Bis(acetylacetonato-κ2O,O′)aqua(diacetylmethanido-κC)iridium(III)
In the crystal structure of the title compound, [Ir(C5H7O2)3(H2O)], the IrIII atom is six-coordinated and situated in a slightly distorted octahedral environment. The complex contains both Ir—O and Ir—C bonds and was isolated from a reaction mixture of IrCl3(H2O)x, pentan...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053680903760X |
| _version_ | 1818791637941223424 |
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| author | Qiao-Wen Chang Ming-Jin Xie Wei-Ping Liu Xi-Zhu Chen Qing-Song Ye |
| author_facet | Qiao-Wen Chang Ming-Jin Xie Wei-Ping Liu Xi-Zhu Chen Qing-Song Ye |
| author_sort | Qiao-Wen Chang |
| collection | DOAJ |
| description | In the crystal structure of the title compound, [Ir(C5H7O2)3(H2O)], the IrIII atom is six-coordinated and situated in a slightly distorted octahedral environment. The complex contains both Ir—O and Ir—C bonds and was isolated from a reaction mixture of IrCl3(H2O)x, pentane-2,5-dione and NaHCO3. O—H...O hydrogen bonding between the water molecules and the carbonyl O atoms of adjacent molecules leads to a layered motif extending parallel to (010). |
| first_indexed | 2024-12-18T15:14:31Z |
| format | Article |
| id | doaj.art-dc93a16568144ac485ca328106d1a479 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-18T15:14:31Z |
| publishDate | 2009-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-dc93a16568144ac485ca328106d1a4792022-12-21T21:03:33ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-10-016510m1264m126410.1107/S160053680903760XBis(acetylacetonato-κ2O,O′)aqua(diacetylmethanido-κC)iridium(III)Qiao-Wen ChangMing-Jin XieWei-Ping LiuXi-Zhu ChenQing-Song YeIn the crystal structure of the title compound, [Ir(C5H7O2)3(H2O)], the IrIII atom is six-coordinated and situated in a slightly distorted octahedral environment. The complex contains both Ir—O and Ir—C bonds and was isolated from a reaction mixture of IrCl3(H2O)x, pentane-2,5-dione and NaHCO3. O—H...O hydrogen bonding between the water molecules and the carbonyl O atoms of adjacent molecules leads to a layered motif extending parallel to (010).http://scripts.iucr.org/cgi-bin/paper?S160053680903760X |
| spellingShingle | Qiao-Wen Chang Ming-Jin Xie Wei-Ping Liu Xi-Zhu Chen Qing-Song Ye Bis(acetylacetonato-κ2O,O′)aqua(diacetylmethanido-κC)iridium(III) Acta Crystallographica Section E |
| title | Bis(acetylacetonato-κ2O,O′)aqua(diacetylmethanido-κC)iridium(III) |
| title_full | Bis(acetylacetonato-κ2O,O′)aqua(diacetylmethanido-κC)iridium(III) |
| title_fullStr | Bis(acetylacetonato-κ2O,O′)aqua(diacetylmethanido-κC)iridium(III) |
| title_full_unstemmed | Bis(acetylacetonato-κ2O,O′)aqua(diacetylmethanido-κC)iridium(III) |
| title_short | Bis(acetylacetonato-κ2O,O′)aqua(diacetylmethanido-κC)iridium(III) |
| title_sort | bis acetylacetonato amp 954 2o o amp 8242 aqua diacetylmethanido amp 954 c iridium iii |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053680903760X |
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