Surface Active Sites of Modified Zeolites and Zirconia in the Conversion of Nitrogen(I, II) Oxides
Samples of zirconia doped with transition metal (Cr, Co, Ce) oxides, and also rhodium-promoted and Fe-containing zeolites of different structural types, were studied by NH 3 -TPD and IR spectroscopy. The various samples were analyzed with respect to their catalytic performances in deNO x reactions,...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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SAGE Publications
2007-02-01
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| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1260/026361707781485771 |
| _version_ | 1797288800438714368 |
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| author | Svetlana M. Orlyk Tatyana V. Mironyuk Tatyana M. Boichuk |
| author_facet | Svetlana M. Orlyk Tatyana V. Mironyuk Tatyana M. Boichuk |
| author_sort | Svetlana M. Orlyk |
| collection | DOAJ |
| description | Samples of zirconia doped with transition metal (Cr, Co, Ce) oxides, and also rhodium-promoted and Fe-containing zeolites of different structural types, were studied by NH 3 -TPD and IR spectroscopy. The various samples were analyzed with respect to their catalytic performances in deNO x reactions, in particular the selective catalytic reduction of NO (N 2 O) using hydrocarbons as reducing agents (HC SCR). Bifunctional zeolite- and ZrO 2 -based catalysts exhibited high activity in the SCR of nitrogen(I, II) oxides to dinitrogen due to the combination of the surface redox and acidic properties exhibited by these materials. |
| first_indexed | 2024-03-07T18:55:46Z |
| format | Article |
| id | doaj.art-dc51e76056d44164acc8039122a56c1c |
| institution | Directory Open Access Journal |
| issn | 0263-6174 2048-4038 |
| language | English |
| last_indexed | 2024-03-07T18:55:46Z |
| publishDate | 2007-02-01 |
| publisher | SAGE Publications |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj.art-dc51e76056d44164acc8039122a56c1c2024-03-02T00:29:46ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40382007-02-012510.1260/026361707781485771Surface Active Sites of Modified Zeolites and Zirconia in the Conversion of Nitrogen(I, II) OxidesSvetlana M. OrlykTatyana V. MironyukTatyana M. BoichukSamples of zirconia doped with transition metal (Cr, Co, Ce) oxides, and also rhodium-promoted and Fe-containing zeolites of different structural types, were studied by NH 3 -TPD and IR spectroscopy. The various samples were analyzed with respect to their catalytic performances in deNO x reactions, in particular the selective catalytic reduction of NO (N 2 O) using hydrocarbons as reducing agents (HC SCR). Bifunctional zeolite- and ZrO 2 -based catalysts exhibited high activity in the SCR of nitrogen(I, II) oxides to dinitrogen due to the combination of the surface redox and acidic properties exhibited by these materials.https://doi.org/10.1260/026361707781485771 |
| spellingShingle | Svetlana M. Orlyk Tatyana V. Mironyuk Tatyana M. Boichuk Surface Active Sites of Modified Zeolites and Zirconia in the Conversion of Nitrogen(I, II) Oxides Adsorption Science & Technology |
| title | Surface Active Sites of Modified Zeolites and Zirconia in the Conversion of Nitrogen(I, II) Oxides |
| title_full | Surface Active Sites of Modified Zeolites and Zirconia in the Conversion of Nitrogen(I, II) Oxides |
| title_fullStr | Surface Active Sites of Modified Zeolites and Zirconia in the Conversion of Nitrogen(I, II) Oxides |
| title_full_unstemmed | Surface Active Sites of Modified Zeolites and Zirconia in the Conversion of Nitrogen(I, II) Oxides |
| title_short | Surface Active Sites of Modified Zeolites and Zirconia in the Conversion of Nitrogen(I, II) Oxides |
| title_sort | surface active sites of modified zeolites and zirconia in the conversion of nitrogen i ii oxides |
| url | https://doi.org/10.1260/026361707781485771 |
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