Melamine-imprinted electrochemical sensor of graphene/ionic liquid composites and its use for the detection of melamine in dairy products

By exchanging the conventional role of functional monomer and template molecules, we develop a new molecularly imprinted nanospheres with grape grain structures based on multi-hydrogen bonding interactions between melamine and 6-aminouracil. Molecular imprinting-electrochemical sensor was establishe...

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Main Authors: Peini Zhao, Xiaolai Zhang, Jingcheng Hao
Format: Article
Language:English
Published: KeAi Communications Co., Ltd. 2022-07-01
Series:ChemPhysMater
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2772571521000140
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author Peini Zhao
Xiaolai Zhang
Jingcheng Hao
author_facet Peini Zhao
Xiaolai Zhang
Jingcheng Hao
author_sort Peini Zhao
collection DOAJ
description By exchanging the conventional role of functional monomer and template molecules, we develop a new molecularly imprinted nanospheres with grape grain structures based on multi-hydrogen bonding interactions between melamine and 6-aminouracil. Molecular imprinting-electrochemical sensor was established with the assistance of graphene and ionic liquids. The content of melamine in dairy products was detected by the molecular imprinting-electrochemical sensor. The detection limit was determined to be as low as 1.57 × 10−3 mg kg-1.
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spelling doaj.art-dd231f86bc5e4ab6a5b8383c4061362a2022-12-22T04:41:58ZengKeAi Communications Co., Ltd.ChemPhysMater2772-57152022-07-0113195202Melamine-imprinted electrochemical sensor of graphene/ionic liquid composites and its use for the detection of melamine in dairy productsPeini Zhao0Xiaolai Zhang1Jingcheng Hao2Key Laboratory of Colloid and Interface Chemistry & Key Laboratory of Special Aggregated Materials, Shandong University, Ministry of Education, Jinan 250100, ChinaKey Laboratory of Colloid and Interface Chemistry & Key Laboratory of Special Aggregated Materials, Shandong University, Ministry of Education, Jinan 250100, ChinaCorresponding author.; Key Laboratory of Colloid and Interface Chemistry & Key Laboratory of Special Aggregated Materials, Shandong University, Ministry of Education, Jinan 250100, ChinaBy exchanging the conventional role of functional monomer and template molecules, we develop a new molecularly imprinted nanospheres with grape grain structures based on multi-hydrogen bonding interactions between melamine and 6-aminouracil. Molecular imprinting-electrochemical sensor was established with the assistance of graphene and ionic liquids. The content of melamine in dairy products was detected by the molecular imprinting-electrochemical sensor. The detection limit was determined to be as low as 1.57 × 10−3 mg kg-1.http://www.sciencedirect.com/science/article/pii/S2772571521000140Molecular imprintingGrapheneIonic liquidElectrochemical sensorDairy product
spellingShingle Peini Zhao
Xiaolai Zhang
Jingcheng Hao
Melamine-imprinted electrochemical sensor of graphene/ionic liquid composites and its use for the detection of melamine in dairy products
ChemPhysMater
Molecular imprinting
Graphene
Ionic liquid
Electrochemical sensor
Dairy product
title Melamine-imprinted electrochemical sensor of graphene/ionic liquid composites and its use for the detection of melamine in dairy products
title_full Melamine-imprinted electrochemical sensor of graphene/ionic liquid composites and its use for the detection of melamine in dairy products
title_fullStr Melamine-imprinted electrochemical sensor of graphene/ionic liquid composites and its use for the detection of melamine in dairy products
title_full_unstemmed Melamine-imprinted electrochemical sensor of graphene/ionic liquid composites and its use for the detection of melamine in dairy products
title_short Melamine-imprinted electrochemical sensor of graphene/ionic liquid composites and its use for the detection of melamine in dairy products
title_sort melamine imprinted electrochemical sensor of graphene ionic liquid composites and its use for the detection of melamine in dairy products
topic Molecular imprinting
Graphene
Ionic liquid
Electrochemical sensor
Dairy product
url http://www.sciencedirect.com/science/article/pii/S2772571521000140
work_keys_str_mv AT peinizhao melamineimprintedelectrochemicalsensorofgrapheneionicliquidcompositesanditsuseforthedetectionofmelamineindairyproducts
AT xiaolaizhang melamineimprintedelectrochemicalsensorofgrapheneionicliquidcompositesanditsuseforthedetectionofmelamineindairyproducts
AT jingchenghao melamineimprintedelectrochemicalsensorofgrapheneionicliquidcompositesanditsuseforthedetectionofmelamineindairyproducts