; where the diffusive processes are partially reduced. Finally, only oxidation and some localized nitridation could be identified. Carburization could not be identified due to the high oxygen potentials in the environment, and to the short-selected exposure times.
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spelling doaj.art-dc0a325fe92844358ac15f9d16aa753d2022-12-21T23:08:15ZengAIDIC Servizi S.r.l.Chemical Engineering Transactions2283-92162018-08-017010.3303/CET1870183Evaluation of Corrosion Damage Obtained During the Combustion Process in a Boiler. Case Study: Ferritic Steel ASTM A335 P91Anibal Alviz-MezaViatcheslav KafarovDario Y. Pena-BallesterosThe corrosive effects developed on Fe-9Cr-1Mo steel in a typical combustion environment were evaluated. For this, steel samples were submitted in a pirotubular horizontal boiler, through the design of a coupon holder. With the experimental conditions characterized, the theoretical corrosion products were simulated; which showed similarity with SEM-EDS and DRX analysis, in the formation of hematite, magnetite and chromite. On the other hand, the oxide layers morphology deposited on the substrate, indicated the appearance of multiple efforts in them: cracks, pores, voids and detachments were observed. To complement these observations, the kinetic study was carried out, which allowed to determine a semi-protective behaviour from the oxide layers formed on Fe-9Cr-1Mo steel; where the diffusive processes are partially reduced. Finally, only oxidation and some localized nitridation could be identified. Carburization could not be identified due to the high oxygen potentials in the environment, and to the short-selected exposure times.https://www.cetjournal.it/index.php/cet/article/view/613
spellingShingle Anibal Alviz-Meza
Viatcheslav Kafarov
Dario Y. Pena-Ballesteros
Evaluation of Corrosion Damage Obtained During the Combustion Process in a Boiler. Case Study: Ferritic Steel ASTM A335 P91
Chemical Engineering Transactions
title Evaluation of Corrosion Damage Obtained During the Combustion Process in a Boiler. Case Study: Ferritic Steel ASTM A335 P91
title_full Evaluation of Corrosion Damage Obtained During the Combustion Process in a Boiler. Case Study: Ferritic Steel ASTM A335 P91
title_fullStr Evaluation of Corrosion Damage Obtained During the Combustion Process in a Boiler. Case Study: Ferritic Steel ASTM A335 P91
title_full_unstemmed Evaluation of Corrosion Damage Obtained During the Combustion Process in a Boiler. Case Study: Ferritic Steel ASTM A335 P91
title_short Evaluation of Corrosion Damage Obtained During the Combustion Process in a Boiler. Case Study: Ferritic Steel ASTM A335 P91
title_sort evaluation of corrosion damage obtained during the combustion process in a boiler case study ferritic steel astm a335 p91
url https://www.cetjournal.it/index.php/cet/article/view/613
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AT darioypenaballesteros evaluationofcorrosiondamageobtainedduringthecombustionprocessinaboilercasestudyferriticsteelastma335p91