N-[2-({[1-(4-Chlorophenyl)-1H-pyrazol-3-yl]oxy}methyl)phenyl]-N-methoxyhydrazinecarboxamide
In the title compound, C18H18ClN5O3, the hydrazinecarboxamide N—N—C(O)—N unit is nearly planar [maximum deviation = 0.074 (2) Å] and is inclined at a dihedral angle of 57.43 (7)° with respec...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812038214 |
| _version_ | 1818322149584142336 |
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| author | Rajni Kant Vivek K. Gupta Kamini Kapoor Chetan S. Shripanavar Kaushik Banerjee |
| author_facet | Rajni Kant Vivek K. Gupta Kamini Kapoor Chetan S. Shripanavar Kaushik Banerjee |
| author_sort | Rajni Kant |
| collection | DOAJ |
| description | In the title compound, C18H18ClN5O3, the hydrazinecarboxamide N—N—C(O)—N unit is nearly planar [maximum deviation = 0.074 (2) Å] and is inclined at a dihedral angle of 57.43 (7)° with respect to the plane of the attached benzene ring. The chlorophenyl group makes dihedral angles of 19.71 (7) and 34.07 (6)° with the pyrazole and benzene rings, respectively. In the crystal, pairs of N—H...O hydrogen bonds link the molecules into inversion dimers that are further linked into chains along the a-axis direction by N—H...N hydrogen bonds. In addition, π–π stacking interactions are observed between benzene rings [centroid–centroid distance = 3.680 (1) Å]. |
| first_indexed | 2024-12-13T10:52:12Z |
| format | Article |
| id | doaj.art-dc328e2a00294aa0ac4217222f50311b |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:52:12Z |
| publishDate | 2012-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-dc328e2a00294aa0ac4217222f50311b2022-12-21T23:49:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-10-016810o2916o291610.1107/S1600536812038214N-[2-({[1-(4-Chlorophenyl)-1H-pyrazol-3-yl]oxy}methyl)phenyl]-N-methoxyhydrazinecarboxamideRajni KantVivek K. GuptaKamini KapoorChetan S. ShripanavarKaushik BanerjeeIn the title compound, C18H18ClN5O3, the hydrazinecarboxamide N—N—C(O)—N unit is nearly planar [maximum deviation = 0.074 (2) Å] and is inclined at a dihedral angle of 57.43 (7)° with respect to the plane of the attached benzene ring. The chlorophenyl group makes dihedral angles of 19.71 (7) and 34.07 (6)° with the pyrazole and benzene rings, respectively. In the crystal, pairs of N—H...O hydrogen bonds link the molecules into inversion dimers that are further linked into chains along the a-axis direction by N—H...N hydrogen bonds. In addition, π–π stacking interactions are observed between benzene rings [centroid–centroid distance = 3.680 (1) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536812038214 |
| spellingShingle | Rajni Kant Vivek K. Gupta Kamini Kapoor Chetan S. Shripanavar Kaushik Banerjee N-[2-({[1-(4-Chlorophenyl)-1H-pyrazol-3-yl]oxy}methyl)phenyl]-N-methoxyhydrazinecarboxamide Acta Crystallographica Section E |
| title | N-[2-({[1-(4-Chlorophenyl)-1H-pyrazol-3-yl]oxy}methyl)phenyl]-N-methoxyhydrazinecarboxamide |
| title_full | N-[2-({[1-(4-Chlorophenyl)-1H-pyrazol-3-yl]oxy}methyl)phenyl]-N-methoxyhydrazinecarboxamide |
| title_fullStr | N-[2-({[1-(4-Chlorophenyl)-1H-pyrazol-3-yl]oxy}methyl)phenyl]-N-methoxyhydrazinecarboxamide |
| title_full_unstemmed | N-[2-({[1-(4-Chlorophenyl)-1H-pyrazol-3-yl]oxy}methyl)phenyl]-N-methoxyhydrazinecarboxamide |
| title_short | N-[2-({[1-(4-Chlorophenyl)-1H-pyrazol-3-yl]oxy}methyl)phenyl]-N-methoxyhydrazinecarboxamide |
| title_sort | n 2 1 4 chlorophenyl 1h pyrazol 3 yl oxy methyl phenyl n methoxyhydrazinecarboxamide |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812038214 |
| work_keys_str_mv | AT rajnikant n214chlorophenyl1hpyrazol3yloxymethylphenylnmethoxyhydrazinecarboxamide AT vivekkgupta n214chlorophenyl1hpyrazol3yloxymethylphenylnmethoxyhydrazinecarboxamide AT kaminikapoor n214chlorophenyl1hpyrazol3yloxymethylphenylnmethoxyhydrazinecarboxamide AT chetansshripanavar n214chlorophenyl1hpyrazol3yloxymethylphenylnmethoxyhydrazinecarboxamide AT kaushikbanerjee n214chlorophenyl1hpyrazol3yloxymethylphenylnmethoxyhydrazinecarboxamide |