catena-Poly[[diaquamanganese(II)]-μ-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato]
In the title polymer, [Mn(C8H8O5)(H2O)2]n, the MnII atom is in a distorted octahedral coordination mode, binding to the bridging O atom of the bicycloheptane unit, two O atoms from corresponding carboxylate groups, one carboxylate O atom from a symmetry-related bridging ligand and two water O atoms....
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810019021 |
| _version_ | 1819105123841867776 |
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| author | Na Wang Jie Feng Dong-Hang Wang Qiu-Yue Lin |
| author_facet | Na Wang Jie Feng Dong-Hang Wang Qiu-Yue Lin |
| author_sort | Na Wang |
| collection | DOAJ |
| description | In the title polymer, [Mn(C8H8O5)(H2O)2]n, the MnII atom is in a distorted octahedral coordination mode, binding to the bridging O atom of the bicycloheptane unit, two O atoms from corresponding carboxylate groups, one carboxylate O atom from a symmetry-related bridging ligand and two water O atoms. This arrangement leads to the formation of polymeric chains propagating parallel to [001]. The crystal structure is stabilized by several O—H...O hydrogen-bonding interactions involving the coordinated water molecules as donors and the carboxylate O atoms as acceptors. |
| first_indexed | 2024-12-22T02:17:15Z |
| format | Article |
| id | doaj.art-dd08913c4394402f9f41b4037ac07374 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-22T02:17:15Z |
| publishDate | 2010-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-dd08913c4394402f9f41b4037ac073742022-12-21T18:42:14ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-06-01666m717m71710.1107/S1600536810019021catena-Poly[[diaquamanganese(II)]-μ-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato]Na WangJie FengDong-Hang WangQiu-Yue LinIn the title polymer, [Mn(C8H8O5)(H2O)2]n, the MnII atom is in a distorted octahedral coordination mode, binding to the bridging O atom of the bicycloheptane unit, two O atoms from corresponding carboxylate groups, one carboxylate O atom from a symmetry-related bridging ligand and two water O atoms. This arrangement leads to the formation of polymeric chains propagating parallel to [001]. The crystal structure is stabilized by several O—H...O hydrogen-bonding interactions involving the coordinated water molecules as donors and the carboxylate O atoms as acceptors.http://scripts.iucr.org/cgi-bin/paper?S1600536810019021 |
| spellingShingle | Na Wang Jie Feng Dong-Hang Wang Qiu-Yue Lin catena-Poly[[diaquamanganese(II)]-μ-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato] Acta Crystallographica Section E |
| title | catena-Poly[[diaquamanganese(II)]-μ-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato] |
| title_full | catena-Poly[[diaquamanganese(II)]-μ-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato] |
| title_fullStr | catena-Poly[[diaquamanganese(II)]-μ-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato] |
| title_full_unstemmed | catena-Poly[[diaquamanganese(II)]-μ-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato] |
| title_short | catena-Poly[[diaquamanganese(II)]-μ-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato] |
| title_sort | catena poly diaquamanganese ii amp 956 7 oxabicyclo 2 2 1 heptane 2 3 dicarboxylato |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810019021 |
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