Synthesis, structure and physicochemical properties of zinc and copper complexes based on sulfonamides containing 8-aminoquinoline ligands
Sulfonamides obtained by reaction of 8-aminoquinoline with 4-nitrobenzenesulfonylchloride and 2,4,6-triisopropylbenzenesulfonyl chloride were used to synthesize coordination compounds with CuII and ZnII with a ML2 composition. Determination of the crystal structures of the resulting zinc and copper...
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| Format: | Article |
| Language: | English |
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Sociedade Brasileira de Química
2008-01-01
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| Series: | Química Nova |
| Subjects: | |
| Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422008000500044 |
| _version_ | 1811212591931850752 |
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| author | Luiz Everson da Silva Paulo Teixeira de Sousa Jr. Antonio Carlos Joussef Clóvis Piovezan Ademir Neves |
| author_facet | Luiz Everson da Silva Paulo Teixeira de Sousa Jr. Antonio Carlos Joussef Clóvis Piovezan Ademir Neves |
| author_sort | Luiz Everson da Silva |
| collection | DOAJ |
| description | Sulfonamides obtained by reaction of 8-aminoquinoline with 4-nitrobenzenesulfonylchloride and 2,4,6-triisopropylbenzenesulfonyl chloride were used to synthesize coordination compounds with CuII and ZnII with a ML2 composition. Determination of the crystal structures of the resulting zinc and copper complexes by X-ray diffraction show a distorted tetrahedral environment for the [Cu(qnbsa)2], [Cu(qibsa)2] and [Zn(qibsa)2] complexes in which the sulfonamide group acts as a bidentate ligand through the nitrogen atoms from the sulfonamidate and quinoline groups. The complex [Zn(qnbsa)2] crystallizes with a water molecule from the solvent and the Zn is five-coordinated and shows a bipyramidal-trigonal geometry. The electrochemical and electronic spectroscopy properties of the copper complexes are also discussed. |
| first_indexed | 2024-04-12T05:31:39Z |
| format | Article |
| id | doaj.art-dc9ef82a59cd4b1dabc39316ba03d270 |
| institution | Directory Open Access Journal |
| issn | 0100-4042 1678-7064 |
| language | English |
| last_indexed | 2024-04-12T05:31:39Z |
| publishDate | 2008-01-01 |
| publisher | Sociedade Brasileira de Química |
| record_format | Article |
| series | Química Nova |
| spelling | doaj.art-dc9ef82a59cd4b1dabc39316ba03d2702022-12-22T03:46:03ZengSociedade Brasileira de QuímicaQuímica Nova0100-40421678-70642008-01-013151161116410.1590/S0100-40422008000500044Synthesis, structure and physicochemical properties of zinc and copper complexes based on sulfonamides containing 8-aminoquinoline ligandsLuiz Everson da SilvaPaulo Teixeira de Sousa Jr.Antonio Carlos JoussefClóvis PiovezanAdemir NevesSulfonamides obtained by reaction of 8-aminoquinoline with 4-nitrobenzenesulfonylchloride and 2,4,6-triisopropylbenzenesulfonyl chloride were used to synthesize coordination compounds with CuII and ZnII with a ML2 composition. Determination of the crystal structures of the resulting zinc and copper complexes by X-ray diffraction show a distorted tetrahedral environment for the [Cu(qnbsa)2], [Cu(qibsa)2] and [Zn(qibsa)2] complexes in which the sulfonamide group acts as a bidentate ligand through the nitrogen atoms from the sulfonamidate and quinoline groups. The complex [Zn(qnbsa)2] crystallizes with a water molecule from the solvent and the Zn is five-coordinated and shows a bipyramidal-trigonal geometry. The electrochemical and electronic spectroscopy properties of the copper complexes are also discussed.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422008000500044copperzincsulfonamide complexes |
| spellingShingle | Luiz Everson da Silva Paulo Teixeira de Sousa Jr. Antonio Carlos Joussef Clóvis Piovezan Ademir Neves Synthesis, structure and physicochemical properties of zinc and copper complexes based on sulfonamides containing 8-aminoquinoline ligands Química Nova copper zinc sulfonamide complexes |
| title | Synthesis, structure and physicochemical properties of zinc and copper complexes based on sulfonamides containing 8-aminoquinoline ligands |
| title_full | Synthesis, structure and physicochemical properties of zinc and copper complexes based on sulfonamides containing 8-aminoquinoline ligands |
| title_fullStr | Synthesis, structure and physicochemical properties of zinc and copper complexes based on sulfonamides containing 8-aminoquinoline ligands |
| title_full_unstemmed | Synthesis, structure and physicochemical properties of zinc and copper complexes based on sulfonamides containing 8-aminoquinoline ligands |
| title_short | Synthesis, structure and physicochemical properties of zinc and copper complexes based on sulfonamides containing 8-aminoquinoline ligands |
| title_sort | synthesis structure and physicochemical properties of zinc and copper complexes based on sulfonamides containing 8 aminoquinoline ligands |
| topic | copper zinc sulfonamide complexes |
| url | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422008000500044 |
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