The synthesis and characterization of complexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with potassium 3-dithiocarboxy-3-aza-5-amino-pentanoate
Complexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with a new polydentate dithiocarbamate ligand, 3-dithiocarboxy-3-aza-5-aminopentanoate (daap-), of the type M(daap)2.nH2O (M= Zn(II), Cd(II), n = 2, or M= Pt(II) Pd(II), n = 0), have been prepared and characterized by elemental analy...
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| Format: | Article |
| Language: | English |
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Serbian Chemical Society
2004-01-01
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| Series: | Journal of the Serbian Chemical Society |
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| Online Access: | http://www.doiserbia.nb.rs/img/doi/0352-5139/2004/0352-51390402137L.pdf |
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| author | Leka Zorica Grujić Slobodan A. Tešić Živoslav L. Lukić Svetlana R. Skuban Sonja J. Trifunović Srećko R. |
| author_facet | Leka Zorica Grujić Slobodan A. Tešić Živoslav L. Lukić Svetlana R. Skuban Sonja J. Trifunović Srećko R. |
| author_sort | Leka Zorica |
| collection | DOAJ |
| description | Complexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with a new polydentate dithiocarbamate ligand, 3-dithiocarboxy-3-aza-5-aminopentanoate (daap-), of the type M(daap)2.nH2O (M= Zn(II), Cd(II), n = 2, or M= Pt(II) Pd(II), n = 0), have been prepared and characterized by elemental analysis IR and UV/VIS spectroscopy, as well as magnetic measurements. The spectra of the complexes suggest a bidentate coordination of the daap- ligand to the metal ions via the sulfur atoms of the deprotonated dithiocarbamato group. The fact that under the same experimental conditions its S-methyl ester does not form complexes could be taken as proof of the suggested coordination mode. |
| first_indexed | 2024-12-19T14:17:33Z |
| format | Article |
| id | doaj.art-dd3dfe814e864643a7bed55be8aa56cc |
| institution | Directory Open Access Journal |
| issn | 0352-5139 1820-7421 |
| language | English |
| last_indexed | 2024-12-19T14:17:33Z |
| publishDate | 2004-01-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-dd3dfe814e864643a7bed55be8aa56cc2022-12-21T20:17:56ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51391820-74212004-01-0169213714410.2298/JSC0402137L0352-51390402137LThe synthesis and characterization of complexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with potassium 3-dithiocarboxy-3-aza-5-amino-pentanoateLeka Zorica0Grujić Slobodan A.1Tešić Živoslav L.2Lukić Svetlana R.3Skuban Sonja J.4Trifunović Srećko R.5Faculty of Metallurgy and Technology, University of Montenegro, PodgoricaDepartment of Chemistry, Faculty of Science, University of Kragujevac, P. O. Box 60, KragujevacFaculty of Chemistry, University of Belgrade, P. O. Box 158, BelgradeInstitute of Physics, Faculty of Science, Novi Sad, Serbia and MontenegroInstitute of Physics, Faculty of Science, Novi Sad, Serbia and MontenegroDepartment of Chemistry, Faculty of Science, University of Kragujevac, P. O. Box 60, KragujevacComplexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with a new polydentate dithiocarbamate ligand, 3-dithiocarboxy-3-aza-5-aminopentanoate (daap-), of the type M(daap)2.nH2O (M= Zn(II), Cd(II), n = 2, or M= Pt(II) Pd(II), n = 0), have been prepared and characterized by elemental analysis IR and UV/VIS spectroscopy, as well as magnetic measurements. The spectra of the complexes suggest a bidentate coordination of the daap- ligand to the metal ions via the sulfur atoms of the deprotonated dithiocarbamato group. The fact that under the same experimental conditions its S-methyl ester does not form complexes could be taken as proof of the suggested coordination mode.http://www.doiserbia.nb.rs/img/doi/0352-5139/2004/0352-51390402137L.pdfzinc(ii)cadmium(ii)platinum(ii)palladium(ii)complexessynthesisdithiocarbamate |
| spellingShingle | Leka Zorica Grujić Slobodan A. Tešić Živoslav L. Lukić Svetlana R. Skuban Sonja J. Trifunović Srećko R. The synthesis and characterization of complexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with potassium 3-dithiocarboxy-3-aza-5-amino-pentanoate Journal of the Serbian Chemical Society zinc(ii) cadmium(ii) platinum(ii) palladium(ii) complexes synthesis dithiocarbamate |
| title | The synthesis and characterization of complexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with potassium 3-dithiocarboxy-3-aza-5-amino-pentanoate |
| title_full | The synthesis and characterization of complexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with potassium 3-dithiocarboxy-3-aza-5-amino-pentanoate |
| title_fullStr | The synthesis and characterization of complexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with potassium 3-dithiocarboxy-3-aza-5-amino-pentanoate |
| title_full_unstemmed | The synthesis and characterization of complexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with potassium 3-dithiocarboxy-3-aza-5-amino-pentanoate |
| title_short | The synthesis and characterization of complexes of zinc(II), cadmium(II), platinum(II) and palladium(II) with potassium 3-dithiocarboxy-3-aza-5-amino-pentanoate |
| title_sort | synthesis and characterization of complexes of zinc ii cadmium ii platinum ii and palladium ii with potassium 3 dithiocarboxy 3 aza 5 amino pentanoate |
| topic | zinc(ii) cadmium(ii) platinum(ii) palladium(ii) complexes synthesis dithiocarbamate |
| url | http://www.doiserbia.nb.rs/img/doi/0352-5139/2004/0352-51390402137L.pdf |
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