5-Fluoro-3-(2-phenylhydrazinylidene)indolin-2-one
In the title compound, C14H10FN3O, the six- and five-membered rings of the isatin moiety and the six-membered ring of phenylhydrazone are nearly planar with r.m.s. deviations of 0.0003, 0.0004 and 0.007 Å, respectively. The dihedral angle between the phenyl ring and the is...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811015285 |
| _version_ | 1819291498225598464 |
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| author | Wen-Bin Wei Shuo Tian Hong Shen Jie Sun Hai-Bo Wang |
| author_facet | Wen-Bin Wei Shuo Tian Hong Shen Jie Sun Hai-Bo Wang |
| author_sort | Wen-Bin Wei |
| collection | DOAJ |
| description | In the title compound, C14H10FN3O, the six- and five-membered rings of the isatin moiety and the six-membered ring of phenylhydrazone are nearly planar with r.m.s. deviations of 0.0003, 0.0004 and 0.007 Å, respectively. The dihedral angle between the phenyl ring and the isatin ring system is 6.09 (9)°. The molecular structure is stabilized by a strong intramolecular N—H...O hydrogen bond, leading to the formation of a pseudo-six-membered ring, generating an S(6) ring. The crystal structure features intermolecular N—H...O interactions. |
| first_indexed | 2024-12-24T03:39:35Z |
| format | Article |
| id | doaj.art-dcd06ace1e0a47cbaab5ad36a3a7d9c8 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:39:35Z |
| publishDate | 2011-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-dcd06ace1e0a47cbaab5ad36a3a7d9c82022-12-21T17:16:57ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-06-01676o1294o129410.1107/S16005368110152855-Fluoro-3-(2-phenylhydrazinylidene)indolin-2-oneWen-Bin WeiShuo TianHong ShenJie SunHai-Bo WangIn the title compound, C14H10FN3O, the six- and five-membered rings of the isatin moiety and the six-membered ring of phenylhydrazone are nearly planar with r.m.s. deviations of 0.0003, 0.0004 and 0.007 Å, respectively. The dihedral angle between the phenyl ring and the isatin ring system is 6.09 (9)°. The molecular structure is stabilized by a strong intramolecular N—H...O hydrogen bond, leading to the formation of a pseudo-six-membered ring, generating an S(6) ring. The crystal structure features intermolecular N—H...O interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536811015285 |
| spellingShingle | Wen-Bin Wei Shuo Tian Hong Shen Jie Sun Hai-Bo Wang 5-Fluoro-3-(2-phenylhydrazinylidene)indolin-2-one Acta Crystallographica Section E |
| title | 5-Fluoro-3-(2-phenylhydrazinylidene)indolin-2-one |
| title_full | 5-Fluoro-3-(2-phenylhydrazinylidene)indolin-2-one |
| title_fullStr | 5-Fluoro-3-(2-phenylhydrazinylidene)indolin-2-one |
| title_full_unstemmed | 5-Fluoro-3-(2-phenylhydrazinylidene)indolin-2-one |
| title_short | 5-Fluoro-3-(2-phenylhydrazinylidene)indolin-2-one |
| title_sort | 5 fluoro 3 2 phenylhydrazinylidene indolin 2 one |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811015285 |
| work_keys_str_mv | AT wenbinwei 5fluoro32phenylhydrazinylideneindolin2one AT shuotian 5fluoro32phenylhydrazinylideneindolin2one AT hongshen 5fluoro32phenylhydrazinylideneindolin2one AT jiesun 5fluoro32phenylhydrazinylideneindolin2one AT haibowang 5fluoro32phenylhydrazinylideneindolin2one |