Sputtering of lithium and lithium compound films under deuterium and helium ion bombardment

Conditioning of plasma facing components (PFCs) using lithium (Li) evaporation has shown to improve plasma performance in fusion devices by imposing low recycling boundary conditions. It is important to understand the retention and sputtering dynamics of deuterium (D) in Li and Li compound (LiO and...

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Main Authors: L. Buzi, A.O. Nelson, Y. Yang, R. Kaita, P.S. Krstić, B.E. Koel
Format: Article
Language:English
Published: Elsevier 2019-05-01
Series:Nuclear Materials and Energy
Online Access:http://www.sciencedirect.com/science/article/pii/S2352179118302473
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author L. Buzi
A.O. Nelson
Y. Yang
R. Kaita
P.S. Krstić
B.E. Koel
author_facet L. Buzi
A.O. Nelson
Y. Yang
R. Kaita
P.S. Krstić
B.E. Koel
author_sort L. Buzi
collection DOAJ
description Conditioning of plasma facing components (PFCs) using lithium (Li) evaporation has shown to improve plasma performance in fusion devices by imposing low recycling boundary conditions. It is important to understand the retention and sputtering dynamics of deuterium (D) in Li and Li compound (LiO and LiCO) films to most efficiently make predictions on plasma performance. Energetic D2+ incident on thin Li films is shown to readily form LiD leading to a lower Li sputtering yield than the sputtering yield of pure Li. Measured sputtering yields for thin LiD films agree with previous simulations and bulk erosion measurements. The He+ sputtering yield of pure Li was 2–3 times higher than the sputtering yield of D2+ on LiD. Incident 1000–1200 eV/D2+ sputtered LiO films at a slower rate than D2+ on LiD and LiCO films. Keywords: Deuterium retention, Lithium carbonate, Lithium deuteride, Sputtering, Thin films
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spelling doaj.art-dc57f9a59aa94626a0b576d4cc3217ff2022-12-22T03:38:34ZengElsevierNuclear Materials and Energy2352-17912019-05-0119411415Sputtering of lithium and lithium compound films under deuterium and helium ion bombardmentL. Buzi0A.O. Nelson1Y. Yang2R. Kaita3P.S. Krstić4B.E. Koel5Department of Chemical and Biological Engineering, Princeton University, A311 EQuad, Olden Street, Princeton, NJ 08544-5263, United StatesDepartment of Astrophysical Sciences, Princeton Program in Plasma Physics, Princeton University, Princeton, NJ 08544, United StatesDepartment of Chemical and Biological Engineering, Princeton University, A311 EQuad, Olden Street, Princeton, NJ 08544-5263, United StatesPrinceton Plasma Physics Laboratory, Princeton, NJ 08540, United StatesInstitute for Advanced Computational Science, Stony Brook University, NY 11794, United StatesDepartment of Chemical and Biological Engineering, Princeton University, A311 EQuad, Olden Street, Princeton, NJ 08544-5263, United States; Corresponding author.Conditioning of plasma facing components (PFCs) using lithium (Li) evaporation has shown to improve plasma performance in fusion devices by imposing low recycling boundary conditions. It is important to understand the retention and sputtering dynamics of deuterium (D) in Li and Li compound (LiO and LiCO) films to most efficiently make predictions on plasma performance. Energetic D2+ incident on thin Li films is shown to readily form LiD leading to a lower Li sputtering yield than the sputtering yield of pure Li. Measured sputtering yields for thin LiD films agree with previous simulations and bulk erosion measurements. The He+ sputtering yield of pure Li was 2–3 times higher than the sputtering yield of D2+ on LiD. Incident 1000–1200 eV/D2+ sputtered LiO films at a slower rate than D2+ on LiD and LiCO films. Keywords: Deuterium retention, Lithium carbonate, Lithium deuteride, Sputtering, Thin filmshttp://www.sciencedirect.com/science/article/pii/S2352179118302473
spellingShingle L. Buzi
A.O. Nelson
Y. Yang
R. Kaita
P.S. Krstić
B.E. Koel
Sputtering of lithium and lithium compound films under deuterium and helium ion bombardment
Nuclear Materials and Energy
title Sputtering of lithium and lithium compound films under deuterium and helium ion bombardment
title_full Sputtering of lithium and lithium compound films under deuterium and helium ion bombardment
title_fullStr Sputtering of lithium and lithium compound films under deuterium and helium ion bombardment
title_full_unstemmed Sputtering of lithium and lithium compound films under deuterium and helium ion bombardment
title_short Sputtering of lithium and lithium compound films under deuterium and helium ion bombardment
title_sort sputtering of lithium and lithium compound films under deuterium and helium ion bombardment
url http://www.sciencedirect.com/science/article/pii/S2352179118302473
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